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...that the inventor of the electric motor was a blacksmith named Thomas Davenport? Described as "a brilliantly unsuccessful inventor", Davenport invented the first rotary electric motor. In 1836 he headed out -- on foot -- from his Vermont home to file a patent application at the Patent Office in Washington, D.C. By the time he got there, he had squandered away his money and couldn't afford the $30 filing fee so he turned around and went home. When he later mailed in his application with money he'd raised, the Patent office was destroyed in a fire. He did finally get credit for his invention on Feb. 5, 1837.

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Class 568/356 - Carbon to carbon unsaturation in the reactant


Subclass of Class 568 - Organic compounds -- part of the class 532-570 series
Definition: Processes wherein the -COO- containing reactant contains
No. of patents: 31
Last issue date: 07/24/2007


NumberTitleIssue Date
7247753Method for producing macrocyclic ketones by means of dieckmann codensation in the gas phase
The invention relates to a method for producing macrocyclic ketones of general formula (I) by direct cyclisation of compounds of general formula (II) in the gas phase on a heterogeneous catalyst. In general formula (I), X represents a monounsaturated or polyunsatura...
07/24/2007
6872856Cyclic ketones, their preparation and their use in the synthesis of amino acids
A method is provided for making an enantiomerically pure compound of the formula: in which R and R′ represent C1?C10 alkyl, C2?C10 alkenyl or C3?C10 cycloalkyl and the wedges signify (S)- or (R)-stereochemistry, the substituents in compound (II) being trans. Conju...
03/29/2005
6828464Preparation of cyclopentenones
The present invention provides a process for preparing 2-cyclopentenones of the general formula: where R1 to R4 are each hydrogen atoms or are alkyl or alkenyl radicals having from 1 to 12 carbon ...
12/07/2004
6787671Catalytic osmium-assisted oxidative cleavage of olefins
An osmium-assisted process for the oxidative cleavage of oxidizable organic compounds such as unsaturated organic compounds, including alkenes and olefins into aldehydes, carboxylic acids, esters, or ketones. The process uses a metal catalyst comprising osmium and a...
09/07/2004
6518461Method of continuously producing a cyclododecanone compound
A cyclododecanone compound is continuously produced by an isomerization reaction of a corresponding epoxycyclododecane compound in the presence of a catalyst including lithium bromide and/or lithium iodide, the isomerization reaction being carried out by ...
02/11/2003
6500990Method for producing jasmonate derivatives and intermediates thereof
A process for efficiently producing a 2-alkyl-2-cyclopentenone comprising reacting an amine and a hydrogen halide, which are present in a ratio ranging from 1.1:1 to 5:1, with a 2-alkylidene cyclopentanone to carry out an isomerization reaction. A process...
12/31/2002
6242413Bicyclic aldehyde and ketone odorants
The invention relates to bicyclic aldehydes and ketones of formula (I): ##STR1## wherein n is 1 or 2; R1 and R4 are independently H or CH3 ; and R2 and R3 are independently H, CH3 or CH2 C...
06/05/2001
6200786Process for the preparation of nootkatone by laccase catalysis
A method of producing nootkatone by laccase catalyzed oxidation of valencene. Valencene and a composition having laccase activity are reacted in the presence of an oxygen source, at a valencene concentration greater than 0.1%, to form valencene hydroperox...
03/13/2001
6031139Preparation of ଱-fluoroketones
The use of polar organic solvent as the solvent in the direct fluorination, to make an ଱-fluoroketone, of an enol ester or enol trialkylsilyl ether of a compound containing a tautomerisable ketone group, the solvent being relatively inert to fluorin...
02/29/2000
6025527Trimethylcyclohexenylcyclopropyl ketones, process for producing same, and uses thereof in perfumery
Described are trimethylcyclohexenylcyclopropyl ketones having the structure: ##STR1## wherein one of the dashed lines is a carbon--carbon double bond and the other of the dashed lines is a carbon--carbon single bond, uses thereof in augmenting, ...
02/15/2000
5519160Alkyl 3-(substituted or unsubstituted benzylidene)-1-alkyl-2-oxocyclopentanecarboxylate derivatives, process for preparing the same
Derivatives of alkyl 3-(substituted or unsubstituted benzylidene)-1-alkyl-2-oxocylopentanecarboxylate of the following formula (I), ##STR1## wherein R1 and R2 individually represent a lower alkyl group; X is a halogen atom,...
05/21/1996
5399775Process for preparing substituted cyclobutanes
The present invention relates to a process for the preparation of substituted cyclobutanes and their use as intermediates for the preparation of anti-viral nucleoside analogs....
03/21/1995
5243080Method of fluorinating by using N-fluoropyridinium pyridine heptafluorodiborate
The present invention provides a novel compound represented as ##STR1## The present novel compound is prepared by reacting fluorine with pyridine-boron trifluoride and is useful as a fluorinating agent in the fluorination of organic compounds....
09/07/1993
5191125Procedure for the preparation of bicyclo [3.2.0]hept-2-en-7-ones
A procedure is described for the preparation of compounds having a bicyclo[3.2.0]heptenonic structure corresponding to the formula: ##STR1## wherein R1 and R2, the same or different are hydrogen or a C1 -C4...
03/02/1993
5118863Process for producing an ଱,ଲ-unsaturated carbonyl compound
