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| Number | Title | Issue Date |
| 8101537 | Prepolymerized catalyst for olefin polymerization, method of producing this prepolymerized catalyst and method of producing olefin polymer A method of producing a prepolymerized catalyst for olefin polymerization comprising a fine powder removal step of removing fine particles from olefin-prepolymerized catalyst particles for olefin polymerization. The prepolymerized catalyst having a low fine particle... | 01/24/2012 |
| 7354880 | Catalyst composition and methods for its preparation and use in a polymerization process The present invention relates to a catalyst composition and a method for making the catalyst composition of a polymerization catalyst and a carboxylate metal salt. The invention is also directed to the use of the catalyst composition in the polymerization of olefin(... | 04/08/2008 |
| 7341971 | Production of olefin polymerization catalysts The invention provides a process for producing an olefin polymerization catalyst, comprising an organometallic compound of a transition metal or of an actinide or lanthanide, in the form of solid catalyst particles, comprising forming a liquid/liquid emulsion system... | 03/11/2008 |
| 7271119 | Process for preparing an olefin polymerization catalyst component Process for preparing an olefin polymerisation catalyst component in the form of particles having a predetermined size range, said process comprising the steps of a) preparing a solution of a complex of a Group 2 metal and an electron donor by reacting a compound of... | 09/18/2007 |
| 7232551 | Fluidized bed method and reactor for the treatment of catalysts and catalyst carriers A method for the treatment of catalysts or catalyst carriers by: a) introducing and distributing a gas in the lower section of a reactor containing a catalyst or catalyst carrier bulk material; b) forming a fluidized bed in the reactor; c) treating the particles in ... | 06/19/2007 |
| 7199077 | Fischer-tropsch catalyst prepared with a high purity iron precursor A Fischer-Tropsch catalyst comprising iron and at least one promoter is prepared via a method which comprises the preparation of a high purity iron precursor and which uses a nominal amount of water in the catalyst production. The catalyst particles prepared with th... | 04/03/2007 |
| 7067451 | Soluble magnesium complexes useful for the production of polyolefin catalysts and catalysts prepared therewith A method of forming a polyolefin catalyst component includes halogenating metal complexes. The metal complexes result from reacting a metal alkoxide with an alcohol-ether. A particular non-limiting example is a magnesium complex formed by reacting magnesium alkoxide... | 06/27/2006 |
| 7057010 | Process for the continuous drying of polymers containing N or amino, ammonium or spirobicyclic ammonium groups Process for the drying of polymers containing N or amino, ammonium or spirobicyclic ammonium groups, comprising cationic N-containing groups, and suitable counterions, in which the gelled and washed polymers obtained by polymerization, crosslinkage and optionally al... | 06/06/2006 |
| 7008898 | Method for producing a poly-1-olefin in the presence of a ziegler catalyst The invention relates to a method for producing a poly-1-olefin by polymerisation of a 1-olefin of the formula R4CH═CH2, in which R4 is hydrogen or an alkyl radical having from 1 to 10 carbon atoms, in suspension, in solution or in... | 03/07/2006 |
| 7009015 | Alpha-olefin polymerization catalyst system which contains an aromatic silane compound Aromatic silane compounds containing at least an aromatic ring bound directly to the silicon atom, wherein the aromatic ring has at least one substituent located in the ortho position selected from C1-10 hydrocarbon groups, are useful as electron donors i... | 03/07/2006 |
| 6977235 | Catalyst systems comprising a calcined chromium catalyst and a non-transition metal cyclopentadienyl cocatalyst According to an embodiment, catalyst systems for polymerizing olefins include a catalyst comprising chromium and a cocatalyst comprising a substituted or unsubstituted non-transition metal cyclopentadienyl compound (Cp). The catalyst also comprises an inorganic oxid... | 12/20/2005 |
| 6969747 | Olefin polymerization titanium catalyst An olefin polymerization titanium catalyst. It comprises a titanium compound and an organoaluminium compound cocatalyst supported on a soluble polysulfone comprising free reactive sulfone groups. The molar ratio of titanium of aluminum is 1–10:200 and the weight r... | 11/29/2005 |
| 6946420 | Coordination catalyst systems employing chromium support-agglomerate and method of their preparation The present invention is directed to a coordinating catalyst system comprising at least one pre-catalyst selected from late transition metal bidentate or tridentate ligand containing compounds, at least one support-agglomerate having chromium immobilized thereto (e.... | 09/20/2005 |
