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Class 568/323 - Halogen containing reactant (e.g., dehydrohalogenation, etc.)


Subclass of Class 568 - Organic compounds -- part of the class 532-570 series
Definition: Processes wherein the compound is prepared by reacting a
No. of patents: 159
Last issue date: 10/09/2007


1        
NumberTitleIssue Date
7279604Boron carbide as an effective Friedel-Crafts type catalyst
The compound boron carbide, B4C, is an effective catalyst for the alkylation and acylation of aromatics to produce polybenzyls, ketones, esters and alkyl benzenes. The catalyst boron carbide is also effective in conducting intramolecular Friedel-Crafts ty...
10/09/2007
7253323Method for the production of benzophenones
A process for preparing benzophenones of the formula I, where X may be chlorine, hydroxyl, methoxy or C1-C6-alkylcarbonyloxy, and Y may be chlorine or bromine, by reacting an acid chloride o...
08/07/2007
7247742Recycling polyethylene naphthalate containing materials in a process to produce diesters
A process for preparing a dialkylester of a naphthalenedicarboxylic acid comprising directing a liquid phase reaction mixture comprising a low molecular weight alcohol, a naphthalenedicarboxylic acid, a dialkylester of a naphthalenedicarboxylic acid, and a polyethyl...
07/24/2007
7238832Production method of a coupling compound
There is provided a method for producing a coupling compound of formula (1): (Y—)(n−1)R1—R2—(R1)(n′−1)  (1) wherein R1, R2 n and n′ are as defined belo...
07/03/2007
7202384Process for producing 5-nitro-3,4-dihydro-1(2H)-naphthalinone, 1,5-naphthalenediamine and 1,5-naphthalene diisocyanate
The present invention relates to a process for producing 5-nitro-3,4-dihydro-1(2H)-naphthalinone, 1,5-naphthalenediamine and 1,5-naphthalene diisocyanate, in which 4-(2-nitrophenyl)-n-butyronitrile is converted to 4-(2-nitrophenyl)-n-butyric acid. ...
04/10/2007
7148384Preparation of fluorinated acetophenones
The invention relates to a process for preparing fluorinated acetophenones from fluorinated aryl compounds in the presence of N-hydroxyphthalimide and the use thereof. ...
12/12/2006
7129367Phosphine compound, its intermediate, its complex with palladium and a manufacturing method of unsaturated compounds by using the palladium complex
Palladum-phosphine complexes obtained by reacting a 5 compound of formula (1) below with a palladium compound: F(I) (wherein R1 is a hydrogen atom, an alkyl group, a cycloalkyl group or a phenyl group which may be substituted; R2 and R3
10/31/2006
7119235Process utilizing zeolites as catalysts/catalyst precursors
According to one aspect of the invention, there is provided the use of an organic ionic liquid in a zeolite-catalysed process, for example an acylation, alkylation, isomerisation or hydrocracking process in which zeolites act as catalysts or catalyst precursors, esp...
10/10/2006
7087789Methods for nucleophilic fluoromethylation
A novel, convenient and efficient method for trifluoromethylation of substrate compounds is disclosed. Particularly, alkoxide and hydroxide induced nucleophilic trifluoromethylation of carbonyl compounds, disulfides and other electrophiles, using phenyl trifluoromet...
08/08/2006
6984760Acylation of aromatic compounds
This invention particularly relates to a process for the acylation of aromatic compounds by an acylating agent for preparing corresponding acylated aromatic compounds, using a solid catalyst. ...
01/10/2006
6977313Production process of 2,7-dibromofluorenone
A process is provided for the production of 2,7-dibromofluorenone. According to the process, a 2,7-dibromofluorene-contianing raw material is oxidized with molecular oxygen in the presence of a phase transfer catalyst such as a quaternary ammonium salt in a heteroge...
12/20/2005
6943257Process for preparation of aromatic halides from aromatic amines
The present invention provides a process for preparing an aromatic bromide or aromatic iodide from an aromatic amine derivative using nitrite anion and halodimethylsulfonium halide generated in situ from hydrobromic acid/DMSO or hydriodic acid/DMSO. The process for ...
