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Class 564/334 - Purification or recovery


Subclass of Class 564 - Organic compounds -- part of the class 532-570 series
Definition: Processes directed to the purification, separation, or recovery
No. of patents: 44
Last issue date: 12/14/2004


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NumberTitleIssue Date
6831192Process for preparing methylenedianiline and methylenebis(phenyl isocyanate)
A process for preparing methylenedianiline by reacting aniline with formaldehyde in the presence of acid catalysts comprising, in a semicontinuous process, introducing aniline with or without acid catalyst, feeding formaldehyde with or without acid catalyst through ...
12/14/2004
6818795Process for the preparation of mixtures of methylenedianiline and its higher homologous products
Process for the production of methylenedianiline and its higher homologous products which comprises reacting aniline, or one of its derivatives, and formaldehyde, or one of its precursors, in one or two reactors in the presence of a solid acid catalyst selected from...
11/16/2004
6680385Catalytic preparation of aryl methyl ketones using a molecular oxygen-containing gas as the oxidant
A method for the preparation of aryl methyl ketones converts a variety of ethyl arenas to the corresponding aryl methyl ketones using a dioxygen-containing gas as the oxidant. The catalyst used for the reaction is a metal complex bearing general formulas ...
01/20/2004
6673970Process for preparing methylene diphenylamines by partial neutralization of acidic methylene diphenylamines
Disclosed herein is a process for preparing a reaction product containing methylene diphenylamine, comprising reacting aniline and formaldehyde in the presence of an acid catalyst wherein the acid level of the resulting reaction mixture is reduced during ...
01/06/2004
6639102Process for producing polyisocyanates of the diphenyl methane series having a reduced color value
Polyisocyanates of the diphenyl methane series having reduced color values are obtained by a) reacting aniline and formaldehyde in the presence of an acid catalyst to form a polyamine, b) neutralizing the reaction mixture containing polyamine with a base,...
10/28/2003
6610888Reaction of a solution comprising a mixture
A method of reacting a solution comprising a mixture of chemical compounds which are in chemical equilibrium with one another with at least one further chemical compound (9) is provided. The method comprises the following steps: fractionation of the solut...
08/26/2003
6433219Method for the production of methylenedi(phenylamine and methylenedi(phenyl isocyanate)
A process for preparing methylenedianiline by reacting aniline with formaldehyde in the presence of acid catalysts comprising, in a semicontinuous process, introducing aniline with or without acid catalyst, feeding formaldehyde with or without acid cataly...
08/13/2002
5942151Polymeric MDI color
A process for the production of polymethylene polyphenyl polyisocyanates is disclosed. The process comprises phosgenating the corresponding polyamines in solution in an inert organic solvent, removing excess phosgene, and stripping the solvent, the improv...
08/24/1999
5889070Process for preparing polyamines and polysocyanates
Disclosed herein is an improved process for preparing a polyamine mixture derived by reacting aniline with formaldehyde in the presence of an acid catalyst the improvement comprising mildly reducing the polyamine mixture by a process step comprising catal...
03/30/1999
5684180Fractionation and purification of aromatic polyamine mixtures and the use thereof
The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and to the use thereof....
11/04/1997
5679841Fractionation and purification of aromatic polyamine mixtures and the use thereof
The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and the use thereof....
10/21/1997
5679840Fractionation and purification of aromatic polyamine mixtures and the use thereof
The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and their use....
10/21/1997
5675035Fractionation and purification of aromatic polyamine mixtures and the use thereof
The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and to their use....
10/07/1997
5672737Fractionation and purification of mixtures of aromatic polyamines and use thereof
The invention relates to a process for the fractionation and purification of mixtures of aromatic polyamines and to the use thereof....
09/30/1997
5648519Fractionation and purification of aromatic polyamine mixtures and the use thereof
The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and to the use thereof....
07/15/1997
5648520Fractionation and purification of aromatic polyamine and the use thereof
The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and the use thereof....
07/15/1997
5386059Process for preparing polyamines for lighter color polyisocyanate based foam
The present invention encompasses an improved process for preparing polymethylene polyphenyl polyisocyanate comprising reacting phosgene with polymethylene polyphenyl polyamine, the improvement wherein the polymethylene polyphenyl polyamine is acidified p...
01/31/1995
5359141Process for the production of polynuclear aromatic polyamines
The invention relates to an improved process for the production of polynuclear aromatic polyamines by condensation of aniline with formaldehyde in the presence of water and acidic catalysts and working up of the reaction mixture by extraction with a hydro...
10/25/1994
5312989Method for the purification of 4,4'-diamino-diphenylmethane
A method of purifying 4,4'-diaminodiphenylmethane comprising partially melting a crystal of crude 4,4'-diaminodiphenylmethane and removing a melt to obtain a high purity 4,4'-diaminodiphenylmethane. By utilizing the method, a high purity 4,4'-diaminodiphe...
05/17/1994
5296612Process for producing enyne derivatives
A process for producing an enyne derivative, and intermediate, which is useful for preparing compounds showing strong inhibiting activities against squalane epoxidase of Eumycetes and strong anti-cholesterol activities. The process comprises reacting a co...
03/22/1994
5286760Process for reducing impurity levels in methylene diphenyamines
Disclosed herein is a process for preparing a reaction product containing methylene diphenylamine comprising reacting aniline with an aldehyde, in the presence of a low level of an acid wherein the acid level is reduced before digesting reaction mixture a...