| 6943224 | Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby A process for forming a coordination catalyst system comprising sequentially or substantially simultaneously contacting: (I) pre-catalyst reactants comprising (a) at least one first ligand-containing reactant; and (b) at least one first transition metal reactant sui... | 09/13/2005 |
| 6927261 | Method of making supported transition metal polymerization catalysts and compositions formed therefrom The present invention is directed to a novel one-step method for forming a supported catalyst complex of high activity by substantially simultaneously contacting a bidentate or tridentate ligand forming compound, a transition metal compound and a Lewis acid support-... | 08/09/2005 |
| 6887817 | Olefin polymerization catalyst and process for preparing polyolefins using said catalyst An olefin polymerization catalyst is described which includes: (A) a solid catalyst component being prepared by copulverizing a magnesium compound, an aluminum compound, an electron donor and a titanium compound, and (B) an organoaluminum compound. The present inven... | 05/03/2005 |
| 6755364 | Methods and apparatus for mechanical treatment of materials such as catalysts Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fraction... | 06/29/2004 |
| 6649731 | Catalysts for polyester production, process for producing polyester, and polyester By the present invention, there are provided a catalyst for polyester preparation, which comprises a solid titanium compound containing titanium, oxygen, carbon and hydrogen and having a Ti--O bond and which has a maximum solubility in ethylene glycol, as... | 11/18/2003 |
| 6639043 | Azonaphthalene sulfonates as polymerization catalysts The present invention relates to a synthetic method comprising contacting at least one diaryl carbonate with one or more dihydroxy aromatic compounds in the presence of a transesterification catalyst under melt polymerization conditions to afford a produc... | 10/28/2003 |
| 6600011 | Process for purification and drying of polymer hydrogels This invention relates to a method for purifying and drying a polymer hydrogel. This invention is based in part upon the discovery that rapid drying of polymer hydrogels can eliminate the problem of unacceptable levels of soluble oligomers caused by prolo... | 07/29/2003 |
| 6468936 | Solid MAO/metallocene catalyst complex for propylene polymerization The catalyst is a mixture of metallocene catalyst component of the general formula: R"b (CpR4)(CpR'4)MR*v-2 where R" is a bridge imparting stereorigidity to the structure to the metallocene by connecting the two cycl... | 10/22/2002 |
| 6420304 | Polymer-supported carbonylation catalyst and its use The invention relates to a polymer-supported carbonylation catalyst and its use in a process for preparing organic carboxylic acid or anhydride having n+1 carbon atoms. The invention relates also to a process for preparing organic carboxylic acid or anhyd... | 07/16/2002 |
| 6417320 | Catalyst and method for its production and use The production of linear polyester by the interchange of ester radicals or esterification and polycondensation of multivalent alcohols with multivalent carboxylic acids takes place by means of catalysts. In order that the catalyst features the lowest poss... | 07/09/2002 |
| 6403519 | Process for the preparation of a catalyst for the polymerization of alpha-olefins, catalyst obtained and polymerization process using such a catalyst Process for the preparation of a catalyst for the polymerization of alpha-olefins involves contacting a porous polyolefin support with a solution containing an activator (ii) to form a suspension. The suspension is evaporated in a reactor fitted with a st... | 06/11/2002 |
| 6384159 | Production of polyethylene with a titanium amide catalyst The present invention relates to a process to produce polyethylene through homopolymerization or copolymerization of ethylene with alpha-olefins in the presence of a titanium amide catalyst supported by an organic polymer material, for the production of m... | 05/07/2002 |
| 6358381 | Rhodium electrocatalyst and method of preparation The invention relates to a novel rhodium sulfide catalyst for the reduction of oxygen in industrial electrolyzers. The catalyst is highly resistant towards corrosion and poisoning by organic species, thus resulting particularly suitable for use in aqueous... | 03/19/2002 |
| 6300273 | Catalysts for the (co)polymerization of ethylene The present invention relates to catalysts for the polymerization of ethylene and its mixtures with olefins CH.sub.2.dbd.CHR.sup.VIII, comprising the reaction product of a solid catalyst component containing Ti, Mg and halogen, an alkyl-Al compound and a ... | 10/09/2001 |
