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Class 562/486 - By crystallization


Subclass of Class 562 - Organic compounds -- part of the class 532-570 series
Definition: Processes wherein the purification or recovery involves
No. of patents: 137
Last issue date: 04/06/2010


1        
NumberTitleIssue Date
7692039Process for preparing purified terephthalic acid
The present invention relates to a process for preparing purified terephthalic acid [PTA,], comprising the steps: dissolving crude terephthalic acid [CTA] in an aqueous medium in a reactor; hydrogenating CTA at a temperature of about 260-320° C. and a pressure of a...
04/06/2010
7381386Extraction process for removal of impurities from mother liquor in the synthesis of carboxylic acid
A method for removing impurities from a mother liquor comprising a carboxylic acid, a metal catalyst, impurities by (a) evaporating the mother liquor comprising a carboxylic acid, a metal catalyst, impurities and a solvent in a first evaporator zone to produce a vap...
06/03/2008
7358392Process for the oxidative purification of terephthalic acid
Disclosed is a process to produce a purified carboxylic acid slurry. The process comprises removing impurities from a crystallized product in a solid liquid displacement zone to form the purified carboxylic acid slurry. The process produces purified carboxylic acid ...
04/15/2008
7358414Para-xylene process using perm-selective separations
Processes and apparatus are disclosed for recovery of purified products from a fluid mixture by means of integrated perm-selective separations with purified product recovery operations. More particularly, integrated processes of the invention comprise separations by...
04/15/2008
7355071Method for preparing 2,6-naphthalene dicarboxylic acid
Disclosed is an improved method for preparing 2,6-naphthalene dicarboxylic acid from di-lower alkyl 2,6-naphthalene dicarboxylate, which is characterized in that hydrolyzing di-lower alkyl 2,6-naphthalene dicarboxylate in a specified amount of water in the presence ...
04/08/2008
7351396Extraction process for removal of impurities from an aqueous mixture
A method for removing impurities from an aqueous mixture or purified aqueous by extracting the aqueous mixture or purified aqueous mixture with an extraction solvent in an extraction zone to form an extract stream and the raffinate stream; and optionally separating ...
04/01/2008
7342128Method for oxidizing a slurry composition in a post oxidation zone in the presence of added steam
The present invention relates to a process for oxidizing a slurry composition in a post oxidation zone in the presence of added steam. More specifically, the present invention relates to a process for oxidizing a crude terephthalic acid composition in a post oxidati...
03/11/2008
7307188Purification of carboxylic acids by complexation with selective solvents
A method and apparatus for purifying carboxylic acids is disclosed. A mixture containing crude carboxylic acid is contacted with a selective crystallization solvent to form a slurry of a salt complex of the carboxylic acid and the selective crystallization solvent. ...
12/11/2007
7291270Process for removal of impurities from an oxidizer purge stream
A process is disclosed that relates to the removal of impurities and the recovery of a mother liquor and wash filtrate from an oxidizer purge stream produced in the synthesis of carboxylic acid, typically terephthalic. More particularly, the process involves the rem...
11/06/2007
7282151Process for removal of impurities from mother liquor in the synthesis of carboxylic acid using pressure filtration
A process is disclosed that relates to the recovery of a metal catalyst from an oxidizer purge stream produced in the synthesis of carboxylic acid, typically terephthalic. More particularly, the process involves recovery of a metal catalyst from an oxidizer purge st...
10/16/2007
7273559Process for removal of impurities from an oxidizer purge stream
A process is disclosed that relates to the removal of impurities and the recovery of a mother liquor and wash filtrate from an oxidizer purge stream produced in the synthesis of carboxylic acid, typically terephthalic. More particularly, the process involves the rem...
09/25/2007
7238833Production of aromatic carboxylic acids
A process for the production of an aromatic carboxylic acid comprising contacting in the presence of a catalyst, within a continuous flow reactor, one or more precursors of the aromatic carboxylic acid with an oxidant, such contact being effected with said precursor...
07/03/2007
7196215Process for the production of purified terephthalic acid
Disclosed is a process for the production of terephthalic acid by a plurality of process steps including the catalyst oxidation of a dialkylbenzene compound, a second oxidation, a hydrogenation of the product of the second oxidation, and crystallization of the hydro...
