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Class 560/245 - Gas phase


Subclass of Class 560 - Organic compounds -- part of the class 532-570 series
No. of patents: 110
Last issue date: 08/12/2008


1      
NumberTitleIssue Date
7411107Alkene separation process
A process for the oxidation of a C2 to C4 alkane to produce the corresponding alkene and carboxylic acid which process comprises separation of the alkene from a mixture of the alkene, the alkane and oxygen by absorption in a metallic salt solut...
08/12/2008
7371706Catalyst for removing hydrocarbons from exhaust gas and method for purification of exhaust gas
A catalyst for removing hydrocarbons from exhaust gas containing methane and an excess of oxygen, which comprises palladium or palladium/platinum supported on at least one carrier selected from zirconia, sulfated zirconia and tungsten-zirconia, and a method for trea...
05/13/2008
7338917Purification catalyst for exhaust gas
A purification catalyst for exhaust gas enhances the activity for each precious metal by effectively utilizing the precious metal without incurring a high production cost, thereby improving endurance. The purification catalyst for exhaust gas comprises a composite o...
03/04/2008
7294734Process for converting a hydrocarbon to an oxygenate or a nitrile
This invention relates to a process for converting a hydrocarbon reactant to a product comprising an oxygenate or a nitrile, the process comprising: (A) flowing a reactant composition comprising the hydrocarbon reactant, and oxygen or a source of oxygen, and optiona...
11/13/2007
7265243Catalytic oxacylation vapor phase process
This invention relates to a catalyst which comprises palladium metal as the main catalyst, tin metal or a mixture of tin and additional metals as the promoter, in combination with an alkali or alkaline earth metal compound, supported on the outer surface of a porous...
09/04/2007
7208136Alcohol steam reforming catalysts and methods of alcohol steam reforming
The present invention provides steam reforming catalyst compositions containing Pd and Zn, and methods of steam reforming alcohols over a catalyst. Surprisingly superior results and properties of the present invention, including low temperature activity and/or low c...
04/24/2007
7202377Process for preparing vinyl acetate
The present invention relates to a method of saturating ethylene-containing gases with acetic acid before they are fed into a vinyl acetate reactor, in which the acetic acid recovered in the vinyl acetate process is introduced into a column having a countercurrent s...
04/10/2007
7201866Concrete test cylinder mold cap
A method and apparatus for molding a reproducible uniform concrete test cylinder. Concrete is poured into a concrete test cylinder mold. A cap having at least one excretion hole is placed on the top portion of the concrete test cylinder mold. The cap is pressed agai...
04/10/2007
7166742Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate
A fluid bed process for the manufacture of vinyl acetate from ethylene, acetic acid and oxygen comprising feeding ethylene and acetic acid into a fluid bed reactor through a first inlet, introducing the oxygen into the reactor through a second inlet, co-joining the ...
01/23/2007
7166557Process for the preparation of a microspheroidal catalyst
Process for preparing a catalyst active for the fluid bed acetoxylation of ethylene to produce vinyl acetate. The process comprises the steps of (a) impregnating microspheroidal silica support particles by the incipient wetness technique with an aqueous solution of ...
01/23/2007
7122707Method for producing an annular shell catalyst and use thereof for producing acrolein
Coated catalysts which are suitable for the gas-phase catalytic oxidation of propene to acrolein are prepared by a process in which rings are used as supports and water is used as a binder. ...
10/17/2006
7087191Shell metal catalyst and a precursor thereof, a process for their preparation and the use of the catalyst
A process for preparing a shell metal catalyst or a precursor of a shell metal catalyst which process includes the steps of: applying a slurry having a diluent; a catalytically active metal or a precursor compound thereof; and optionally a refractory oxide; designat...
08/08/2006
7078563Oxidation process for the production of alkenes and carboxylic acids
A process for the oxidation of a C2 to C4 alkane to produce the corresponding alkene and carboxylic acid which process comprises contacting in an oxidation reaction zone, said alkane, molecular oxygen-containing gas, and the corresponding alken...
