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| Number | Title | Issue Date |
| 7053123 | Substituted (e)-styryl benzylsulfones for treating proliferative disorders (E)-Styryl benzylsulfones useful as antiproliferative agents, including, for example, anticancer agents, are provided according to formula I: wherein: R1 is selected from the group consisting of halogen, C1–C6 alkoxy, nitro, phosphonato, amino, sulfamyl... | 05/30/2006 |
| 6551467 | Microwave facilitated allyllic substitution The present invention is draw to microwave heating of a transition metal-catalysed organic reaction, in which a catalyst complex between a transition metal and an auxiliary ligand or ligands, the ligand being asymmetric or symmetric, monodentate or bident... | 04/22/2003 |
| 5284555 | Process for preparing organophosphines Olefins can be induced to react with phosphines at ambient temperature and pressure to produce organophosphines by free-radical addition. Suitable olefins include C1 to C4 alpha-olefins, cyclic olefins, polycycloalkenyl species, ally... | 02/08/1994 |
| 5279870 | Cured epoxy resins exhibiting nonlinear optical properties The present invention is directed to a novel epoxy polymeric composition resulting from reacting (A) at least one compound containing an average of more than one epoxide group per molecule with (B) at least one curing agent for component (A). At least a p... | 01/18/1994 |
| 5104503 | Photochemical dimerization of organic compounds At least one of selectivity and reaction rate of photosensitized vapor phase dimerizations, including dehydrodimerizations, hydrodimerizations and cross-dimerizations of saturated and unsaturated organic compounds is improved by conducting the dimerizatio... | 04/14/1992 |
| 4877501 | Process for fabrication of lipid microstructures Method and process for forming selected microstructures having predetermined shape and dimension from surfactants comprising the steps of: selecting a lipid which self aggregates into a predetermined microstructure selected from the group of helices and t... | 10/31/1989 |
| 4874488 | Photochemical dimerization and functionalization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and silanes The space-time yield and/or the selectivity of the photochemical dimerization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and primary, secondary and tertiary silanes with Hg and U.V. light is enhanced by refluxing the substrate in... | 10/17/1989 |
| 4832807 | Phosphorylation of alcohols Phosphorylation of alcohols by contacting the alcohol with a phosphorous sulphide under the impact of ultrasound. The phosporylated produce can be converted into a metal salt, which is a suitable anti-wear additive for lubricating oils.... | 05/23/1989 |
| 4767873 | Helical metallocene oligomers and a method for their preparation The invention describes a helicene compound having the structure ##SPC1## which contains seven six-membered conjugated aromatic rings capped by two five-membered rings which do not superimpose on each other. The invention also describes a helical metallocene o... | 08/30/1988 |
| 4746760 | Process for functionalizing alkanes Process for functionalizing saturated hydrocarbons comprising: (a) reacting said saturated hydrocarbons of the formula: wherein H represents a hydrogen atom; and R1 represents a saturated hydrocarbon radical, with a metal complex of the formula: wherei... | 05/24/1988 |
| 4632741 | Synthesis of alkyl phosphinate salts and bis(alkyl) phosphinate salts An improved method for the preparation of phosphinate salts or bis(alkyl) phosphinate salts by the reaction of an olefinic material with a hypophosphite salt by means of irradiation with UV light in the presence of a photoinitiator is disclosed.... | 12/30/1986 |
| 4384966 | Phosphorus substituted 4-methyloxetan-2-ones, processes for their preparation and their use Compounds having the formula ##STR1## are described, wherein X is oxygen or sulphur or the moiety X is absent and A and D are as defined in claim 1. Compounds I may be prepared by reacting a compound ##STR2## with diketene in the presence o... | 05/24/1983 |
| 4357307 | Method of separating isotopes in which a compounding of selectivity is achieved by limiting the timing of the collection step Methods for separating isotopes are disclosed including providing molecules which contain the element whose isotopes are to be separated and which have an isotopically shifted but overlapping infrared absorption spectrum associated with those isotopes whi... | 11/02/1982 |
| 4330382 | Synthesis process using photo-induced deligandation A process is provided for inducing a ligand substitution reaction. The process involves exposing to optical radiation a gaseous mixture including a compound of a transition metal and a first ligand and a gaseous second ligand. The gaseous transition metal... | 05/18/1982 |
| 4188273 | Process for preparing novel thin films A thin film of less than 300 microns in thickness can be obtained by crosslinking a surfactant with plasma or radiation. This thin film is as high in strength as an ordinary plastic film, and is usable as a substance-separating film, a substance-protectin... | 02/12/1980 |
