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Class 203/8 - For inhibiting or preventing a polymerization reaction


Subclass of Class 203 - Distillation: processes, separatory
Definition: Processes directed to adding a substance to inhibit or prevent
No. of patents: 132
Last issue date: 01/13/2009


1        
NumberTitleIssue Date
7476299Vessel for easily polymerizable compound
A decomposition reaction apparatus or distillation apparatus for acrylic acid in which a column bottom liquid heated in a reboiler (5) is supplied from a supply port (1a) provided on a side wall of a column body (1) having: a top plate (
01/13/2009
7368492Process for the synthesis of glycolonitrile
A process to prepare substantially pure glycolonitrile in an aqueous medium is provided by reacting hydrogen cyanide and formaldehyde. The formaldehyde feed stream is heated prior to reacting with hydrogen cyanide, resulting in an aqueous glycolonitrile solution wit...
05/06/2008
7351310Rectificative separation of fluids comprising (meth) acrylic monomers
A process for rectificatively separating fluids including (meth)acrylic monomers in a rectification column by directly cooling the vapor including (meth)acrylic monomers rising to the top of the rectification column to form top condensate including (meth)acrylic mon...
04/01/2008
7332626Method for production of (meth) acrylic acid
A method for producing acrylic acid by absorbing acrylic acid at a high ratio and obtaining an acrylic acid-containing solution of high concentration is provided. This method comprises a step of circulating part of a discharged gas from an absorption step of acrylic...
02/19/2008
7332624Method for production of acrylic acid
A method for the production of acrylic acid comprises (i) a step for introducing a polymerization inhibitor to a stage other than a stage for supplying a raw material and a stage for supplying a reflux of said distilling column or (ii) a step for supplying the acryl...
02/19/2008
7326323High capacity purification of thermally unstable compounds
Separations processes and apparati capable of purifying thermally sensitive materials at high capacity. An apparatus having a rectification section and a stripping section with the stripping section having a stripping tray with 5 to 50% open area, a pressure drop fr...
02/05/2008
7319167Method for distilling (meth)acrylic acid and/or the ester thereof
A method for distilling (meth)acrylic acid and/or the ester thereof by withdrawing vapor generated in a distillation column by distillation from the top of the column, condensing the vapor to give a condensate, and circulating part of the condensate as reflux liquid...
01/15/2008
7304176Process for producing easily polymerizable substance
It is an object of the present invention to provide a process for producing easily polymerizable substance, which can realize stable operation of a purification system, and can stably maintain a production amount by avoiding production stoppage, upon production of a...
12/04/2007
7294240Method for producing (meth)acrylic acid esters
Basic (meth)acrylates IV are prepared by transesterification of alkyl (meth)acrylates I in the presence of a catalyst and working-up of the reaction mixture by distillation, by a process in which a gas or gas mixture which is inert under the reaction conditions is p...
11/13/2007
7288169Distillation apparatus for readily polymerizable compound
A distillation apparatus for subjecting a crude readily polymerizable compound to distillation under vacuum conditions to purify the same includes a distillation column and a vacuum generator, an exhaust gas conduit of the vacuum generator being connected to a conne...
10/30/2007
7282118Method for production of easily polymerizable substance and purification apparatus
This invention resides in providing a method for the prevention of possible polymerization of the easily polymerizable substance during the purification thereof by a column provided with (a) at least one tray directly fixed to a support ring with a bolt and a nut an...
10/16/2007
7279075Thermal separating process between at least one gaseous and at least one liquid stream, of which at least one comprises (meth)acrylic monomers
In a thermal separating process between at least one gaseous and at least one liquid stream, of which at least one comprises (meth)acrylic monomers, in a separating column containing sieve trays as separating internals, at least some of the sieve trays are operated ...
10/09/2007
7267747Plant and method for vacuum distillation of hydrocarbon liquids
A vacuum distillation system and method utilizing a low capacity vacuum producing ejector operated in parallel with a primary ejector during the Winter months enables significant reduction in the absolute pressure of a vacuum distillation column. Operation of a vacu...
09/11/2007
7238743Production process for water-absorbent resin
The present invention provides a process for producing a water-absorbent resin of which the residual monomer content and the extractable content are low. The process for producing a water-absorbent resin comprises the step of polymerizing at least one monomer compon...
07/03/2007
7235158Perforated tray column without downcomer
A perforated tray without downcomer having only a small deviation between the opening ratio based on the diameter of a column and the actual opening ratio and a perforated tray column without downcomer formed by disposing such perforated trays without downcomer are ...
06/26/2007
7183428Method for production of acrylic acid
A method for producing acrylic acid by using an acrylic acid-containing solution of high concentration without azeotropic distillation is provided. This method of producing acrylic acid comprises introducing an acrylic acid-containing gas obtained by catalytic gas p...
02/27/2007
7179875Method for producing water-absorbent resins
In a process for preparing water-absorbent resins based on acrylic acid, crude acrylic acid is firstly isolated from the reaction gases from the catalytic gas-phase oxidation of propane, propylene and/or acrolein. This is treated with an aldehyde scavenger and pure ...
02/20/2007
7150809Thermal separating process
(Meth)acrylic monomers are separated by a thermal separation process by ascending at least one ascending gaseous stream in a separating column containing a sequence of mass transfer trays and a liquid stream that contains dissolved polymerization inhibitor which des...
12/19/2006
7128826Polymerization inhibitor for styrene dehydrogenation units
Quinone methide derivatives such as 4-benzylidene-2,6-di-tert-butyl-cyclohexa-2,5 dienone are used to inhibit styrene monomer polymerization in the dehydrogenator portion of a styrene monomer production system. The inhibitor contacts the dehydrogenation effluent and...
