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Class 562/423 - Preparation by carbonation


Subclass of Class 562 - Organic compounds -- part of the class 532-570 series
Definition: Processes wherein an aromatic carboxylic acid is produced
No. of patents: 42
Last issue date: 10/07/2008


1    
NumberTitleIssue Date
7432390Production of carboxylic acids or carboxylic acid esters
In the production of carboxylic acid or carboxylic acid ester, a reaction product containing the carboxylic acid or carboxylic acid ester which has been produced by the reaction of an olefin, carbon monoxide, and water or an alcohol in the presence of HF is heat-tre...
10/07/2008
7214830Process for the preparation of acylphosphines, acyl oxides and acyl sulfides
A description is given of processes for the preparation of mono- and bisacylphosphines and of mono- and bisacylphosphine oxides and mono- and bisacylphosphine sulfides, which comprises first reacting organic P-monohalogenophosphines or P,P-dihalogenophosphines, or m...
05/08/2007
7135428Catalyst solution for implementing anionic lactam polymerization, method for production thereof and polyamide moulding compound
A catalyst solution for the anionic polymerization of lactones and/or lactams comprises a salt of at least one compound of the general formula I In this formula (I), R1 is H or an aliphatic, cycloaliph...
11/14/2006
7094931Process for the preparation of acylphosphines, acyl oxides and acyl sulfides
A description is given of processes for the preparation of mono- and bisacylphosphines and of mono- and bisacylphosphine oxides and mono- and bisacylphosphine sulfides, which comprises first reacting organic P-monohalogenophosphines or P,P-dihalogenophosphines, or m...
08/22/2006
6562999Process for separation of crude naphthalene dicarboxylic acid using reverse osmosis
Disclosed is a process for purifying 2,6-naphthalene dicarboxylic acid produced by disproportionation and more efficiently recycling byproduct dipotassium salts which includes the steps of: a) Contacting an aqueous solution containing the disalt of 2,6-ND...
05/13/2003
6441224Process for carboxylation of naphthoic acid to naphthalene dicarboxylic acid
Disclosed is a method for selective carboxylation of naphthoic acid, or other aromatic mono-acids to form primarily 2,3-naphthalene dicarboxylic acid (2,3-NDA) or other aromatic diacids which comprises reacting said aromatic mono-acid in the presence of o...
08/27/2002
6350904Method for producing ortho-alkylated benzoic acid derivatives
The invention relates to a process for the preparation of ortho-alkylated benzoic acid derivatives of the formula I ##STR1## characterized in that an aryl bromide of the formula II ##STR2## is reacted with a secondary or tertiary organolithium compound an...
02/26/2002
6348624Process for making certain benzoic acid compounds
The subject invention involves processes for making 2,4-difluoro-3-Q1-benzoic acid, wherein Q1 is derived from an electrophilic reagent, comprising the steps of: (a) treating 1-bromo-2,4-difluorobenzene with a strong, non-nucleophilic base; then trea...
02/19/2002
6107516Production of aromatic hydroxycarboxylic acids
A process for the production of aromatic hydroxycarboxylic acids such as salicylic acid comprising contacting an aromatic hydroxy compound such as phenol with carbon dioxide in the presence of fluoride ion. The products are useful as pharmaceuticals and c...
08/22/2000
6040478Process for dicarboxylating dihydric phenols
A process is disclosed for dicarboxylating dihydric phenols, notably those where the hydroxyl groups are in the para or the ortho position vis-a-vis one another. More particularly, the invention pertains to a process for preparing 2,5-dihydroxyterephthali...
03/21/2000
5616787Process for the preparation of alkylated aromatic carboxylic acids and acyl halides
The invention relates to a process for the preparation of polyalkylated aromatic carboxylic acids of formula I ##STR1## wherein R1, R2, R3, R4 and R5 are each independently of one another hydroge...
04/01/1997
5312975Process for the preparation of 5-(2,4-difluorophenyl)-salicylic acid
A process for the preparation of 5-(2,4-difluorophenyl)-salicylic acid comprising the reaction of an organometallic derivative with a suitable substituted benzene in the presence of a transition-metal based catalyst is described....
05/17/1994
5210322Processes for the preparation of ethers
A process for preparing ethers which comprises contacting a carboxylated ether with a metal oxide catalyst under conditions effective to produce the ether....
