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Class 568/799 - Preparing by reduction or dehydrogenation (e.g., by hydrogenation, etc.)


Subclass of Class 568 - Organic compounds -- part of the class 532-570 series
Definition: Processes which include forming the compound by reduction
No. of patents: 86
Last issue date: 01/11/2011


1      
NumberTitleIssue Date
7868210Process for the preparation of phenol
A process is described for the preparation of phenol by the hydrodeoxygenation of polyhydroxylated benzene derivatives or by the selective hydroxylation of benzene under depletive conditions, characterized in that the above-mentioned reactions are carried out in the...
01/11/2011
7462747Process for preparing polyalcohols from formaldehyde having a low formic acid content
The invention relates to a process for preparing polymethylol compounds of the formula (I) where the radicals R are each, independently of one another, a further methylol group or an alkyl group having from 1 to 22 carbon a...
12/09/2008
7425657Palladium catalyzed hydrogenation of bio-oils and organic compounds
The invention provides palladium-catalyzed hydrogenations of bio-oils and certain organic compounds. Experimental results have shown unexpected and superior results for palladium-catalyzed hydrogenations of organic compounds typically found in bio-oils. ...
09/16/2008
7388116Hydrogenation of methylolalkanals
Process for the catalytic hydrogenation of methylolalkanals of the general formula where R1 and R2 are each, independently of one another, a further methylol group or an alkyl group having from 1 to 22...
06/17/2008
7371358Catalyst for treatment and control of post-combustion emissions
The present invention utilizes two precious metals with two to five different metal-oxides in a layered matrix to convert CO, HCs, and NOx to CO2, and N2 by oxidation of two components and reduction of the other in a moderately high temperature...
05/13/2008
7358399Process for the preparation of N,N-diisopropyl-3-(2-hydroxy-5-methylphenyl)-3-phenyl-propaneamine
A process is described for the preparation of N,N-diisopropyl-3-(2-hydroxy-5-methylphenyl)-3-phenyl-propaneamine comprising substitution of the sulfonyloxy group of the compound of the formula in which the substituents R an...
04/15/2008
7312365Process for low temperature cleavage of an oxidation mixture comprising hydroperoxides
A process for cleaving an oxidation product comprising s-butyl benzene hydroperoxide and/or cumene hydroperoxide which reduces the production of non-recoverable by-products from dimethylbenzyl alcohol (DMBA) and ethyl methyl benzyl carbinol (EMBA). ...
12/25/2007
7282613Process for producing phenol and methyl ethyl ketone
A process for producing phenol and methyl ethyl ketone (MEK). ...
10/16/2007
7230141Method for producing toluol derivatives
A process for preparing toluene derivatives of the formula I, where R1, R2 and R3 independently of one another are hydrogen, halogen, C1–C6-alkyl, hydroxyl...
06/12/2007
7208438Catalyst and method for the alkylation of hydroxyaromatic compounds
A method of making a catalyst comprising mixing a metal oxide precursor and a pore former to form a metal oxide precursor mixture and calcining the metal oxide precursor mixture in the presence of a flowing gas having a flow rate to form the catalyst comprising meta...
04/24/2007
7141703Process for producing phenol and ketone using neutralizing base
Improved processes for oxidizing alkylbenzene(s) to produce phenol and ketone product(s) using neutralizing base. ...
11/28/2006
7119237Process and catalyst for preparing alcohols
Alcohols prepared by reacting carboxylic acids and/or carboxylic esters with hydrogen in the presence of a special catalyst. ...
10/10/2006
6984744Phosphine ligands
The invention is concerned with new phosphine ligands of formula I wherein R1 and R2 are independently of each other unsubstituted alkyl, aryl, cycloalkyl or heteroaryl, or alkyl, ary...
01/10/2006
6936738Process for the preparation of phenol by means of the hydrodeoxygenation of benzene-diols
A process is described for the preparation of phenol characterized in that the phenol is obtained by means of the hydrodeoxygenation of benzene-diols with hydrogen, operating in continuous, in an aqueous solution, at temperatures ranging from 250 to 500° C., at pre...
