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Class 570/176 - Replacing halogen with hydrogen


Subclass of Class 570 - Organic compounds -- part of the class 532-570 series
Definition: Process wherein an atom of halogen is removed and replaced
No. of patents: 132
Last issue date: 11/15/2011


1        
NumberTitleIssue Date
8058489Processes for producing pentafluoropropenes and azeotropes comprising HF and certain halopropenes of the formula CClF, CClF, or CHF
A process is disclosed for making CF3CF═CHF or mixtures thereof with CF2═CFCHF2. The process involves (i) contacting CHCl2CF2CF3, and optionally CHClFCF2CClF2, in a reaction ...
11/15/2011
7872161Process for producing 2,3,3,3-tetrafluoropropene
A process is disclosed for making CF3CF═CH2 The process involves (i) contacting CHCl2CF2CF3 in a reaction zone in the presence of a catalytically effective amount of a dehydrofluorination catalyst to produce C...
01/18/2011
7795482Method of hydrodechlorination to produce dihydrofluorinated olefins
Disclosed herein is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkene with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents with hydrogen. Also ...
09/14/2010
7629496Process for the manufacture of 1,1,1,3,3-pentafluoropropane
A process for the manufacture of 1,1,1,3,3-pentafluoropropane, which comprises reacting 1,1,1,3,3,3-hexafluoropropane with a source of hydrogen. ...
12/08/2009
7470828Direct conversion of HCFC 225ca/cb mixture to HFC 245cb and HFC 1234yf
Provided are methods for producing hydrofluorocarbons via the selective reduction of a halocarbon blend comprising 1,3-dichloro-1,1,2,2,3-pentafluoropropane. ...
12/30/2008
7354890Cleaning composition and method
Cleaning compositions composed of specific amounts of carbonic acid and/or carbonate, hydrogen peroxide, aluminum fluoride and water are highly effective for cleaning electronic devices of resist, resist residues, titanium dioxide, aluminum oxide and silicon dioxide...
04/08/2008
7348461Processes for halogenating compounds
Methods and materials are provided for the production of essentially isomerically pure perhalogenated and partially halogenated compounds. One embodiment of the present invention provides a process for the production of essentially isomerically pure CFC-216aa. Other...
03/25/2008
7335805Processes for purifying reaction products and processes for separating chlorofluorinated compounds
Methods and materials are provided for the production of essentially isomerically pure perhalogenated and partially halogenated compounds. One embodiment of the present invention provides a process for the production of essentially isomerically pure CFC-216aa. Other...
02/26/2008
7335804Direct conversion of HCFC 225ca/cb mixture
Provided are methods for producing hydrofluorocarbons via the selective reduction of a halocarbon blend comprising 1,3-dichloro-1,1,2,2,3-pentafluoropropane. ...
02/26/2008
7332635Processes for purifying chlorofluorinated compounds
Methods and materials are provided for the production of essentially isomerically pure perhalogenated and partially halogenated compounds. One embodiment of the present invention provides a process for the production of essentially isomerically pure CFC-216aa. Other...
02/19/2008
7329786Processes for producing CFCFHCF
Methods and materials are provided for the production of essentially isomerically pure perhalogenated and partially halogenated compounds. One embodiment of the present invention provides a process for the production of essentially isomerically pure CFC-216aa. Other...
02/12/2008
7285692Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropane
A process is disclosed for the manufacture of CF3CH2CHF2 and CF3CHFCh2F. The process involves (a) reacting hydrogen fluoride, chlorine, and at least one halopropene of the formulaCX3CCl═CClX (where ...
10/23/2007
7285690Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,3,3,3-hexafluoropropane
A process for the manufacture of CF3CH2CHF2 and CF3CH2CF3 is disclosed. The process involves (a) reacting HF and at least one halopropene of the formula CX3CCl═CClX (where each X is indep...
10/23/2007
7285691Process for the preparation of 1,1,1,3,3,3-hexafluoropropane and at least one of 1,1,1,2,3,3-hexafluoropropane and 1,1,1,2,3,3,3-heptafluoropropane
A process is disclosed for the manufacture of 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) and at least one 1,1,1,2,3,3-hexafluoropropane (HFC-236ea) and 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea). The process involves (a) reacting HF, Cl2, and at least on...