10/31/2006
7128813Process for manufacturing high purity methacrylic acid
A process for the high yield production of high purity glacial methacrylic acid (“HPMAA”) with minimization of decomposition of hydroxy isobutyric acid (HIBA). The HPMAA is substantially pure, specifically 99% pure or greater with a water content of 0.05% or les...
10/31/2006
7125475Nitrosophenols and C-nitrosoanilines as polymerization inhibitors
Inhibitor blends that include both nitrosophenols and nitrosoanilines, optionally in combination with air or oxygen, reduce the premature polymerization of ethylenically unsaturated monomers. unsaturated monomers. ...
10/24/2006
7119224Preparation of (METH) acrylic acid and (METH) acrylic esters
A process for preparing and/or working up mixtures by (meth)acrylic acid and/or (meth)acrylic ester in the presence of at least one polymerization inhibitor and at least one oxygenous gas, which comprises metering in at least part of the oxygenous gas at an exit rat...
10/10/2006
7081185Purification apparatus provided with low heat conductive member
The object of this invention to provide an improved arrangement that enables to prevent adhesion of polymer on or around the inner wall of a purification apparatus directly equipped on the outer wall thereof with an attachment such as a support by suppressing local ...
07/25/2006
7048834Method for purification of acrylic acid
The present invention provides an industrially easy and economical method for purification of acrylic acid which enables to efficiently eliminate impurities from a crude acrylic acid containing aldehydes as the impurities while the formation of acrylic acid polymer ...
05/23/2006
7037411Apparatus and method for handling easily polymerizable substance, apparatus for extracting liquid from apparatus under reduced pressure, and process for producing easily polymerizable substance
In an apparatus capable of distilling and refining an easily polymerizable substance, piping is performed so that when a strainer in action is switched to a backup strainer, the strainer can be switched after removing air in the backup strainer to replace air in the...
05/02/2006
7029556Method for purifying (meth)acrylic monomers by distillation
The invention concerns a method of purifying a (meth) acrylic monomer selected among (meth) acrylic acids and their esters, by distillation in the presence of at least a polymerisation inhibitor requiring input of oxygen and/or an inhibitor having better efficacy in...
04/18/2006
7022220C-nitrosoaniline compounds and their blends as polymerization inhibitors
Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine o...
04/04/2006
7014736Apparatus and process for purification of acrylic acid family
An apparatus and a process for purification of an acrylic acid family. The apparatus is an apparatus for distillation purification of the acrylic acid family encompassing acrylic acid and its esters, and includes: a distillation column 10 to which a liquid co...
03/21/2006
6966973Apparatus and process for producing (meth)acrylic acid
The present invention provides an apparatus for producing (meth)acrylic acid and a process for producing (meth)acrylic acid with this apparatus wherein the apparatus enables the production of (meth)acrylic acid stably for a long period of time by effectively inhibit...
11/22/2005
6927268Production process for water-absorbent resin
The present invention provides a process for producing a water-absorbent resin of which the residual monomer content and the extractable content are low. The process for producing a water-absorbent resin comprises the step of polymerizing at least one monomer compon...
08/09/2005
6926820Inhibition of viscosity increase and fouling in hydrocarbon streams including unsaturation
A method of inhibiting fouling and viscosity increase in hydrocarbon streams including ethylenically unsaturated monomers is disclosed. The method includes the step of adding to the hydrocarbon stream an effective amount of one or more quinone methides of the formul...
08/09/2005
6902663C-nitrosoaniline compounds and their blends as polymerization inhibitors
Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine o...
06/07/2005
6899806C-nitrosoaniline compounds and their blends as polymerization inhibitors
Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of: A) at least one first inhibitor selected from the group consisting of C-nitrosoaniline co...
05/31/2005
6878239Process for inhibiting a polymerization in a vacuum section of an easily polymerizable compound purification system
A process for inhibiting a polymerization of an easily polymerizable compound purification system is disclosed. According to the present invention, the polymerization of the easily polymerizable compound such as (meth)acrylic acid and (meth)acrylate flowed in...
04/12/2005
6863779Distillation of styrene
A process for the distillation of vinylaromatic monomers in the presence of 4-tert-butylcatechol (TBC) and oxygen, wherein no aromatic nitro or amino compound is present in any effective amount. The process is particularly suitable for destabilizing and purifying st...
03/08/2005
6835288Method for preventing undesired polymerization in a mixture of substances containing ethylenically unsaturated compounds
A process for preventing undesired polymerization is conducted by maintaining an effective concentration of a stabilizer which comprises N-oxyl radicals in a mixture containing ethylenically unsaturated compounds, wherein (i) an el...
12/28/2004
6695928Method for production of (meth) acrylic acid and/or (meth)acrylic esters
A method for the production of (meth)acrylic acid and/or a (meth)acrylic ester is provided. This method for the production of (meth)acrylic acid and/or a (meth)acrylic ester includes washing the device constructed for the production thereof with a basic s...
02/24/2004
6685823C-nitrosoaniline compounds and their blends as polymerization inhibitors
Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quin...
02/03/2004
6676808Method for starting up distilling column
A method for starting up a distilling column destined to handle an easily polymerizing compound-containing solution characterized by supplying at the start of the operation of the distilling column a polymerization inhibitor to the bottom liquid of the di...
01/13/2004
6673212Polymerization-inhibited distillation
Identified herein are inhibitors which may be added to the boiling pot portion of a distillation apparatus prior to or during the distillation of an alkylene carbonate. The inhibitors retard the occurrence of undesirable reactions of the alkylene carbonat...
01/06/2004
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