05/11/1993
5189205Process for preparing isocyanates
A process for preparing isocyanates comprising (a) contacting carbon dioxide and a primary amine in the presence of an aprotic organic solvent and an organic, nitrogenous base to produce the corresponding ammonium carbamate salt, and (b) reacting the ammo...
02/23/1993
51839342-trifluoromethyl-4-hydroxybenzoic acid
Disclosed is a novel compound 2-trifluoromethyl-4-hydroxybenzoic acid represented by the formula: ##STR1##...
02/02/1993
5072036Process for preparing para-hydroxybenzoic acid
Para-hydroxybenzoic acid is prepared by reacting an alkali metal salt of phenol except the lithium and sodium salts with carbon dioxide in the presence of at least one compound selected from compounds of the following formulae (I) and (II): ##STR1## ...
12/10/1991
4996354Preparation of 2,4-dihydroxybenzoic acid
2,4-Dihydroxybenzoic acid is prepared in a solids mixer by reacting resorcinol with an alkali metal bicarbonate and/or alklai metal carbonate in a carbon dioxide atmosphere using as the alkali metal bicarbonate or alkali metal carbonate a mixture of the c...
02/26/1991
4942257Method of manufacturing alkali metal salt of 2,3,6,7-naphthalenetetracarboxylic acid
A method of manufacturing an alkali metal salt of 2,3,6,7-naphthalenetetracarboxylic acid. Either a sodium salt or a mixture of sodium salt and potassium salt of at least one naphthalenecarboxylic acid selected form the group consisting of naphthoic acids...
07/17/1990
4853414Halogenated esters
Compounds of formula (I), useful as insecticides and knockdown agents: ##STR1## where Y is C1-6 alkoxy, Z is halo or C1-6 alkoxy; R is --(CH2)p --(O)m --R3 where m and p may be 0 or 1; ...
08/01/1989
4845276Preparation of dialkoxybenzoic acid
2,6-dialkoxybenzoic acid is made by metalation of 1,3-dialkoxybenzene by reaction with potassium dialkylamide. The metalated dialkoxybenzene is carbonated and acidified to form the dialkoxybenzoic acid....
07/04/1989
4845277Method of preparing dialkoxybenzoic acid
2,6-dialkoxybenzoic acid is made by direct metalation of 1,3-dialkoxybenzene by potassium. The metalated dialkoxybenzene is carbonated and acidified to form the dialkoxybenzoic acid....
07/04/1989
4820868Process for preparation of naphthalene-2,6-dicarboxylic acid dialkali metal salts
Disclosed is a process for the preparation of a naphthalene-2,6-dicarboxylic acid dialkali metal salt which comprises heating an alkali metal salt of naphthoic acid and/or a dialkali metal salt of naphthalene-dicarboxylic acid under pressure with carbon d...
04/11/1989
4780567Process for producing aromatic hydroxycarboxylic acids
This invention provides a process for selectively producing aromatic hydroxycarboxylic acids, which comprises subjecting a liquid mixture consisting of a polycyclic aromatic hydrocarbon, an alkali metal salt of an aromatic hydroxy compound and a free arom...
10/25/1988
4730083Process for the preparation of 3,5-dialkyl-4-hydroxy benzoic acid
An improved process for the preparation of 3,5-dialkyl-4-hydroxybenzoic acid comprising the reaction of 2,6-dialkylphenol and carbon dioxide in the presence of a mono- or polyalkylene glycol ether....
03/08/1988
4697037Preparation of dibenzo[b,f]thiepin compounds
The preparation of dibenzo[b,f]thiepin compounds by a process comprising the direct carboxylation of an ortho-toluyl-aryl sulfide to introduce a phenylacetic acid side chain is disclosed....
09/29/1987
4658054Process for the preparation of 5,6-dialkoxyanthranilic acids
A process for the preparation of 5,6-dialkoxyanthranilic acids is described. The 5,6-dialkoxyanthranilic acids are useful in the preparation of substituted quinazolinediones which are active cardiotonic agents....
04/14/1987
4564700Process for the preparation of fluorene-9-carboxylic acid
An improved process for the preparation of fluorene-9-carboxylic acid comprising reacting fluorene and a dialkyl carbonate with alkyls of 1 to 5 carbon atoms in the presence of a member of the group consisting of alkali metal hydrides or potassium alcohol...