09/13/2005
6933405User- and eco-friendly hypervalent iodine reagent and method of synthesis
The present invention is a user- and eco-friendly hypervalent iodine reagent (mIBX) capable of selectively oxidizing allylic and benzylic alcohols in water and other eco-friendly solvents and having generally the following structure:
08/23/2005
6875894Bis(alkylthio)carbenium salts
The invention relates to bis(alkylthio)carbenium salts of the formula I with the stated definitions for R1, R2, R3 and Y−, and to a process for the preparation th...
04/05/2005
6872855Method for expedient synthesis of [18F]-labeled α-trifluoromethyl ketones
The present invention is directed to a convenient method of synthesizing radiolabeled α-trifluoromethyl ketones by a fluorination reaction. The present invention also relates to imaging agents and markers for identifying cell proliferation, or viral infection. The ...
03/29/2005
6855850Method of manufacturing fluorine compounds, and a method of recovering or regenerating precursors of fluorinating agents
To provide a practical method of manufacturing fluorine compounds in a small number of steps that can carry out fluorination reaction of substrates using easily available fluorinating agents that can be inexpensively produced industrially, and recover precursors of ...
02/15/2005
6849768Sol-gel derived porous microcomposite of perfluorinated ion-exchange polymer and metal oxide
Porous microcomposites have been prepared from perfluorinated ion-exchange polymer and metal oxides such as silica using the sol-gel process. Such microcomposites possess high surface area and exhibit extremely high catalytic activity. ...
02/01/2005
6825383Catalytic process for regiospecific chlorination of alkanes, alkenes and arenes
The present invention provides a process for regiospecific chlorination of an aromatic or aliphatic compound with a chlorine source comprising a metal chloride and other than Cl2 and SO2Cl2 in presence of hypervalent iodine catalyst ...
11/30/2004
6730814Clay based catalytic process for the preparation of acylated aromatic ethers
This invention relates to a process for the preparation of acylated aromatic ethers, in particular the acylation of anisole (methoxybenzene) and veratrole (1,2-dimethoxybenzene) for the preparation of corresponding acylated aromatic ether, namely, p-methoxyacetophen...
05/04/2004
6667422Process for the preparation of ଱-haloketones
A process for preparing an ଱-haloketone of the formula (1) ##STR1## where R1 is an optionally heteroatom-containing and optionally substituted hydrocarbon radical, R2 is a hydrogen, alkyl, aralkyl or aryl radical, and X is a halogen...
12/23/2003
6548710Process for preparing 1-indanones
The present invention relates to a process for preparing 1-indanones of formula I: ##STR1## and isomers thereof, wherein R1, R2, R3, R4, R5, and R6 independently represent H or a C1
04/15/2003
6525226Process for preparation of substituted aromatic compound employing friedel-crafts reaction using a reusable basic anionic clay catalyst
A process for Friedel-Crafts type liquid-phase alkylation or acylation of an aromatic compound using a hydrotalcite-type basic anionic clay catalyst represented by a formula: [(M2+)1-x (M3+)x (OH)2 ]x...
02/25/2003
6476253Process for preparing monoacetylated hydroquinone compounds
The present invention relates to a process for preparing monoacetylated hydroquinone compounds of the formula I, ##STR1## to the novel final products of the process and to a process for preparing the precursors....
11/05/2002
6437191Process for the acylation of aromatic compounds using a reusable solid catalyst comprising indium halide
A process for the liquid phase acylation of aromatic compounds by acyl halides to corresponding acylated aromatic compounds, using a reusable solid catalyst comprising indium halide represented by a formula: Mx In1-x Ay(a)/s wherein, S is...
08/20/2002
6420608Process for the preparation of trifluoromethyl acetophenone
A process for the preparation of a compound of formula I ##STR1## wherein Y is a group that is inert during preparation of the compound and m is from 0 to 4 is described. The process broadly involves the steps of a) reacting a compound of formula II ...