03/27/2007
7173150Process for recovering terephthalic acid from pulverized product of spent polyethylene terephthalate and system for use in such process
This invention provides a process a process for recovering terephthalic acid from pulverized products of spent polyethylene terephthalate. This process comprises (1) a decomposition reaction step where the pulverized products of spent polyethylene terephthalate are ...
02/06/2007
7161027Process for the oxidative purification of terephthalic acid
Disclosed is a process to produce a purified carboxylic acid slurry. The process comprises removing impurities from a crystallized product in a solid liquid displacement zone to form the purified carboxylic acid slurry. The purified carboxylic acid slurry is further...
01/09/2007
7153998Method for refining 2,6-naphthalene dicarboxylic acid
The present invention relates to a method for refining 2,6-naphthalene dicarboxylic acid, and particularly to a method for refining 2,6-naphthalene dicarboxylic acid comprising recrystallizing crude 2,6-naphthalene dicarboxylic acid in the form of an amine salt usin...
12/26/2006
7132566Process for the purification of a crude carboxylic acid slurry
Disclosed is a process to produce a purified carboxylic acid product. The process comprises removing impurities from a crude carboxylic acid slurry in a solid-liquid displacement zone to form a slurry product. The slurry product if further treated in a staged oxidat...
11/07/2006
7102029Method of crystallization
The present invention proposes a crystallization process comprising the steps of feeding a slurry solution in which a terephthalic acid solution or a part of the terephthalic acid is precipitated to a crystallization vessel, precipitating the terephthalic acid in th...
09/05/2006
7074954Process for the oxidative purification of terephthalic acid
Disclosed is a process to produce a purified carboxylic acid slurry. The process comprises removing impurities from a crystallized product in a solid liquid displacement zone to form the purified carboxylic acid slurry. The process produces purified carboxylic acid ...
07/11/2006
7005540Method of purifying aromatic polycarboxylic acid
Crude polycarboxylic acid is slurried in an aqueous medium and the slurry is brought into contact with a metal catalyst while preventing catalyst components thereof from contaminating crystals. Since hydrogenation or decarbonylation of a polymerization inhibitory su...
02/28/2006
6992037Precious metal catalyst for debenzylation
One aspect of the invention relates to catalyst composite containing a metal catalyst and a specifically defined carbon support containing a carbonaceous material. For example, the carbon support may have a total pore surface area of about 800 m2/g or mor...
01/31/2006
6855845Process for the preparing bromoisophithalic acid compound
The present invention relates to a process for preparing bromoisophthalic acid compounds, particularly 5-bromoisophthalic acid compounds and 4,5-dibromoisophthalic acid compounds comprising brominating an isophthalic acid compound of the general formula (1)
02/15/2005
6765113Production of aromatic carboxylic acids
A process for the production of an aromatic carboxylic acid comprising contacting in the presence of a catalyst, within a continuous flow reactor, one or more precursors of the aromatic carboxylic acid with an oxidant, such contact being effected with said precursor...
07/20/2004
6756509Method for purifying crude 2,6-naphthalenedicarboxylic acid
A method for purifying crude 2,6-naphthalenedicarboxylic acid includes a reduction step of reducing crude 2,6-naphthalenedicarboxylic acid containing 6-formyl-2-naphthoic acid with hydrogen and a cleaning step of cleaning the reduction product with alcohol. Preferab...
06/29/2004
6723873Production of terephthalic acid and ethylene glycol from polyethlene terephthalate by ammoniolysis
A process for forming reactants useful in the manufacture of polyethylene terephthalate includes the steps of: (a) contacting recyclable polyethylene terephthalate with ammonium hydroxide whereby a mixture of ammonium terephthalate and ethylene glycol is formed, (b)...
04/20/2004
6720448Method of recovering chemical species by depolymerization of poly (ethylene terephthalate) and related use
The present invention relates to a method of recovering a solution comprising the chemical species obtained by depolymerization of PET from a material containing poly(ethylene terephthalate) in the form of bottles, by making said material react, in the absence of wa...