08/30/2005
6806395Process for preparation of 3,5-bisalkylphenols
A process for producing a 3,5-bisalkylphenol (2) according to the following reaction scheme: (wherein R1 represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, or a hydroxyl-protecti...
10/19/2004
6765118Method for the production of alcohols on rhenium-containing activated charcoal supported catalysts
In a process for the preparation of alcohols by catalytic hydrogenation of carbonyl compounds, the catalyst used is 0.01 to 50% by weight of rhenium and 0 to 20% by weight, in each case based on the total weight of the catalyst, of at least one further metal chosen ...
07/20/2004
6676919Method for producing platinum metal catalysts
The invention relates to a method for producing catalysts by immersion coating a metallic support with at least one platinum metal. An aqueous medium which comprises at least one platinum metal complex, at least one reduction agent and at least one comple...
01/13/2004
6555717Catalytic dehydroxylation of diols and polyols
Secondary alcohols, specifically diols and polyols, are dehydroxylated to the corresponding primary alcohols using a homogeneous organometallic ruthenium complex catalyst....
04/29/2003
6508753Chiral ligands for asymmetric catalysis
A novel phosphine ligand is an enantiomerically enriched compound of formula 5 ##STR1## or the opposite enantiomer thereof, wherein Ar1 and Ar2 represent the same or different aromatic groups of up to 20 C atoms. A transition me...
01/21/2003
6486337Ruthenium-disphosphine complexes and their use as catalysts
The present invention concerns novel complexes, suitable in particular for use as catalysts in the asymmetric hydrogenation of ketones, of formula 1 ##STR1## or a diastereoisomer thereof, wherein each Ar is an aromatic or heteroaromatic group of up to 20 atoms...
11/26/2002
6201160Preparation of alcohols
Alcohols are prepared by the catalytic hydrogenation of the corresponding carbonyl compounds at elevated temperatures and at superatmospheric pressure in the liquid phase by a process in which the catalyst used contains copper on an SiO2 -conta...
03/13/2001
6156933Supercritical hydrogenation
Process for the selective hydrogenation of alphatic or aromatic substrates under supercritical or near critical conditions. Hydrogenation is effected using a heterogeneous catalyst in a continuous flow reactor containing a supercritical or near critical r...
12/05/2000
6140545Preparation of alcohols
In a process for preparing alcohols by gas phase hydrogenation of carboxylic acids or esters thereof at elevated temperature and elevated pressure in the presence of catalysts consisting of or comprising, as hydrogenating components, oxides of main group ...
10/31/2000
6054627Hydrogenation catalyst, process for preparing and process of using said catalyst
Disclosed are catalysts in powdered form comprising a major amount of the oxides of a first metal selected from copper or zinc, a second metal selected from chromium, molybdenum, tungsten and vanadium, and optionally, a minor amount of the oxide of a prom...
04/25/2000
6015927Process for preparing cyclohexanones by hydrogenation of the corresponding phenols (II)
Substituted or unsubstituted cyclohexanones are advantageously prepared by hydrogenation of the corresponding phenols in the presence of a palladium-on-carbon catalyst at from 100 to 250° C. and from 1 to 20 bar of hydrogen pressure if the reaction is ca...
01/18/2000
5969196Process for preparing 3,5-dimethylphenol
For the preparation of 3,5-dimethylphenol by catalytic demethylation of isophorone in the gas phase in the presence of a metal or a metal alloy as catalyst, an isophorone-containing process stream is guided through reaction zones that contain said catalys...
10/19/1999
5874649Process for preparing unsaturated alcohol
The object of the present invention resides in efficiently providing unsaturated alcohol from an ଱,ଲ-unsaturated aldehyde. The present invention provides a process for preparing unsaturated alcohol by selectively reducing the aldehyde group of an ...