07/16/2002
6417357Coupling reactions with palladium catalysts
This invention relates to a novel, inventive process for the preparation of biphenyls or aromatic olefins by coupling reactions of the Suzuki coupling and Heck coupling type, using allylpalladium catalysts of the μ-halo(triisopropylphosphine)(η3
07/09/2002
6410796Process for the preparation of poly(fluoroalkyl)acetophenones
Acetophenones which are di- or polysubstituted by fluoroalkyl groups on the aromatic ring are prepared in a particularly advantageous manner from the corresponding fluoroalkylanilines and acetaldoxime by preparing a corresponding diazonium salt mixture fr...
06/25/2002
6348631Method for acylation or sulphonylation of an aromatic compound
The present invention relates to a process for the acylation or sulphonylation of an aromatic compound. More particularly, the invention relates to a process for the acylation or sulphonylation of an activated or deactivated aromatic compound. The invention is...
02/19/2002
6303812Isolation of products from selective dehalogenation of haloaromatics
Disclosed is a method of isolating the aromatic product formed when a substrate having the general formula ##STR1## is dehalogenated, forming a product mixture of copper salts and aromatic product, where X is the halogen removed from the substrate to form...
10/16/2001
6300522Process for the preparation of 2-hydroxyalkyl halophenones
A process is provided for the preparation of compounds of Formula (1): ##STR1## wherein X1 and X2 are each independently H, Cl or F, provided that at least one of X1 and X2 is Cl or F; one of R1 and R...
10/09/2001
6281400Process for preparation of a catalytic microcomposite from a silicate and a highly fluorinated ion exchange resin
The present invention relates to a process for preparing a microcomposite comprising a highly fluorinated ion-exchange polymer containing pendant sulfonate functional groups, said polymer existing as aggregated particles entrapped within and dispersed thr...
08/28/2001
6274770Process for preparation of aromatic compounds
##STR1## There is disclosed a process for the preparation of a compound of general formula (I), wherein Y and Z each independently represent a fluorine atom or a hydroxy group, and a, b, c and d independently represent 0, 1, 2 or 3 provided that the sum o...
08/14/2001
6271421Process for selective mono-debromination of polybromoalkyl aryl or heteroaryl ketones
A process for selectively debrominating polybromoalkyl aryl ketones and polybromoalkyl heteroaryl ketones is disclosed. The process comprises contacting an alpha-polybrominated ketone with an alkali metal sulfite in the presence of a C2 -C...
08/07/2001
6211413Process for the preparation of phenyl alkyl ketones and benzaldehydes
There is provided a process for the preparation of compounds of formula I ##STR1## wherein: X is H or F, Y is CF3 or F and R1 is hydrogen or C1 -C2 alkyl; in which process ##STR2## (1) a compound of formula II, where...
04/03/2001
6211399Pressurized chlorination and bromination of aromatic compounds
Disclosed is a method of adding 1 to 4 chlorine or bromine atoms to an aromatic ring of compound that has at least one electron-withdrawing groups on that ring. The aromatic compound is reacted with a chlorinating agent or a brominating agent in the prese...
04/03/2001
6194599Process for preparing biaryl compounds
The present invention provides a process for preparing biaryl compounds comprising reacting an arylzinc reagent with an arylchloride in the presence of a nickel catalyst or a palladium catalyst. The present invention specifically provides a process for th...
02/27/2001
6184418Aromatic compound acylation method
A method for acylating an aromatic compound, specifically an activated or deactivated aromatic compound, is disclosed. The method is suitable for preparing aromatic ketones. The preparation of a catalyst and novel bismuth compounds is also disclosed. Said...
02/06/2001
6147049Tetra-hydronaphthalenes
The present invention provides compounds of formula I: ##STR1## wherein R1 is hydrogen or methyl and R2 is alkyl. These compounds are useful as fixatives in fragrance compositions. Processes of making such compounds are also pro...
11/14/2000
6139770Photoinitiators and oxygen scavenging compositions
An oxygen scavenging composition or system is provided comprising an oxygen scavenging material, a photoinitiator, and at least one catalyst effective in catalyzing an oxygen scavenging reaction, wherein the photoinitiator comprises a benzophenone derivat...
10/31/2000
6133409Process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and ଱ଲ-unsaturated carboxylic acid and aldehyde compounds
This invention is directed to a process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and ଱,ଲ-unsaturated carboxylic acid and aldehyde compounds and to polymeric hydroxylamine resin compounds useful therefor....
10/17/2000
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