| 6153553 | Process for the polymerization of alpha olefins using a new aluminophosphate support Novel catalysts are provided for the polymerization of olefins such as ethylene. These catalysts comprise a novel amorphous aluminophosphate comprising, on a microlevel, sheets of aluminophosphate as well as spheres of aluminophosphate plus a chromium com... | 11/28/2000 |
| 6133188 | Process for preparing an ethylene polymerization catalyst and ethylene polymerization process A preparation process for a catalytic support, based on a special alumina modified with varying quantities of magnesium chloride is described, a higher rate of MgCl2 leading to a lesser quantity of heavy molecular chains in the final polymer. T... | 10/17/2000 |
| 6114271 | Process for the preparation of a polymerization and copolymerization of ethylene to give ultrahigh molecular-weight ethylene polymers Process for the preparation of a catalyst component for the polymerization and copolymerization of ethylene to give ultrahigh-molecular-weight ethylene polymers. Reaction of a Grignard compound with a halogenating agent, a titanium compound, a perhalogen ... | 09/05/2000 |
| 6100351 | Olefin polymerization process and products thereof Methods of producing polyolefin polymers by polymerizing an -olefin in the presence of a catalyst including a pro-catalyst having a magnesium halide, an aluminum halide, a tetravalent titanium halide, an electron donor, and a silane having the form... | 08/08/2000 |
| 6068828 | Zirconia powder, method for producing the same, and zirconia ceramics using the same A zirconia powder has an average particle diameter in a range from larger than 0.5 μm to 0.8 μm, and particles of 90 volume percent of the zirconia powder having a diameter of 1.5 μm or smaller. Using this zirconia powder, a zirconia ceramics having un... | 05/30/2000 |
| 6043181 | Process for the polymerization of alpha olefins using a new aluminophosphate support Novel catalysts are provided for the polymerization of olefins such as ethylene. These catalysts comprise a novel amorphous aluminophosphate comprising, on a microlevel, sheets of aluminophosphate as well as spheres of aluminophosphate plus a chromium com... | 03/28/2000 |
| 6018006 | Process for preparing an ethylene polymerization catalyst and ethylene polymerization process A preparation process for a catalytic support, based on a special alumina modified with varying quantities of magnesium chloride is described, a higher rate of MgCl2 leading to a lesser quantity of heavy molecular chains in the final polymer. T... | 01/25/2000 |
| 5994256 | Process for forming a catalyst precursor for copolymerizing ethylene and an alpha-olefin of 3 to 10 carbon atoms A process is described for forming a catalyst precursor, for copolymerizing ethylene and an alpha-olefin of 3 to 10 carbon atoms, by preparing a contact mixture of an inert solvent, dibutylmagnesium and tetraalkyl orthosilicate which is free of precipitat... | 11/30/1999 |
| 5948720 | Catalyst for the production of flexible polyolefin compositions, methods for making and using same, and products thereof A catalyst for use in the production of flexible polyolefins using a pro-catalyst of (a) a magnesium halide, (b) an aluminum halide, (c) a tetravalent titanium halide, (d) an electron donor comprising at least one of 2,6-lutidine, 6-chloro-2-picoline, or ... | 09/07/1999 |
| 5714424 | Multi-component polyolefin catalysts The present invention encompasses a monolithic multi-component composite polyolefin catalyst particle comprising at least two distinct supported catalyst components wherein each catalyst component is capable of producing a resin having a melt index differ... | 02/03/1998 |
| 5648309 | Process for the preparation of a poly-1-olefin A Ziegler catalyst in which the transition metal component has been prepared by reacting a transition metal compound of titanium, zirconium, vanadium or chromium with a gel-like dispersion of a magnesium alcoholate is used for the preparation of poly-1-ol... | 07/15/1997 |
| 5585447 | Catalyst for the (co)polymerization of alpha-olefins, a process for its preparation and (co)polymerization process making use thereof This catalyst has the general formula VX3, mAIX3, nZ, wherein X is a halogen atom, Z is at least one at least partially halogenated, branched or unbranched, saturated hydrocarbon, m is between 0.1 and 10, and n is between 1 and 300. ... | 12/17/1996 |
| 5484754 | Process for treating a catalytic component, resultant component, and polymerization of ethylene using such component A process for the polymerization of ethylene or the copolymerization of ethylene with an alpha-olefin, in suspension or in gas phase, in the presence of a catalyst consisting essentially of a cocatalyst and a catalytic component based on at least Mg, Ti a... | 01/16/1996 |