07/18/2006
7053024Process for making a catalyst
Process for preparing a supported metal catalyst composition comprising impregnating support particles having a mean diameter of greater than 300 microns with a solution of least one catalytically active metal, or precursor thereof, such that the metal, or its precu...
05/30/2006
7030056Process for preparing a catalyst, the catalyst and a use of the catalyst
A process for preparing a catalyst which process comprises the steps of: (a) introducing a Group 8 metal compound onto a carrier, (b) converting a first portion of the Group 8 metal compound on the carrier into met...
04/18/2006
6987200Process for producing catalysts comprising nanosize metal particles on a porous support, in particular for the gas-phase oxidation of ethylene and acetic acid to give vinyl acetate
The invention relates to a method for producing a catalyst containing one or several metals from the group of metals comprising the sub-groups Ib and VIIIb of the periodic table on porous support particles, characterized by a first step in which one or several precu...
01/17/2006
6959712Method of making a smoking composition
The present invention relates to smoking articles such as cigarettes, and in particular to catalytic systems containing metallic or carbonaceous particles that reduce the content of certain harmful or carcinogenic substances, including polyaromatic hydrocarbons, tob...
11/01/2005
6960278Method of improving the properties of adhesion of a non-oxide ceramic substrate before gluing it
A method of improving the properties of adhesion of a non-oxide ceramic substrate before gluing it includes the steps of irradiating the surface of the ceramic substrate using an excimer laser and applying a coupling agent to the irradiated surface. ...
11/01/2005
6936568Selective hydrogenation catalyst
A catalyst for selective hydrogenation of acetylene including a high surface area support material with a surface area at least about 150 m2/g and gold wherein the gold comprises from about 0.05 to about 5.0 weight percent of the catalyst and wherein the ...
08/30/2005
6936564Supported catalyst consisting of metal of the platinum group and obtained by means of controlled electroless deposition
The invention relates to a supported platinum group metal catalyst obtainable by controlled electroless deposition of at least one platinum group metal from a deposition solution which comprises i) at least one homogeneously dissol...
08/30/2005
6903046Metal modified Pd/Ni catalysts
This invention relates to improved catalytic compositions suited for use in hydrogenation processes and to an improved process for hydrogenating organic compounds as in amination of alcohols or hydrogenation of nitro groups to the amine using the catalyst. The catal...
06/07/2005
6852877Process for the production of vinyl acetate
A process for the production of vinyl acetate comprising contacting in a first reaction zone a gaseous feedstock comprising essentially ethane with a molecular oxygen-containing gas in the presence of a catalyst to produce a first product stream comprising acetic ac...
02/08/2005
6825149Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
A shell impregnated catalyst of Pd-Au produced on a silica support to have a Pd loading of 1.8 g/L of catalyst to about 7.2 g/L and a Au to Pd weight ratio of 0.3 to 2.0 by impregnating the support with aqueous solutions of palladium and gold salts or acids and ther...
11/30/2004
6815394Palladium-based catalysts
A phenyl ester is produced by allowing benzene, a carboxylic acid and molecular oxygen to react with each other in the presence of a catalyst comprising (A) palladium, (B) at least one element selected from elements of groups 13, 14, 15, and 16 and the fourth to six...
11/09/2004
6806382Catalyst composition and process for making same
A process for preparing a supported metal catalyst composition which comprises impregnating microspheroidal support particles with a solution of at least one catalytically active metal, or precursor, drying the impregnated support particles and then treating the mob...
10/19/2004
6768013Intrinsically safe oxidation process
A novel process for the direct oxidation of hydrogen and hydrocarbons is disclosed, where the explosion risks inherent in gas phase oxidations are substantially eliminated. Gaseous oxidation reactants are soluble in a first reaction solvent phase such as a perfluoro...