10/23/2007
7247759Fluorination reactor
Fluorination reactions in which an organic compound to be fluorinated is contacted with elemental fluorine and HF is produced as a byproduct are disclosed, wherein the elemental fluorine is contacted with the organic compound in the presence of a fluoride-adsorbing ...
07/24/2007
7230146Process for producing fluoropropenes
Dehydrohalogenation processes for the preparation of fluoropropenes from corresponding halopropanes, in which the fluoropropenes have the formula CF3CY═CXNHP, wherein X and Y are independently hydrogen or a halogen selected from fl...
06/12/2007
7214839Method of making hydrofluorocarbons
A manufacturing process for making hydrofluorocarbons (HFCs), by reacting a hydrochlorocarbon and HF in a liquid phase catalytic reactor using a large mole ratio of HF to hydrochlorocarbon to minimize formation of high boiling by-products and improve HF consumption ...
05/08/2007
7208136Alcohol steam reforming catalysts and methods of alcohol steam reforming
The present invention provides steam reforming catalyst compositions containing Pd and Zn, and methods of steam reforming alcohols over a catalyst. Surprisingly superior results and properties of the present invention, including low temperature activity and/or low c...
04/24/2007
7202388Processes for preparing fluoroarenes from haloarenes
Processes for preparing fluoroarenes are provided. The processes include contacting a compound having an unactivated aryl group with a source of fluoride or bifluoride in the presence of a transition metal a ligand. ...
04/10/2007
7151197Processes for purifying chlorofluorinated compounds and processes for purifying CF3CFHCF3
Methods and materials are provided for the production of essentially isomerically pure perhalogenated and partially halogenated compounds. One embodiment of the present invention provides a process for the production of essentially isomerically pure CFC-216aa. Other...
12/19/2006
7135601Catalytic method for the production of fluoroalkylenes from chlorofluorohydrocarbons
A process for producing a producing a product of the formula: R—CF═CHR1 wherein R is F or CF3 and R1 is F when R is F and is H when R is CF3 by reacting a reactant of the formula: CF...
11/14/2006
7102040Fluoropolymer lined metallic vessel design
The invention provides an apparatus useful in fluorinating organic compounds, or more particularly to a reactor system suitable for the fluorination of organic compounds on a commercial scale. The apparatus is also useful in chemical reactions including heating or c...
09/05/2006
7026521Methane and methyl chloride as selective reducing agent in the transformation of hydrochlorofluorocarbons or chlorofluorocarbons to hydrofluorocarbons
A gas phase reaction process for producing a hydrofluorocarbon from a hydrochlorofluorocarbon or chlorofluorocarbon reactant by contacting, in the presence of a catalyst, the hydrochlorofluorocarbon or chlorofluorocarbon reactant with a reducing agent selected from ...
04/11/2006
6963016Process for the synthesis of highly active modified carbon supported palladium catalyst
The present invention relates to a process for the synthesis of highly active modified carbon supported palladium catalyst by simultaneously impregnating activated carbon with a palladium precursor and an aluminium precursor. The carbon supported palladium catalyst ...
11/08/2005
6927191Oxidation catalyst
An inside layer including zeolite and an outside layer including alumina and Pd are formed in a layered shape on a carrier, and Ag and Bi are simultaneously allowed to be carried on the inside and outside layers through impregnation. Thus, production of an alloy thr...
08/09/2005
6903063Azeotrope-like composition of 1-chloro-1,3,3,3-tetrafluoropropane and hydrogen fluoride
The invention relates to azeotropic and azeotrope-like mixtures of 1-chloro-1,3,3,3-tetrafluoropropane (HCFC-244fa) and hydrogen fluoride, which are useful as intermediates in the production of HCFC-244fa. ...
06/07/2005
6878853Process for preparing dihalogenated adamantanes
This invention discloses a process for preparing a dihalogenated adamantane by reacting an adamantane optionally substituted with alkyl at 1-position with a halosulfonic acid, comprising the first stage of monohalogenation conducted at −5 to 15° C. and then the s...
04/12/2005
6784327Process for the production of fluorinated organic compounds and fluorinating agents
A process for the production of a fluorinated organic compound, characterized by fluorinating an organic compound having a hydrogen atoms using IF5; and a novel fluorination process for fluorinating an organic compound having a hydrogen atoms by using a f...
