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Class 203/9 - Of unsaturated hydrocarbon


Subclass of Class 203 - Distillation: processes, separatory
Definition: Processes directed to inhibiting or preventing the polymerization
No. of patents: 120
Last issue date: 07/01/2008


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NumberTitleIssue Date
7393986Process for the production and purification of vinyl aromatic monomers
Process for the production of vinyl aromatic monomers which comprises: a) feeding an aromatic stream and an olefinic stream to an alkylation unit; b) feeding the reaction product coming from the alkylation section to a first separation section; c) recovering the mon...
07/01/2008
7351310Rectificative separation of fluids comprising (meth) acrylic monomers
A process for rectificatively separating fluids including (meth)acrylic monomers in a rectification column by directly cooling the vapor including (meth)acrylic monomers rising to the top of the rectification column to form top condensate including (meth)acrylic mon...
04/01/2008
7348466Solvent extraction
In a method for the solvent extraction of butadiene from a mixture of hydrocarbons having four carbon atoms per molecule, which method inherently produces tars, the extraction process is operated with a tar loading level, relative to the solvent employed, of no more...
03/25/2008
7326323High capacity purification of thermally unstable compounds
Separations processes and apparati capable of purifying thermally sensitive materials at high capacity. An apparatus having a rectification section and a stripping section with the stripping section having a stripping tray with 5 to 50% open area, a pressure drop fr...
02/05/2008
7304196Fuel components and their selective manufacturing methods
A method for dimerizing isobutene, wherein, in dimerizing conditions, the isobutene is brought into contact with a porous cation exchange resin comprising a styrene polymer, which is cross-linked with divinyl benzene, and any sulphonic acid groups adhering to the po...
12/04/2007
7288169Distillation apparatus for readily polymerizable compound
A distillation apparatus for subjecting a crude readily polymerizable compound to distillation under vacuum conditions to purify the same includes a distillation column and a vacuum generator, an exhaust gas conduit of the vacuum generator being connected to a conne...
10/30/2007
7276636Styrene process with recycle from dehydrogenation zone
A styrene process is disclosed that uses a dehydrogenation reactor and a transalkylation reactor and in which a significant portion of the benzene, the inhibitors, or both, recovered from the dehydrogenation reactor passes to the transalkylation reactor. The process...
10/02/2007
7205438Solvent recovery blends from diene production
A diene production stream comprising a solvent recovery blend from diene production comprising one or more fouling agent, one or more extractive distillation solvent, and from about 1 ppm to about 1000 ppm of N,N-disubstituted amide. ...
04/17/2007
7128826Polymerization inhibitor for styrene dehydrogenation units
Quinone methide derivatives such as 4-benzylidene-2,6-di-tert-butyl-cyclohexa-2,5 dienone are used to inhibit styrene monomer polymerization in the dehydrogenator portion of a styrene monomer production system. The inhibitor contacts the dehydrogenation effluent and...
10/31/2006
7125475Nitrosophenols and C-nitrosoanilines as polymerization inhibitors
Inhibitor blends that include both nitrosophenols and nitrosoanilines, optionally in combination with air or oxygen, reduce the premature polymerization of ethylenically unsaturated monomers. unsaturated monomers. ...
10/24/2006
7094939Styrene process with recycle from dehydrogenation zone
A styrene process is disclosed that uses a dehydrogenation reactor and a transalkylation reactor and in which a significant portion of the benzene, the inhibitors, or both, recovered from the dehydrogenation reactor passes to the transalkylation reactor. The process...
08/22/2006
7045647Blends of quinone alkide and nitroxyl compounds and polymerization inhibitors
Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of: A) at least one nitroxyl compound, and B) at least one quinone alkide compound having an electro...
05/16/2006
7029556Method for purifying (meth)acrylic monomers by distillation
The invention concerns a method of purifying a (meth) acrylic monomer selected among (meth) acrylic acids and their esters, by distillation in the presence of at least a polymerisation inhibitor requiring input of oxygen and/or an inhibitor having better efficacy in...
04/18/2006
7022220C-nitrosoaniline compounds and their blends as polymerization inhibitors
Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine o...
04/04/2006
6902663C-nitrosoaniline compounds and their blends as polymerization inhibitors
Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine o...
06/07/2005
6835288Method for preventing undesired polymerization in a mixture of substances containing ethylenically unsaturated compounds
A process for preventing undesired polymerization is conducted by maintaining an effective concentration of a stabilizer which comprises N-oxyl radicals in a mixture containing ethylenically unsaturated compounds, wherein (i) an el...
12/28/2004
6592722Polymerization inhibitor for vinyl-containing materials
This invention relates to a process of inhibiting the polymerization of vinyl-containing materials through the use of an effective amount of a polymerization inhibitor comprising quinone diimide and a nitroxyl stable free radical under various conditions....
07/15/2003
6579442Methods and compositions for inhibiting polymerization of vinyl monomers
Methods and compositions for inhibiting the polymerization of vinyl monomers are disclosed. Combinations of nitroxyl compounds and aliphatic amines are effective at inhibiting the polymerization of vinyl monomers under both processing and storage conditio...
06/17/2003
6540881Method for refining (meth)acrylic acid
This invention relates to a method for preventing (meth)acrylic acid from polymerizing during the course of distillation. The method provides for refining (meth)acrylic acid by a procedure including the steps of feeding a mixed gas obtained by catalytic g...
04/01/2003
6475348Mixture of substances containing compounds with vinyl groups and stabilizers
A mixture contains one or more vinyl-containing compounds as component (A) and, as a further component, a stabilizer (B) which contains one or more readily volatile nitroxyl compounds as component (b1), one or more sparingly volatile nitroxyl c...
