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Class 568/866 - Preparing from ether


Subclass of Class 568 - Organic compounds -- part of the class 532-570 series
Definition: Processes which include reacting an ether to prepare the
No. of patents: 59
Last issue date: 07/15/2008


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NumberTitleIssue Date
4649225Hydrogenolysis of polyalkylene glycols to produce monoethylene glycol monoalkyl ethers, monoethylene glycol and ethanol
This invention relates to a process for selectively cleaving a polyalkylene glycol, e.g., diethylene glycol, containing at least one ether group therein at a carbon-to-oxygen covalent bond and independently at a carbon-to-carbon covalent bond by heating t...
03/10/1987
4633025Method for preparing (+)R-2-methyl-hexane-1,2-diol
A method for preparing important stereospecific intermediates in the synthesis of prostaglandin analogs is disclosed. Said intermediates are (+)R-2-methyl-hexane-1,2-diol and (-)S-2-methyl-hexane-1,2-diol and are prepared via an asymmetric halolactonizati...
12/30/1986
4609768Process for synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane using 1,3-dioxolane as a solvent
This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence o...
09/02/1986
4568780Process for low pressure synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane
This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence o...
02/04/1986
4533774Process for the production of ethylene glycol
Ethylene glycol is produced by reacting at elevated temperature methanol, a polymeric source of formaldehyde and an organic peroxide having the formula R--O--O--R1 wherein R and R1 are independently either alkyl or aralkyl groups con...
08/06/1985
4510336Transetherification method
Transetherification is carried out in a catalytic distillation reactor, wherein the catalytic structure also serves as a distillation structure, by feeding a first ether to the catalyst bed to at least partially dissociate it into a first olefin and a fir...
04/09/1985
4503275Production of butane-1,4-diol
Butane-1,4-diol is produced by converting allyl alcohol to an allyl t-alkyl or -cycloalkyl ether of the general formula: ##STR1## wherein R1 and R2 each, independently of the other, represent a C1 to C4 alk...
03/05/1985
4474973Acidic mixed oxide catalytic dealkylation to produce 1,4-butanediol and tetrahydrofuran
A coproduct continuous dealkylation process is described in which 4-t-butoxy-n-butanol is contacted with acidic silica-alumina catalyst at temperatures in the 160°-200° C. range (reactor wall temperature) in the liquid hourly space velocity regime of 2:...
10/02/1984
4368337Process for converting glycol dialkyl ether
A process is described for converting glycol dialkyl ether without substantial formation of olefin oligomers by reaction with water, comprising reacting a feed glycol di-tertiary alkyl ether represented by structural formula (A) with water using a strongl...
01/11/1983
4313008Synthesis of S-3-chloro-1,2-propanediol
The S-enantiomer of 3-chloro-1,2-propanediol is prepared by reaction of a chlorodeoxy-D-saccharide having the partial structure. ##STR1## to cleave the glycol, reduce the aldehyde so formed to an alcohol, and hydrolyse the alcohol under mild acidic c...
01/26/1982
4287127Production of tetrahydrofuran
Tetrahydrofuran is produced by converting allyl alcohol to an allyl t-alkyl or -cycloalkyl ether of the general formula: ##STR1## wherein R1 and R2 each, independently of the other, represent a C1 to C4 alk...
09/01/1981
4254290Acidic mixed oxide catalytic de-alkylation of tertiary-alkyl-ether-alkanols
A de-alkylation process which comprises contacting a t-alkylether-alkanol, e.g. 4-t-butylether-n-butan-1-ol, with an acidic solid mixed oxide, e.g. silica-alumina, catalyst which results in the formation of alkanediols, e.g. 1,4-butanediol, in the substan...
03/03/1981
4096192Process for the preparation of 2-methyl-1,3-propanediol
A process for the preparation of 2-methyl-1,3-propanediol (MPD) by recycling mixed diols from the process for the preparation of 1,4-butanediol from acrolein and aliphatic diols until the final product is essentially 1,4-butanediol and MPD....
06/20/1978
4069261Process for the production of polyhydric alcohols
Polyhydric alcohols can be produced in high selectivity from substituted 1,3-dioxanes containing at least one hydroxyalkyl group by heating, in the presence of water, said 1,3-dioxane or mixtures thereof in contact with boric acid, boric acid anhydride or...
01/17/1978
4065511Alcohol production
Selected organic peroxides are converted to the corresponding alcohols when contacted with a triorganophosphine in a reaction medium comprising water and an organic solvent miscible with water. In one embodiment, diene polyperoxides are converted to the n...
12/27/1977
4024197Production of butanediol
2-VINYL-5-METHYL-1,3-DIOXANE IS PROVIDED AS A NEW CYCLIC ACETAL WHICH, WHEN HYDROFORMYLATED, HYDROLYZED AND HYDROGENATED PROVIDES HIGH YIELDS OF A MIXTURE OF 1,4-BUTANEDIOL AND 2-METHYL-1,3-PROPANEDIOL....
05/17/1977
4010195Process for producing methyl p-toluate
P-Tolualdehyde freed from reaction-inhibiting substances is autooxidized by a gas containing molecular oxygen in an aliphatic ketone or fatty acid ester solvent under pressure in the absence of catalyst to produce per-p-toluic acid. The resulting per-p-to...
03/01/1977
3947503Manufacture of 1,6-hexanediol from butadiene
1,6-Hexanediol is manufactured by hydroformylation of 1,3-butadiene by a process wherein an acetal of pent-3-en-1-al is formed in a first hydroformylation step in the presence of lower alkanols or alkanediols and of rhodium catalysts, and is then converte...
03/30/1976
3933923Process for the manufacture of vicinal glycols
A process for the manufacture of higher vicinal diols or polyols by hydrolysis of the corresponding mono- or poly-epoxides, characterized in that the hydrolysis is carried out using aqueous solutions of salts of aliphatic mono- and/or polycarboxylic acids...
01/20/1976
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