08/31/2004
6700026Method for preparing difluoromethane
A method for preparing difluoromethane (CF2 H2, HFC-32) by the use of reaction of dichlorodifluoromethane (CF2 Cl2, CFC-12) and/or monochlorodifluoromethane (CF2 ClH, HCFC-22) with hydrogen in the pre...
03/02/2004
6583328Method for the preparation of 1,1,1,3,3-pentafluoropropene and 1,1,1,3,3-pentafluoropropane
A method for the production of 1,1,1,3,3-pentafluoropropene, and particularly to a method characterized by high conversion, yield and selectivity by contacting 2,2-dichloro-1,1,1,3,3,3-hexafluoropropane with hydrogen in the presence of a metal-containing ...
06/24/2003
6566567Catalyst and method for producing 1,1-difluoroethane
The present invention relates to a catalyst for producing 1,1-difluoroethane (HCFC-152a) and producing method thereof. More particularly, it is to provide the catalyst prepared by impregnating palladium on the active carbon pretreated with an aqueous hydr...
05/20/2003
6551469Photochlorination of 1,1,1,3,3-pentafluoropropane
A process for preparing 1-chloro-1,1,3,3,3-pentafluoropropane, CF3 CH2 CF2 Cl, comprising contacting in a reaction zone in the substantial absence of oxygen, reactants comprising chlorine and 1,1,1,3,3-pentafluoropropane, ...
04/22/2003
6548720Process for the manufacture of 1,1,1,3,3-pentafluoropropene, 2-chloro-pentafluoropropene and compositions comprising saturated derivatives thereof
A process is disclosed for producing the pentfluropropenes of the formula CF3 CX.dbd.CF2, where X is H or Cl. The process involves hydrodehalogenating CF3 CCl2 CF3 with hydrogen at an elevated tempera...
04/15/2003
6525231Producing hydrofluoro compounds by hydrogenolysis of iodides
A process is disclosed for producing RCFZH by reaction of an iodide compound of the formula R'CFZI with hydrogen at an elevated temperature, wherein R is SF5, CF2 SF5 or Rf CF2 Y, R' is SF5...
02/25/2003
6509495Selective hydrodehalogenation method
The invention concerns a selective hydrodehalogenation method characterised in that it comprises a step which consists in contacting a substrate including a sp 3 hybridisation carbon atom bearing an electro-attracting group and at least a fluorine atom, a...
01/21/2003
6403846Fluorinated, saturated hydrocarbons
A composition containing less than 95 mol % of a trihydrofluorinated saturated hydrocarbon represented by the following formula (I) Rf1 --R1 --Rf2 (I) (wherein R1 represents a carbon chain in which CHF and CH2...
06/11/2002
6388147Production of 1,2-dihydro and 2,2-dihydro hexafluoropropanes and azeotropes thereof with HF
CF3 CHFCHF2 production is disclosed which involves reacting CF3 CF.dbd.CHF with HF at an elevated temperature over a catalyst selected from the group consisting of aluminum fluoride, fluorided alumina, metals supported on ...
05/14/2002
6376727Processes for the manufacture of 1,1,1,3,3-pentafluoropropene, 2-chloro-pentafluoropropene and compositions comprising saturated derivatives thereof
Disclosed are azeotropic compositions comprising CF3 CHFCF3 and HF. Also disclosed are compositions and a process for producing compositions comprising (c1) CF3 CHFCF3, CF3 CH2 CF3
04/23/2002
6340776Process for producing 1,1,1-trifluoroacetone
A process for producing 1,1,1-trifluoroacetone includes the step of conducting a hydrogenolysis of a halogenated trifluoroacetone, which is represented by the general formula (1), by a hydrogen gas in the presence of a catalyst containing a transition met...
01/22/2002
6291729Halofluorocarbon hydrogenolysis
A highly selective process is disclosed for the hydrogenolysis of 2,2-dichlorohexafluoropropane (i.e., CFC-216aa or CF3 CCl2 CF3) to 2,2-dihydrohexafluoropropane (i.e., HFC-236fa or CF3 CH2 CF3
09/18/2001
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