01/14/1986
4533500Process for manufacturing N-acyliminodiacetic acids
N-acyliminodiacetic acids are manufactured by reacting formaldehyde or a formaldehyde generator compound with a N-unsubstituted amide or a generator thereof and with carbon monoxide in contact with a carbonylation catalyst, for example, a cobalt compound,...
08/06/1985
4529817Process for preparing aromatic hydroxycarboxylic acids
Aromatic hydroxycarboxylic acids are prepared by reacting an alkali metal salt of an aromatic hydroxy compound in solid phase with carbon dioxide, by reacting an alkali metal salt of an aromatic hydroxy compound in the form of granules in a fluidized bed ...
07/16/1985
4518799Processes for the preparation of hydratropic acids
Novel processes for making arylpropionic acids are described. One process comprises carboxylating particular Grignard compounds which are the products of a catalyzed reaction between corresponding arylmagnesium bromides and ethylene. Furthermore, the reac...
05/21/1985
4508920Process for the preparation of aromatic hydroxycarboxylic acids
Aromatic hydroxycarboxylic acids are prepared by reacting alkali metal salts of aromatic hydroxy compounds in the solid phase with carbon dioxide in a process in which the alkali metal salt of the aromatic hydroxy compound is reacted at temperatures of 12...
04/02/1985
4405640Substituted fluorobenzyl cyclopropane carboxylates useful as insecticides
Insecticides of the formula ##STR1## wherein R1 and R2 are each selected from methyl, halomethyl, and halo; X is oxygen, sulphur, sulphonyl or a group NR4 where R4 represents hydrogen, lower alkyl or lower ...
09/20/1983
4345094Process for the production of 6-hydroxy-2-naphthoic acid
The production of 6-hydroxy-2-naphthoic acid from anhydrous potassium 2-naphthoxide and carbon dioxide is improved by forming a mixture of 0.8-1.2 moles of 2-hydroxynaphthalene per equivalent of potassium base, dehydrating the mixture, adding carbon dioxi...
08/17/1982
4345095Process for the production of 6-hydroxy-2-naphthoic acid
The production of 6-hydroxy-2-naphthoic acid from anhydrous potassium 2-naphthoxide and carbon dioxide is improved by forming a mixture of 0.8-1.45 moles of 2-hydroxynaphthalene per equivalent of potassium base, dehydrating the mixture, adding carbon diox...
08/17/1982
4287357Process for the production of 6-hydroxy-2-naphthoic acid
The production of 6-hydroxy-2-naphthoic acid from anhydrous potassium 2-naphthoxide and carbon dioxide is improved by forming a mixture of 0.8-1.2 moles of 2-hydroxynaphthalene per equivalent of potassium base, dehydrating the mixture, adding carbon dioxi...
09/01/1981
4242524Process for the preparation of 2-(4'-nitrophenyl)-propionic acid
The present invention concerns a process for the preparation of 2-(4'-nitrophenyl)-propionic acid of the formula (I): ##STR1## More particularly, this invention relates to a process for the preparation of 2-(4'-nitrophenyl)-propionic acid (I) startin...
12/30/1980
4239913Process for preparing 2-hydroxynaphthalenecarboxylic acids
A process for preparing 2-hydroxynaphthalenecarboxylic acids which comprises reacting a liquid mixture of 1 mole of an alkali ଲ-naphtholate, 0.05 to 3 moles of ଲ-naphthol, and 0.1 to 5 times the weight of the alkali ଲ-naphtholate of ligh...
12/16/1980
4232172Process for the preparation of 3,6-dichloro-salicyclic
An improved process for the preparation of 3,6-dichlorosalicylic acid by carboxylation of potassium 2,5-dichlorophenolate with carbon dioxide in xylene at elevated pressure, where the improvement consists of adding finely powdered, anhydrous potassium car...
11/04/1980
4132732Process for preparing alpha-formyl acids
Alpha-formyl acids are prepared by carboxylation of aldehydes in the presence of unsubstituted or substituted alkaline phenates, and of aprotic organic solvents....
01/02/1979
4084061Process for producing benzyl sodium, phenylacetic acid and derivative thereof
Phenylacetic acid is produced by reacting chlorotoluene with sodium to form tolylsodium, rearranging the product to benzyl sodium and then reacting the benzyl sodium with a carboxylating agent....
04/11/1978
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