02/15/1994
5208379Hydrolysis of polyurethanes
Waste or scrap polyurethane may be conveniently and economically converted to useful active-hydrogen containing polyethers and polyamines by contacting the polyurethane with water, strong base, and an activating agent such as a quaternary ammonium compoun...
05/04/1993
5196591Process for the production of polynuclear aromatic polyamines
The invention relates to an improved process for the production of polynuclear aromatic polyamines by condensation of aniline with formaldehyde in the presence of water and acidic catalysts and working up of the reaction mixture by extraction with a hydro...
03/23/1993
5072045Process for the catalytic alkenylation of arylamines with conjugated dienes
The invention relates to an improved process for producing alkenylated aromatic amines which involves the catalytic reaction of an aromatic amine with a diene. The improvement resides in using a solvent in which the aromatic amine and diene are soluble in...
12/10/1991
5047591Single-stage process for producing bis-(amino-nitrophenyl)-methane
Bis-(amino-nitrophenyl)-methane can be produced in one stage with an approximately quantitative yield by condensing o-nitraniline and formaldehyde in water at a temperature of between 20° and 40° C. in the presence of sulfuric acid, and subsequently ...
09/10/1991
4924028Process for the production of polynuclear aromatic polyamines
This invention relates to an improved process for the preparation of polynuclear aromatic polyamines in which the reaction product is prepared by condensing aniline with formaldehyde in the presence of water and acidic catalysts and is worked up by extrac...
05/08/1990
4914236Process for the preparation of multinuclear aromatic polyamines
The present invention relates to an improved process for the preparation of multinuclear aromatic polyamines by the condensation of aniline with formaldehyde in the presence of water and acid catalysts and working up of the reaction mixture by extraction ...
04/03/1990
4798909Process for recovery of polyarylpolyamines
An arylamine such as aniline is condensed with formaldehyde in the presence of aqueous hydrochloric acid to form a mass containing the hydrogen chloride salt of a polyarylpolyamine. The mass is contacted with additional aniline thereby forming an organic ...
01/17/1989
4654443Hydrolysis of isocyanate distillation bottoms
Liquid distillation residue formed in the phosgenation of polyamines to form polyisocyanates are hydrolyzed to reform the polyamine. The process comprises forming an adduct of the distillation residue with additional polyamine and then hydrolyzing the res...
03/31/1987
4507475Process for purification of crude polyether polyols
A process for purifying crude polyether polyols which are prepared by anionic polymerization of alkylene oxides in the presence of basic catalysts. The polyols are mixed with water and ortho-phosphoric acid in certain quantity ratios, an adsorption agent ...
03/26/1985
4297511Method for the manufacture of polyarylamines having methylene bridges
Through condensation ortho- and para-isomers of methylene dianiline (MDA) as well as PMPPA are produced as condensation products from arylamines, especially from aniline, and formaldehyde in the presence of acid catalysts, in which at least one component ...
10/27/1981
4294987Process for preparing methylene dianilines
An improvement is described in the process of preparing polymethylene polyphenyl polyamines by condensing aniline and formaldehyde in the presence of an acid catalyst in the initial condensation. The improvement enables the amount of acid which has to be ...
10/13/1981
4281197Hydrolytic decomposition method
Porous polyurethane solids such as open cell polyurethane foams are rapidly heated and hydrolytically decomposed into separate polyol component and diamine component by contacting the porous solids with saturated steam in a heated vacuum chamber. Separati...
07/28/1981
4250114Process for the recovery of polyarylpolyamines
An arylamine such as aniline is condensed with formaldehyde in the presence of aqueous hydrochloric acid to form a mass containing the hydrogen chloride salt of a polyarylpolyamine. The mass is contacted with additional aniline thereby forming an organic ...
02/10/1981
4201722Process for separating 4,4'-diaminodiphenylmethane
A process is described for the isolation of 4,4'-diaminodiphenylmethane in substantially pure form (of the order of 99% purity) from admixtures thereof with the corresponding 2,4'-isomer and 2,2'-isomer. The dihydrochloride of the isomeric mixture of diam...
05/06/1980
4172847Treatment of methylene-bridged polyphenylpolyamime mixtures
A process for treating methylene-bridged polyphenylpolyamine mixtures prepared by the silica-alumina catalyzed condensation reaction of aniline and formaldehyde to obtain substantially pure low functionality Diaminodiphenylmethanes having increased 4,4'-p...
10/30/1979
4130588Process for producing methylene dianiline
A process for producing polyamines such as methylene dianiline wherein an aromatic amine such as aniline is reacted with formaldehyde in the presence of an acid catalyst sufficient water is employed to cause a separation into an aqueous phase and an organ...
12/19/1978
4034039Purification of methylenedianilines
A process is described for the isolation of 4,4'-diaminodiphenylmethane in substantially pure form (of the order of purity of at least 95%) from admixtures thereof with the corresponding 2,4'-isomer and 2,2'-isomer. The isomeric mixture of diamines is hea...
07/05/1977
4029879Process for the removal of catalysts from polyether polyols employing water and adsorbent
An improvement in the process of catalyst removal in the preparation of polyether polyols is achieved by adding a critical amount of water from about 1 to about 5 percent by weight based on the weight of polyol to an adsorbent synthetic magnesium silicate...
06/14/1977
4029705Purification process for MDA
A process is described for the selective removal of 2,2'- and 2,4'-diaminodiphenylmethanes from mixtures containing 2,2'-, 2,4'- and 4,4'-diaminodiphenylmethanes and polyamines by heating these mixtures in the presence of aqueous hydrochloric acid (55 to ...
06/14/1977
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