07/27/2004
6696596Catalyst and method for producing vinyl acetate
A process for preparing vinyl acetate in the gas phase from ethylene, acetic acid and oxygen or oxygen-containing gases over a catalyst, consisting essentially of palladium and/or its compounds, gold and/or its compounds and alkali metal compounds on a su...
02/24/2004
6620965Process for vinyl acetate
A process for producing vinyl acetate comprising reacting ethylene, acetic acid and oxygen together in at least partially liquid phase in the presence of a catalyst comprising a noble metal component....
09/16/2003
6605739Method for producing vinyl acetate monomer from ethane or ethylene oxidation
Methods for the catalytic production of vinyl acetate monomer from ethane, ethylene or an ethanelethylene mixture using a first catalyst containing MoVNbPd, MoVLaPdbX (where X is Al, Ga, Ge or Si) or MoVNbX (where X is P, B, Hf, Te, As or mixtures thereof...
08/12/2003
6548697Oxidation process for the production of alkenes and carboxylic acids
A process for the oxidation of a C2 to C4 alkane to produce the corresponding alkene and carboxylic acid which process comprises contacting in an oxidation reaction zone, said alkane, molecular oxygen-containing gas, and optionally, ...
04/15/2003
6534672Fluid bed vinyl acetate catalyst
A catalytically active material useful to prepare vinyl acetate monomer from ethylene, acetic acid, and an oxygen-containing gas under fluid bed conditions comprises a porous microspheroidal support containing catalytically active palladium crystallites f...
03/18/2003
6528679Process for producing phenyl esters using palladium-based catalysts
A phenyl ester is produced by allowing benzene, a carboxylic acid and molecular oxygen to react with each other in the presence of a catalyst comprising (A) palladium, (B) at least one element selected from elements of groups 13, 14, 15, and 16 and the fo...
03/04/2003
6472556Catalyst and use thereof in the production of vinyl acetate
A catalyst for use in the production of vinyl acetate which comprises (1) a catalyst support, (2) palladium, (3) an acid, (4) at least one acetic acid catalyst promoter and (5) at least one vinyl acetate promoter and/or co-promoter. A process for the prod...
10/29/2002
6448432Process for the production of vinyl acetate
A process for the fluid bed production of vinyl acetate which comprises reacting ethylene, acetic acid and an oxygen-containing gas in a fluid bed reactor at elevated temperature in the presence of a fluidised bed of catalyst, in which process, catalyst i...
09/10/2002
6420595Process control for vinyl acetate manufacture
A method of real time process control in a reaction system for the production of vinyl acetate from the oxidation of ethylene and acetic acid. Reaction system samples are collected from the reactor vessel feed and/or effluent and/or from columns and/or tr...
07/16/2002
6420308Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
A shell impregnated catalyst of Pd--Au produced on a silica support to have a Pd loading of 1.8 g/L of catalyst to about 7.2 g/L and a Au to Pd weight ratio of 0.3 to 2.0 by impregnating the support with aqueous solutions of palladium and gold salts or ac...
07/16/2002
6407283Process for the production of vinyl acetate
A process for the production of vinyl acetate which comprises contacting ethylene, acetic acid and an oxygen-containing gas with a supported palladium catalyst prepared by a process comprising the steps of (a) impregnating a catalyst support with a pallad...
06/18/2002
6399813Process for the preparation of fluid bed vinyl acetate catalyst
A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a metal salt of Pd and M, wherein M comprises Ba, ...
06/04/2002
6376706Catalyst and use thereof in the production of vinyl acetate
A catalyst for use in the production of vinyl acetate which comprises (1) a catalyst support, (2) palladium, (3) an acid, (4) at least one acetic acid catalyst promoter and (5) at least one vinyl acetate promoter and/or co-promoter. A process for the prod...
04/23/2002
6350901Process for the production of vinyl acetate
In a process for production of vinyl acetate in which ethylene, liquid acetic acid and an oxygen-containing gas are fed to a fluid bed reactor containing a catalyst comprising a Group VIII metal, a promoter and a co-promoter, stickiness of the catalyst is...
02/26/2002
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