The ice cream cone was invented at the St. Louis Worlds Fair by Ernest Hamwi in 1904. His waffle booth was next to an ice cream vendor who ran short of dishes. Hamwi rolled a waffle to hold ice cream and the cone was born.
Make the Most of Our Site
See this month's Top Inventors and Most Cited Patents.
Stay on top of the latest innovations by subscribing to an RSS feed.
Registered users: Manage your profile.
| Number | Title | Issue Date |
| 7560601 | Method for producing 3-methyl-1,5-pentanediol Provided is a method for producing 3-methyl-1,5-pentanediol by hydrogenating 2-hydroxy-4-methyltetrahydropyran in the presence of a hydrogenation catalyst, characterized in that the hydrogenation is further carried out in the presence of a basic compound. By this me... | 07/14/2009 |
| 7230145 | Catalyst for producing both end-hydroxyl group-terminated diols, process for producing the catalyst, process for producing the diols by using the catalyst, and both end-hydroxyl group-terminated diols obtained by the process A process for producing a both end-hydroxyl group-terminated diol, wherein an epoxy alcohol represented by the general formula (1) is subjected to a hydrogenolysis reaction in the presence of a catalyst for producing both end-hydroxyl group terminated diols, which c... | 06/12/2007 |
| 6750373 | One-step production of 1, 3-propanediol from ethylene oxide and syngas with a cobalt-iron catalyst Disclosed is a new catalyst composition comprising a bimetallic Co—Fe catalyst, optionally complexed with a ligand selected from a N-heterocycle, phosphine, or porphorine ligand, that provides a lower cost alternative for the one step synthesis of 1,3-propanediol ... | 06/15/2004 |
| 6586643 | One-step production of 1,3-propanediol from ethylene oxide and syngas with a catalyst with a N-heterocyclic ligand Disclosed is a new catalyst composition comprising a bimetallic Co--Ru catalyst complexed with a N-heterocylcic ligand that is effective, economical, and provides improvements in oxidative stability in the one step synthesis of 1,3-propanediol (1,3-PDO) f... | 07/01/2003 |
| 6555720 | Method and system for producing 1,4-butanediol A method and system for producing 1,4-butanediol (1,4-BG), and optionally additionally tetrahydrofuran (THF), that promotes more efficient usage of water (H2 O) is provided. In one aspect, the method is comprised of supplying at least one feed ... | 04/29/2003 |
| 6403845 | Preparation of pentanediols from alkoxydihydropyrans ##STR1## are prepared by single-stage reaction of alkoxydihydropyrans of the formula (II) ##STR2## with water and hydrogen in the presence of a catalyst comprising oxides of nickel, zirconium and copper. In the formulae (I) and (II), R, R', R", R'" can be... | 06/11/2002 |
| 6350714 | Method for preparing a catalyst and catalysts prepared accordingly The present invention relates to a process for preparing a catalyst by activating a catalytic composition which comprises a) at least one metal of group IB or IIB or a compound thereof, b) where appropriate a carrier which comprises treating the composition with an... | 02/26/2002 |
| 5981811 | Process for preparing polyprenols A process for the preparation of a polyprenol represented by formula (1): ##STR1## where Y and Z individually represent a hydrogen atom or are coupled together to form a carbon-carbon bond; R represents a hydrogen atom or a protective group for a hyd... | 11/09/1999 |
| 5952533 | Method of producing 1,6-hexane diol from epoxybutadiene 1,6-Hexanediol is prepared by a) Reacting epoxybutadiene in the presence of a metathesis catalyst with elimination of ethene to give bisepoxyhexatrienes of the formulae Ia and Ib ##STR1## and b) hydrogenating these bisepoxyhexatrienes with hydrogen t... | 09/14/1999 |
| 5945571 | Preparation of 1,4-butanediol Described is a method of producing 1,4-butanediol, the method calling for 2,3-dihydrofuran to be decomposed in a single stage over a hydrogenation catalyst in the presence of water and hydrogen at a temperature of 20 to 300° C. and a pressure of 1 to 300... | 08/31/1999 |
| 5905159 | Method of producing 1,4-butanediol and tetrahydrofuran from furan 1,4-butanediol and THF are prepared from furan by a process which comprises converting furan in the presence of water and hydrogen but in the absence of a water-soluble acid in a single stage over a hydrogenation catalyst, the hydrogenation catalyst conta... | 05/18/1999 |