| 4188275 | Process for preparing beta-phosphosulfoxy alcohols Beta-phosphosulfoxy alcohols and preparation thereof by reacting an olefinically unsaturated compound and a poly-thiophosphoric acid with oxygen using actinic radiation as an energy source at a temperature of from -10° to 70° C., preferably in the prese... | 02/12/1980 |
| 4188274 | Process for trifluoromethylation of aromatic and heterocyclic compounds A decarboxylation process for coupling aromatic compounds wherein cyclic hydrocarbons and heterocyclic compounds having at least one labile ring hydrogen are reacted with the mono silver salts of aromatic carboxylic acids, or mono silver salts of unsatura... | 02/12/1980 |
| 4155958 | Beta-phosphosulfoxy alcohols Beta-phosphosulfoxy alcohols and preparation thereof by reacting an olefinically unsaturated compound and a poly-thiophosphoric acid with oxygen using actinic radiation as an energy source at a temperature of from -10° to 70° C., preferably in the prese... | 05/22/1979 |
| 4144152 | Dehalogenation of halogenated compounds Process for degrading halogenated organic compound having C-halogen groups to remove halogen atoms from said compound by treating it with ultraviolet (UV) radiation and hydrogen. Process for degrading such compound by treating it in aqueous alkaline solut... | 03/13/1979 |
| 4104309 | Phosphine oxides having polyfluorinated-chain and their preparation This invention relates to new products comprising at least one isomer of polyfluorinated-chain phosphine oxide with the general formula (I): and complying with one of the developed formulae II or III : ##STR1## in which Cn F2n+1 repr... | 08/01/1978 |
| 4056571 | Process for the preparation of tertiary phosphine oxides Tertiary phosphine oxides are obtained by adding olefins having a terminal hydroxy or amino group or functional derivatives thereof to secondary phosphine oxides. The adducts are useful as intermediates in the preparation of flame-retardant agents, anti-c... | 11/01/1977 |
| 4052484 | Substituted cyclic phosphine oxides A cyclic phosphine oxide of the formula ##STR1## in which R1 is an alkyl or an aryl radical having up to 14 carbon atoms, R2, r3 and R4 each independently is a C1 -C4 -alkyl radical, h... | 10/04/1977 |
| 4008137 | Process for the preparation of phosphonated N,N-disubstituted fatty amides Phosphonated N,N-disubstituted fatty amides were prepared by the free radical addition of dialkyl phosphites to terminal and nonterminal double bonds of N,N-disubstituted amides. The free radical additions of the dialkyl phosphites to the unsaturated amid... | 02/15/1977 |
| 4007229 | Preparation of hydroxyalkyl phosphine oxides and sulfides A process for the preparation of 2-hydroxyalkylphosphine oxides and sulfides. The corresponding 2-acyloxyphosphine is hydrolyzed (or alcoholyzed) and oxidized, in either order, to produce the desired 2-hydroxyalkylphosphine oxide or sulfide. The product m... | 02/08/1977 |
| 4001352 | Process for the preparation of ethane-1,2-diphosphinic acid diesters A process for the preparation of ethane-1,2,-diphosphinic acid diesters of the formula ##STR1## where R1 represents alkyl, phenyl and/or phenalkyl groups having from 1 to 18 carbon atoms and R2 alkyl groups having from 1 to 18 c... | 01/04/1977 |
| 3992273 | Method of preparing substituted phenyl phosphinic acids This invention relates to a method for preparing substituted phenyl phosphinic acids and derivatives thereof by photolysis of aryl iodides in the presence of alkyl phosphonites.... | 11/16/1976 |
| 3988226 | Process for the preparation of phosphonated N,N-disubstituted fatty amides Phosphonated N,N-disubstituted fatty amides were prepared by the free radical addition of dialkyl phosphites to terminal and nonterminal double bonds of N,N-disubstituted amides. The free radical additions of the dialkyl phosphites to the unsaturated amid... | 10/26/1976 |
| 3980711 | Production of methylphosphine oxides Methylphosphine oxides of the general formula (I) ##EQU1## are produced from hydroxymethylphosphines of the general formula (II) ##EQU2## in which formulae R and R' each stand for identical or different alkyl-, cycloalkyl-, aralkyl- or aryl grou... | 09/14/1976 |
| 3970532 | 2-Hydroxyethylphosphines A process for the preparation of 2-hydroxyethylphosphines. The process involves the addition of an alkenyl carboxylate (such as vinyl acetate) to a phosphine containing a P--H bond, followed by conversion of the resulting ester-substituted phosphine to th... | 07/20/1976 |
| 3963570 | Ultraviolet-initiated preparation of N,N-dibutyl-9(10)-dibutylphosphonooctadecanamide N,N-Dibutyloleamide mixed with a slight excess of dibutyl phosphite and exposed to ultraviolet radiation reacts to yield N,N-dibutyl-9(10)-dibutylphosphonooctadecanamide, which is useful in imparting antimicrobial activity to cellulosic textiles and other... | 06/15/1976 |
| 3939050 | Process for the preparation of ethane-1,2-diphosphinic acid diesters A process for the preparation of ethane-1,2-diphosphinic acid diesters of the formula ##EQU1## where R1 represents alkyl, phenyl and/or phenalkyl groups having from 1 to 18 carbon atoms and R2 alkyl groups having from 1 to 18 ca... | 02/17/1976 |