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Class 558/378 - A nitrile reactant contains no acyclic or alicyclic carbon to carbon unsaturation


Subclass of Class 558 - Organic compounds -- part of the class 532-570 series
Definition: Processes wherein a nitrile reactant contains no acyclic
No. of patents: 64
Last issue date: 09/11/2007


1    
NumberTitleIssue Date
7268247Process for the preparation of phenylmalonic acid dinitriles
Phenylmalonic acid dinitriles are prepared by reaction of, for example, phenyl Kalides with malonic acid dinitrile in the presence of palladium catalysts and bases. ...
09/11/2007
7238832Production method of a coupling compound
There is provided a method for producing a coupling compound of formula (1): (Y—)(n−1)R1—R2—(R1)(n′−1)  (1) wherein R1, R2 n and n′ are as defined belo...
07/03/2007
7041856Coupling catalyst and process using the same
There are disclosed a process for producing a coupling compound of formula (1): (Y—)(n−1)R1—R2—(R1)(n′−1),  (1) wherein R1 and R2
05/09/2006
7005534Method for producing hydrolysis-stable ammonium nitriles
The invention relates to a method for producing hydrolysis-stable ammonium nitriles by reacting a compound of formula (1), wherein R1, R2, and R3 are identical or different and represent linear or branched C1–C24
02/28/2006
6790975Aminostyrylanthracene compound, synthetic intermediate thereof, and process for the production thereof
This invention is an aminostyrylanthracene compound represented by, for example, the following general formula [I]. This compound is produced by condensation from a corresponding aminobenzaldehyde and a phosphonic ester or phosphonium salt. ...
09/14/2004
6506926Process for the preparation of 2-alkythiobenzonitrile derivatives
A process for preparing a compound of the formula: ##STR1## which comprises reacting a compound of the formula: ##STR2## wherein R3 is nitro or halo, with a compound of formula R1 S--X wherein X is hydrogen or alkali metal....
01/14/2003
6433214Process for the preparation of 2-(4-methylphenyl)-benzoic acid derivatives
A process for the preparation of 2-(4-methylphenyl)benzoic acid C1-6 alkyl esters by reaction of a sulfonic derivative of formula ##STR1## wherein R is C1-6 alkyl and R1 is optionally perfluorinated C1-6 alkyl o...
08/13/2002
6433209Alpha-substitution of unprotected ଲ-amino ester compounds
Methods for stereoselective substitution in which a (mono or un)-଱-substituted unprotected ଲ-amino ester compound or salt thereof is reacted with an aliphatic electrophile in the presence of a base selected from alkyl lithium compounds, lithiu...
08/13/2002
6407253Method for preparing 4-methyl-biphenyl derivatives
The subject-matter of the invention is a process for the preparation of substituted 4-methylbiphenyls of general formula: ##STR1## in which R is a cyano group or a protected tetrazolyl group of formula: ##STR2## in which R1, situated at the 1 o...
06/18/2002
6392111Method for producing olefins
Olefins containing aromatic substituents are synthesized without the addition of phosphonium salts or phosphanes with the aid of a PdII compound as a catalyst in the presence of nitrogen-containing additives such as N,N-dimethylglycine and a ba...
05/21/2002
6392080Process for the preparation of a cyanobiphenyl
The subject-matter of the invention is a process for the preparation of o-(p-tolyl)benzonitrile, characterized in that an o-halobenzonitrile is treated with a p-tolylmagnesium halide in the presence of a manganous salt and of a cocatalyst comprising a tra...
05/21/2002
6291730Process for the manufacture of halocarbons and selected compounds and azeotropes with HF
A liquid phase process is disclosed for producing halogenated alkane adducts of the formula: CAR1 R2 CBR3 R4 (where A, B, R1, R2, R3, and R4 are as defined in the spec...
09/18/2001
6218564Process for the preparation of substituted aromatic compounds
A process for the preparation of a substituted aromatic compound in which a chloroaromatic compound and an alkyl-, alkenyl- or aryl-boronic acid ester or anhydride are coupled in the presence of palladium and a lipophilic aliphatic phosphine comprising at...
04/17/2001
5922898Process for preparing biaryl compounds
The present invention provides a process for preparing biaryl compounds comprising reacting an arylmetal reagent selected from arylmagnesium reagents and aryllithium reagents with an arylhalide in the presence of a catalyst system comprising a catalyst se...
07/13/1999
5892094Process for preparing 4'-methyl-2-cyanobiphenyl
Process for preparing 4'-methyl-2-cyanobiphenyl, comprising, catalytically hydrogenating at least one brominated cyanobiphenyl compound selected from 4'-dibromomethyl-2-cyanobiphenyl and 4'-bromomethyl-2-cyanobiphenyl; and process for regenerating 4'-meth...
04/06/1999
5856557Process for producing hexafluorobiphenyl -3,3',4,4'-Tetracarboxylic acid precursors
A 2,2',5,5',6,6'-hexafluorobiphenyl-3,3',4,4'-tetracarboxylic acid precursor as an intermediate material for a highly functional fluororesin may be produced at a high yield by reacting tetrafluorophthalonitrile with an alkali metal iodide....