02/23/1999
5817891Preparation of alkylphenols
A process for the preparation of alkylphenols of the formula I ##STR1## in which R1, R2, R3, R4, and R5 stand for hydrogen or C1 -C8 alkyl, by reaction of an alkylcyclohex-2...
10/06/1998
5763353Hydrogenation catalyst precursor, hydrogenation catalyst and production process for alcohols
The present invention provides a hydrogenation catalyst precursor which does not bring about a problem of environmental pollution involved in copper-chromium catalysts and has a high activity, a high durability and a high selectivity as compared with thos...
06/09/1998
5723694Process for preparing monomethylated or dimethylated phenols
Phenols monomethylated or dimethylated in the ortho or para position to the OH group and having the formula ##STR1## can be prepared by reaction of tert-alkyl-substituted phenols of the formula ##STR2## in which at least one free ortho or p...
03/03/1998
5663458Process for producing ଱-phenylethyl alcohol
According to a process for producing ଱-phenylethyl alcohol by hydrogenation of acetophenone, which uses a copper-based catalyst containing at least one alkaline earth metal carbonate and/or at least one alkali metal compound, the hydrogenolysis of s...
09/02/1997
5639922Process for treatment of hydroperoxide mixture
A process is described for the selective decomposition of aromatic primary hydroperoxides by contacting a hydroperoxide mixture containing aromatic primary hydroperoxides and aromatic tertiary hydroperoxides obtained by oxidation of alkylaromatic compound...
06/17/1997
5614641Process for enantioselective hydrogenation of the oxo C.dbd.O double bond
The present invention concerns a process for enantioselective catalytic hydrogenation of the ketone C.dbd.O double bond to a secondary alcohol function, said process using a neutral ruthenium complex as the catalyst and a compound containing a C.dbd.O gro...
03/25/1997
5600026Process for production of cresols
There is disclosed a process for the production of cresols, including the steps of: (a) conducting oxygenation of cymene with oxygen gas or an oxygen-containing gas, thereby obtaining a solution of oxygenation products containing tertiary and primary hydr...
02/04/1997
5576467Method of preparing an alcohol
The present invention relates to a method of preparing an alcohol by reducing a carboxylic acid or a derivative thereof, more particularly, a method of preparing an alcohol by a reduction reaction in the presence of a zirconium-titanium oxide catalyst. A ...
11/19/1996
5495054Tetrahydroindeno[1,2-D][1,3,2]oxazaboroles and their use as enantioselective catalysts
A method for the enantioselective reduction of prochiral ketones using catalytic amounts of tetrahydroindeno[1,2-d][1,3,2] oxazaboroles of formula II is disclosed. ##STR1## The oxazaboroles can be generated in situ from the corresponding cis-1-a...
02/27/1996
5488173Process for selective ortho-methylation of cyclohexanones in the vapor phase
A cyclohexanone having at least one ortho-hydrogen is selectively methylated in the ortho-position in the vapor phase. High conversion of the selected cyclohexanone and high selectivity in the ortho-position are obtained. The reaction products include 2-m...
01/30/1996
5399791Process for production of cresols
There is disclosed a process for the production of cresols, including the steps of: (a) conducting oxygenation of cymene with oxygen gas or an oxygen-containing gas without any addition of an alkali, thereby obtaining a solution of oxygenation products co...
03/21/1995
5227538Catalytic asymmetric reduction of ketones using metal catalysts
A process is provided for the catalytic asymmetric reduction of ketones to provide alcohol reaction products which are enriched in one enantiomer. The asymmetric reduction is accomplished utilizing an achiral metal precatalyst in combination with an optic...
07/13/1993
5220020Catalytic reduction of organic carbonyls using metal catalysts
A process is provided whereby organic carbonyl substrates, including esters, lactones, ketones, amides and imides are reduced in a reaction with a silane reducing reagent and a catalyst. Exemplary catalysts include metal alkoxides and metal aryloxides....
06/15/1993
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