11/05/2002
6471865Solvent exchange column and a method of use therefor
The present invention provides a solvent exchange column for continuously exchanging styrene monomer with the solvent used to produce polybutadiene and a method of use therefor. The solvent exchange column includes an exchange plate support structure coup...
10/29/2002
6447649Polymerization inhibitor for vinyl-containing materials
This invention relates to a process of inhibiting the polymerization of vinyl-containing materials through the use of an effective amount of a polymerization inhibitor comprising quinone diimide and a nitroxyl stable free radical under various conditions....
09/10/2002
6409887Polymerization inhibitor
A monomer composition, stabilized against premature polymerization, comprising: a) an ethylenically unsaturated monomer or mixture of monomers polymerizable by free radical initiation, and b) an effective amount, sufficient to inhibit premature polymeriza...
06/25/2002
6348136Method and apparatus for the purification of vinyl aromatic compounds
The present invention is directed to an apparatus and method for the distillation of a readily polymerizable vinyl aromatic compound employing a polymerization inhibitor. The vinyl aromatic compound is subjected to distillation in at least one fractionati...
02/19/2002
6342648Methods and compositions for inhibiting vinyl aromatic monomer polymerization
The present invention provides compositions and methods inhibiting polymerization of vinyl aromatic compounds comprising a bisphenol compound and an oxidized p-phenylenediamine. In a specific, non-limiting embodiment, the polymerization of the vinyl aroma...
01/29/2002
6210536Polymerization inhibitors for acrylic acids and esters
This invention is directed to certain N,N'-dinitroso phenylenediamines useful as polymerization inhibitors for acrylic acids and esters thereof. Also disclosed are compositions containing such compounds, and methods for inhibiting polymerization using suc...
04/03/2001
6200461Method for inhibiting polymerization of ethylenically unsaturated hydrocarbons
Methods and compositions for inhibiting the polymerization of ethylenically unsaturated hydrocarbons are disclosed. Combinations of aminophenol compound and either of phenylenediamine or hydroxylamine compounds are effective at inhibiting this polymerizat...
03/13/2001
6175049Process for the production of 1, 2-butadiene
The production of 1,2-butadiene in purities of at least 85% becomes possible by means of a process in which a polymerization-inhibitor-containing C4 hydrocarbon fraction is subjected to at least one fractional distillation....
01/16/2001
6117276Inhibiting polymerization of vinyl aromatic monomers
When a nitroxyl compound is heated in an oxygen-free atmosphere with a vinyl aromatic monomer at 50-140° C. for up to 60 days, it forms an activated inhibitor mixture which is superior to the nitroxyl compound itself in preventing the premature polymeriz...
09/12/2000
6096941Distillation of vinylaromatic monomer
Process technology is described making possible substantial improvements in the separation and recovery of highly pure vinyl aromatic monomers, notably styrene. A number of design, construction and operational features are made available for selection and...
08/01/2000
5954924Distillation of vinylaromatic monomer
Process technology is described making possible substantial improvements in the separation and recovery of highly pure vinyl aromatic monomers, notably styrene. A number of design, construction and operational features are made available for selection and...
09/21/1999
5910232Method for inhibiting polymer formation in styrene processing
Inhibition performance is improved in styrene processing through the addition of a stable nitroxide free radical compound to the styrene feed and to the reflux of at least one column....
06/08/1999
5907071Compositions and methods for inhibiting vinyl aromatic monomer polymerization
The polymerization of vinyl aromatic monomers such as styrene is inhibited by the addition of a composition of a stable hindered nitroxyl radical and an oxime compound....
05/25/1999
5888356Inhibition of polymerization of vinylaromatic or vinylaliphatic
The polymerization of a vinylaromatic or vinylaliphatic compound at elevated temperature in the absence of air is inhibited by processing the vinylaromatic or vinylaliphatic compound in the presence of 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl or ...
03/30/1999
5886241Methods and compositions for inhibiting the polymerization of ethylenically unsaturated monomers
The polymerization of an ethylenically unsaturated monomer such as isoprene, butadiene and acrylonitrile is inhibited during storage or handling thereof by the addition of a dihydroxycinnamic acid or derivative thereof....
03/23/1999
5869717Process for inhibiting the polymerization of vinyl aromatics
Applicants have developed a process for inhibiting the polymerization of vinyl aromatic compound during the distillation of the vinyl aromatic compounds. The process involves adding to the vinyl aromatic compound, e.g., styrene, a nitroso compound such as...
02/09/1999
5858176Compositions and methods for inhibiting fouling of vinyl monomers
Methods and compositions for inhibiting fouling in vinyl monomers are disclosed. Alkylphosphonate esters or acids thereof are added to vinyl monomers, particularly ethylene dichloride, that are undergoing processing to inhibit fouling....
01/12/1999
5770021Process and apparatus for purification of a gas stream containing acrolein
A process including a first stage wherein a feed gas stream containing acrolein originating, for example from the gas-phase oxidation of propylene to acrolein, is fractionated into a gaseous effluent and a liquid stream in a cooling column operating such ...
06/23/1998
5756870Methods for inhibiting the polymerization of ethylenically unsaturated monomers
The polymerization of an ethylenically unsaturated monomer such as isoprene and butadiene is inhibited during storage or handling thereof by the addition of a dihydroxycinnamic acid or derivative thereof....
05/26/1998
5744672Method for inhibiting the polymerization of vinyl aromatics
A method for inhibiting the polymerization of vinyl aromatics such as styrene with a mixture of 3,5-di-tert-butyl-4-hydroxy-N,N-dimethylbenzyl amine and carboxylic acids or anhydrides thereof, in the presence of air or oxygen. The weight ratio of said ...
04/28/1998
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