A process for producing an ଱,ଲ-unsaturated carbonyl compound represented by formula (II): ##STR1## which includes subjecting an alkenyl ester represented by formula (I): ##STR2## and an allyl type carbonic ester to catalytic reaction...
06/02/1992
5077275Acylated bicycloalkadiene-compound-containing compositions of matter process for preparing same and perfumery uses thereof
Described are acylated bicycloalkadiene-compound-containing compositions of matter, mixtures of compounds containing predominantly compounds having the structures: ##STR1## with the compositions of matter containing from 50 up to 100% of the com...
12/31/1991
5030739Process for the catalytic oxidation of isoprenoids having allylic groups
The invention is directed to a process for the catalytic oxidation of an isoprenoid containing at least one allylic hydrogen atom, which process comprises reacting the isoprenoid with oxygen or an oxygen-containing gas in an inert solvent in the presence ...
07/09/1991
4910347Cycloaliphatic aldehydes and process for the preparation thereof
Racemic and optically active cycloaliphatic 2,2,6-trimethylcyclohexanecarboxyaldehyde, also known as dihydrocyclocitral, are prepared by a novel process consisting in the cyclization of enol esters of formula ##STR1## wherein the wavy line defin...
03/20/1990
4900870Process for the preparation of cycloaliphatic ketones
Process for the preparation of cycloaliphatic ketones of formula ##STR1## wherein index m designates integer 0, 1 or 2, n stands for 0 or 1 and the dotted lines represent an optional supplemental bond, which process consists in the deprotonation of a...
02/13/1990
47958362-alkanoyl-2-(1-penten-1-yl)cyclohexanones, process for preparing same, and organoleptic uses thereof and intermediates useful in said process
Described are 2-alkanoyl-2-(1-penten-1-yl) cyclohexanones of my invention defined according to the structure: ##STR1## wherein R represents methyl or ethyl; a process for preparing same and organoleptic uses thereof in augmenting or enhancing the aro...
01/03/1989
47883372-alkanoyl-2-(1-penten-1-yl)cyclohexanones, process for preparing same, and organoleptic uses thereof and intermediates useful in said process
Described are 2-alkanoyl-2-(1-penten-1-yl) cyclohexanones of my invention defined according to the structure: ##STR1## wherein R represents methyl or ethyl; a process for preparing same and organoleptic uses thereof in augmenting or enhancing the aro...
11/29/1988
4721815Preparation of substituted benzophenones
There is disclosed a process for the preparation of a benzophenone, which process comprises contacting a feed comprising a 3-cyclohexene carboxylic acid in the vapor phase and under suitable conditions with a ketonic decarboxylative coupling catalyst to c...
01/26/1988
4499297Process for the preparation of alkylated cyclopentenones
Cyclopentenones of formula ##STR1## wherein each of symbols R1 and R2, when taken separately, represents an alkyl radical of C1 to C6, or a hydrogen atom, or, when taken together, they represent a polymethy...
02/12/1985
4385186Optically active 4-hydroxy-3-methyl-2-(2-propynyl)-2-cyclopentenone
The present invention relates to a method for producing an optically active (+)-(s)-4-hydroxy-3-methyl-2-2'-propynyl-2-cyclopentenone which comprises reacting (&#b1;)-4-hydroxy-3-methyl-2-2'-propynyl-2-cyclopentenone acid phthalate of the formula (II), ...
05/24/1983
4310705Preparation of higher unsaturated ketones
An improved process for the preparation of higher unsaturated ketones, such as geranylacetone and farnesylacetone, by reacting a ଲ,γ-unsaturated alcohol and an alkyl acetoacetate at an elevated temperature in the presence of an organic aluminum com...
01/12/1982
4300001Desensitized TNT; its preparation and use
The explosive 2,4,6-trinitrotoluene (TNT) is desensitized by dissolving it in oleum of from 10 to 40% (by weight) in strength. The solutions formed preferably contain at least 400 g and at most 480 g of dissolved TNT per liter of oleum in oleum of 20-25% ...
11/10/1981
42595183-Methyl-5-keto-଱,ω-alkenedioic acids and esters
The invention concerns new 3-methyl-5-keto-଱,ω-alkene-dioic acids of the general formula ##STR1## wherein the double bond is in one of the positions indicated by the broken lines, R1 and R2 independently of one another ar...
03/31/1981
4209450Introduction of a carbonyl group into a cyclohexene ring
A process for introducing an allyl-positioned carbonyl group into a 2,6,6-trimethylcyclohexene ring which carries a polyenyl radical in the 1-position, by oxidizing the ring with a halogen(V)-oxyacid or a salt of such an acid, and the new oxo compounds ob...
06/24/1980
4111993Process for racemization of allethrolone
A novel process for the preparation of racemic allethrolone of the (R,S) configuration comprising heating optically active allethrolone of the (R) configuration or of the (S) configuration or a mixture of the (R) and (S) configurations in non-equimolecula...
09/05/1978
4100208Process for the production of unsaturated compounds
Process for production of ethylenic compounds by hydrogenating the corresponding alkynol with isopropyl alcohol in the presence of a metal complex such as IrH3 CO(P$c;3)2 and IrH3 (P$c;3)2....
07/11/1978
3983177Process for the preparation of unsaturated ketones
Ketones, which are intermediates in the synthesis of vitamin A or perfumes, and have the general formula: ##EQU1## wherein R1 is hydrogen or C1.sub.-10 hydrocarbon, R2 and R3 are hydrogen or C1.sub.-4
09/28/1976
 
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