| 5583270 | Process for the preparation of 1,3-butylene glycol Disclosed are the improvements of a process for the preparation of 1,3-butylene glycol, in which the generation of by-products can be decreased, resulting in being capable of productiong 1,3-butylene glycol having high quality (e.g. an odorless, so-called... | 12/10/1996 |
| 5508394 | Citric esters of polyhydroxy compounds and use thereof in detergents Esters of citric acid or acetylcitric anhydride with compounds of at least 3 OH groups selected from the group consisting of polyglycerol, sugarcarboxylic acids, alkyl glucosides, derivatives of oligosaccharides, aminosorbitol, aminodisorbitol, glucosamin... | 04/16/1996 |
| 5481048 | Method for preparing copper-containing hydrogenation reaction catalyst and method for producing alcohol A copper-containing hydrogenation reaction catalyst is prepared by reducing a precursor of a copper-containing catalyst usable in hydrogenation reaction with hydrogen gas or a mixture of hydrogen and an inert gas by liquid phase reduction in a stream of a... | 01/02/1996 |
| 5414138 | Process for producing 2-formyl-1,4-butanediol A process for producing 2-formyl-1,4-butanediol comprises effecting reaction of 2-butene-1,4-diol with hydrogen and carbon monoxide in the presence of: (a) a rhodium compound, (b) a tris(substituted aryl) phosphite having an electronic parameter, .nu.-val... | 05/09/1995 |
| 5395992 | Synthesis of diols, for use as intermediates for polymeric materials, by starting from terminal diolefins Disclosed is the synthesis of terminal diols, which are organic intermediates used in order to produce polymeric materials, by starting from terminal diolefins, which synthesis is based on the oxidation of diolefins to yield diepoxides, in a double-phase ... | 03/07/1995 |
| 5364987 | Process for the preparation of 1,3-propanediol 1,3-propanediol (PD) is obtained by hydration of acrolein to 3-hydroxypropionaldehyde (HPA) with subsequent catalytic hydrogenation; 3,3'-oxybis-1-propanol (OD) occurs as a yield-reducing by-product. Disclosed is a process which increases the 1,3-propaned... | 11/15/1994 |
| 5345004 | Process for the preparation of 1,3-butylene glycol Disclosed are the improvements of a process for the preparation of 1,3-butylene glycol, in which the generation of by-products can be decreased, resulting in being capable of producing 1,3-butylene glycol having high quality (e.g. an odorless, so-called "... | 09/06/1994 |
| 5243095 | Hydrogenation catalyst, process for preparing and process for using said catalyst In one embodiment, the invention relates to a catalyst in powdered form comprising the oxides of copper, iron, aluminum and manganese wherein the atomic ratio of copper to iron is at least 1:1. In another embodiment, the invention relates to a process for... | 09/07/1993 |
| 5210337 | Formaldehyde resistant catalyst for hydrogenation and hydrogenolysis of aldehydes, acetals, and esters Rhenium has been found to be formaldehyde resistant catalyst and is thus useful in the catalytic hydrogenation of carbonyls, acetals and esters to alcohols when the reaction medium contains formaldehyde as a reactant or impurity. Also, rhenium is a useful... | 05/11/1993 |
| 5103042 | Method for reducing unsaturation of polyethers Polyethers having terminal allyl unsaturation are subject to hydrogenolysis by reaction with a hydrogen donor in the presence of a n-allyl complex forming catalyst. The product polyethers have extremely low levels of unsaturation, and thus are useful in p... | 04/07/1992 |
| 5087775 | Process for the preparation of partially fluorinated alcohols A process for the preparation of partially fluorinated alcohols starting from halogen-containing alkenes, and 2,2,3,3,4,4-hexafluorocyclopentanol as a new partially fluorinated alcohol.... | 02/11/1992 |
| 4873379 | Process for making 1,3-diols from epoxides A process for manufacturing 1,3-glycols is disclosed. The process comprises reacting an epoxide with synthesis gas in the presence of rhodium in the presence of an alkali metal compound.... | 10/10/1989 |
| 4870208 | Asymmetric hydrogenolysis of epoxides A process of preparing chiral alcohols by the asymmetric catalytic hydrogenolysis of epoxides using rhodium or ruthenium catalysts containing chiral phosphine ligands.... | 09/26/1989 |