04/13/2004
6717009Method for making high-purity naphthalenedicarboxylic acid
A high-purity naphthalenedicarboxylic acid is produced by a method including Steps [1] and [2]: In Step [I], a raw mixture of crude terephthalic acid and crude naphthalenedicarboxylic acid is dissolved into high-temperature high-pressure water to form a dibasic acid...
04/06/2004
6689903Crystallization method for production of purified aromatic dicarboxylic acids
Disclosed is a method for the recovery of crystalline terephthalic acid containing less than about 150 ppmw p-toluic acid by subjecting a solution of terephthalic acid containing minor amounts of p-toluic acid to crystallization in a crystallization zone ...
02/10/2004
6670503Method for recovery of terephthalic acid from a material containing poly(ethylene terephthalates)
The present invention relates to a method of recovering terephthalic acid from a material containing poly(ethylene terephthalate) (P.E.T.) in the form of bottles, by making said material react, in the absence of water, with a reagent consisting of one or ...
12/30/2003
6639104Process for the recovery of purified terephthalic acid (PTA)
A process for the preparation of purified terephthalic acid which comprises first introducing a liquid slurry containing crystalized terephthalic acid with impurities into a high pressure rotary filter, then filtering the slurry with the high pressure rot...
10/28/2003
6580005Process for recovering terephthalic acid from pulverized product of spent polyethylene terephthalate and system for use in such process
This invention provides a process a process for recovering terephthalic acid from pulverized products of spent polyethylene terephthalate. This process comprises (1) a decomposition reaction step where the pulverized products of spent polyethylene terepht...
06/17/2003
6579990Process for producing refined pyromellitic acid and refined pyromellitic anhydride
A process for refined pyromellitic anhydride which comprises dissolving crude pyromellitic acid or crude pyromellitic anhydride in water, then cooling an aqueous solution thus obtained to perform crystallization as pyromellitic acid, then separating a cry...
06/17/2003
6534677Non-crushable, non-friable, non-breakable carbon catalyst supports
The present invention provides a carbon-containing catalyst support that includes at least a carbonaceous material nd a thermosetting or sinterable polymer. The components are mixed and the polymer sintered or thermoset to provide a non-crushable, non-fri...
03/18/2003
6461700Aromatic acid monomers, polymers, products and processes for their manufacture
Processes for producing aromatic monomers useful for forming polyesters are disclosed. Cost effective steps employed in the processes permit small amounts of process-related materials typically removed from monomer to remain in an aromatic monomer product...
10/08/2002
6455731Process for producing a high purity aromatic polycarboxylic acid
A process for producing a high purity aromatic polycarboxylic acid by purify a crude aromatic polycarboxylic acid in accordance with the steps of (I) forming an amine salt of an aromatic polycarboxylic acid from the crude polycarboxylic acid and an amine,...
09/24/2002
6452047Process for producing highly pure aromatic polycarboxylic acid
Highly pure, less colored aromatic polycarboxylic acids are produced from crude aromatic polycarboxylic acids by simple procedures at low production costs. The crude aromatic polycarboxylic acid is mixed with aliphatic amine or alicyclic amine in the pres...
09/17/2002
6441225Purification of aromatic diacids
A method is provided to produce dicarboxylic or tricarboxylic aromatic acid from salts of such acids, the method including the steps of providing an aqueous solution of a salt of a dicarboxylic or tricarboxylic aromatic acid, the aqueous solution having a...
08/27/2002
6426430Method for reduction of potassium in an integrated process for the production of 2,6--NDA
Disclosed is a method for reducing alkali metals in aromatic dicarboxylic acids produced by disproportionation or rearrangement of an alkali salt of a mono- or dicarboxylic acid to levels acceptable for polymerization which comprises: a) Washing the aroma...
07/30/2002
6407286Process for recovering hydrogen in producing pure terephthalic acid
A method for recovering and recycling excess hydrogen from process vent streams in the production of highly pure terephthalic acid where the production of the pure terephthalic acid comprises catalytically hydrogenating impure terephthalic acid, which typ...
06/18/2002
6392091Process of purifying and producing high purity aromatic polycarboxylic acids
The present invention provides a solvent extraction purification method for aromatic polycarboxylic acids that meet or exceed polymer-grade specification. The method includes dissolving a crude aromatic polycarboxylic acid in a base compound; removing imp...
05/21/2002
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