| 4861922 | Hydroformylation of 3-methyl-3-buten-1-ol and analogs thereof and use of such hydroformylation products There is disclosed a method of hydroformylating 3-methyl-3-buten-1-ol and analogs thereof with carbon monoxide and hydrogen in the presence of a rhodium compound free from modification by a ligand containing an element belonging to the group V of the peri... | 08/29/1989 |
| 4859801 | Synthesis of mixtures of butanediols Process for preparing 2-alkyl-1,4-butanediols and mixtures with 1,4-butanediol which comprises bringing together, at an initial alkaline pH, and at a temperature and pressure suitable for reaction, 2,3-dihydrofuran, hydrogen, an unsubstituted aliphatic al... | 08/22/1989 |
| 4663468 | Hydroformylation of 3-methyl-3-buten-1-ol and analogs thereof and use of such hydroformylation products There is disclosed a method of hydroformylating 3-methyl-3-buten-1-ol and analogs thereof with carbon monoxide and hydrogen in the presence of a rhodium compound free from modification by a ligand containing an element belonging to the group V of the peri... | 05/05/1987 |
| 4476332 | Preparation of alkanediols Disclosed is an improved process for producing alkanediols by the hydrolytic reduction of hydrolytically reducible furans. The improvement comprises utilizing a supported ruthenium catalyst, and trihaloacetic acid or a mixture thereof as a promoter for th... | 10/09/1984 |
| 4475004 | Preparation of alkanediols Disclosed is an improved process for producing alkanediols by the hydrolytic reduction of hydrolytically reducible furans. The improvement comprises utilizing a supported nickel catalyst, and trihaloacetic acid, preferably trifluoracetic acid or trichloro... | 10/02/1984 |
| 4224248 | Process for the depyrophorization of pyrophoric metal catalysts and uses thereof A process has been developed for the depyrophorization of pyrophoric metal catalysts, such as Raney nickel catalysts, which comprises treating said pyrophoric metal catalysts in water and/or an organic solvent with an organic nitro compound or a nitroso c... | 09/23/1980 |
| 4160771 | Synthesis of tetrahydrofuran This invention provides a process for producing tetrahydrofuran by the reaction of 3-(5'-alkyl-1',3'-dioxane)propionaldehyde and/or 3-(5'-alkyl-1',3'-dioxane)propanol and/or 4-hydroxybutanal with hydrogen in an aqueous medium having a pH between about 0.1... | 07/10/1979 |
| 4146741 | Conversion of furan to 1,4-butanediol and tetrahydrofuran Furan is hydrogenated in the presence of a nickel catalyst and a dicarboxylic acid having 4 to 10 carbons to produce 1,4-butanediol and tetrahydrofuran.... | 03/27/1979 |
| 4123444 | 2-Alkoxy-tetrahydrofurans via hydroformylation of allylic alcohols 2-Alkoxytetrahydrofurans are prepared by hydroformylation of an allylic alcohol in the presence of an alkanol and a rhodium hydroformylation catalyst. The products are useful, inter alia, as intermediates in the preparation of butanediols and substituted ... | 10/31/1978 |
| 4101588 | Production of bis-(dimethyl) acetals of hexane dialdehydes An improved process for the production of aliphatic or cycloaliphatic dialdehydes or acetals of the same by reaction of an aliphatic or cycloaliphatic conjugated diene with carbon monoxide and hydrogen in the presence of a rhodium catalyst which is modifi... | 07/18/1978 |
| 4088700 | Process for the hydrogenolysis of dioxolanes An improved process for the hydrogenolysis of acetals and ketals of organic hydrocarbons is described. The improvement resides in using a catalyst system including a halide of a Group III A element and a supported platinum or rhodium hydrogenation catalys... | 05/09/1978 |
| 3975449 | Hydrogenation of epoxides to primary alcohols A process for producing a primary diol and/or triol from an epoxide which comprises contacting the epoxide with hydrogen gas and a solid catalyst comprising nickel or cobalt at a temperature between 20° and 200°C. and at a pressure sufficient to maintai... | 08/17/1976 |
| 3966827 | Production of 3-methylpentane-1,5-diol The production of 3-methylpentane-1,5-diol by hydroformylation of 2-methylbut-1-en-4-ol with carbon monoxide and hydrogen at elevated temperature and superatmospheric pressure in the presence of a rhodium carbonyl complex which has been modified by a tert... | 06/29/1976 |
| 3963754 | 2-Vinyl-5-methyl-1,3-dioxane 2-Vinyl-5-methyl-1,3-dioxane is provided as a new cyclic acetal which, when hydroformylated, hydrolyzed and hydrogenated provides high yields of a mixture of 1,4-butanediol and 2-methyl-1,3-propanediol.... | 06/15/1976 |