01/05/1999
5763639Process for producing quarternary glycine nitriles
A process for preparing quaternized glycine nitriles of formula I ##STR1## comprising reaction of the corresponding precursor amine, aldehyde, hydrocyanic acid or alkali metal cyanide, and subsequent quaternization with an alkylating agent, wherein t...
06/09/1998
5739375Methylation of organic compounds
Methyl compounds are prepared from carbon acids by reaction with dimethyl carbonate in the presence of a nitrogen-containing base....
04/14/1998
5449808Method for converting amides to nitriles and nitriles to amides
A process which comprises contacting and catalytically reacting under essentially anhydrous conditions in the liquid phase an amide with a nitrile according to the equation: RCONH2 +R1 CN.revreaction.RCN+R1 CONH2 whe...
09/12/1995
5288912Process for the preparation of lithium diarylphosphides and alkylated derivatives thereof
Disclosed is a process for the preparation of alkali metal diarylphosphide compounds wherein at least one of the aryl radicals is substituted with an alkyl group. Also disclosed is the preparation of alkyl(diaryl)phosphine compounds which are obtained by ...
02/22/1994
5288895Process for the preparation of a biphenyl derivative
The subject of the invention is a process for the preparation of 4-methyl-2'-cyanobiphenyl of formula: ##STR1## wherein a benzonitrile halide of general formula: ##STR2## in which Hal represents a halogen atom, is reacted, in the presence of a ...
02/22/1994
5179222Process for preparing phenyl butyronitriles and perfumery use of 2,2-dimethyl-4-phenyl valeronitrile
Described is the use in imparting, augmenting or enhancing aromas to or in perfume compositions, colognes and perfumed articles by admixing therewith an aroma imparting, augmenting or enhancing quantity of 2,2-dimethyl-4-phenyl valeronitrile defined accor...
01/12/1993
5099054Organoclay triphase catalysts
In a method of carrying out organic conversions via heterogeneous phase transfer catalysis by contacting immiscible liquid phases containing respective substances capable of interacting, with a solid catalyst to promote the transfer of reactive species fr...
03/24/1992
5089651Process for producing 3-iminonitriles
A process for producing a 3-iminonitrile represented by the following general formula (I): ##STR1## wherein M represents an alkali metal, which comprises reacting acetonitrile with an alkali metal hydride in an amount of from 0.01 to 0.5 molar e...
02/18/1992
4942221Process for obtaining ଱-amino nitriles and their applications to organic synthesis
The present invention relates to the synthesis of nitriles having an amine function on the adjacent carbon....
07/17/1990
4933470Method of synthesis of vicinal diamines
A method is described for producing vicinal diamines comprising the steps of converting a compound, possessing a leaving group on a carbon atom interposed between carbon atoms containing amino groups, to an aziridine-containing compound and reacting the l...
06/12/1990
4910326ଲ-ketonitrils
A fluorinated ଲ-ketonitrile of the formula: ##STR1## in which: R is alkyl having plural fluorines and R1 is hydrogen or alkyl....
03/20/1990
4894471Continuous process for the alkylation of CH-acid compounds with alkyl carbonates in gas-liquid phase transfer catalysis-conditions
A continuous process for the alkylation of CH-acid compounds with dialkyl carbonates in gas-liquid phase transfer catalysis conditions is described, consisting of contacting a mixture of a CH-acid compound (arylacetonitrile or malonic diester) and of a di...
01/16/1990
4889951Perfluoroalkylation process
Perfluoroalkylaromatic compounds containing at least two carbons in the perfluoroalkyl group are prepared by reacting an aromatic bromide or iodide with a potassium perfluoroalkanoate corresponding to the formula KOOC(CF2)n CF3
12/26/1989
4847401Continuous large-scale production of ethyl 2,2-difluoro-4-pentenoate and 2-fluorinated methyl aminoacetonitriles by use of a flow reactor
The large scale preparation of ethyl 2,2-difluoro-4- pentenoate and 2-fluorinated methyl aminoacetonitriles by reaction of 2-H-perfluoroethyl allyl ether and n-butyl lithium and fluoromethylacetonitrile and a Grignard reagent, respectively, is largly unsu...
07/11/1989
4822904Perfluoroalkylation process
Perfluoroalkylaromatic compounds containing at least two carbons in the perfluoroalkyl group are prepared by reacting an aromatic bromide or iodide with a potassium perfluoroalkanoate corresponding to the formula KOOC(CF2)n CF3
04/18/1989
4814482Trifluoromethylation process
Trifluoromethylaromatic compounds are prepared by reacting the corresponding aromatic bromide or iodide with potassium trifluoroacetate in the presence of cuprous iodide, a phase transfer agent, and a dipolar aprotic solvent....
03/21/1989
4814480Trifluoromethylation process
Trifluoromethylaromatic compounds are prepared by reacting the corresponding aromatic bromide or iodide with a tetraalkylammonium trifluoroacetate in the presence of cuprous iodide and a dipolar aprotic solvent....
03/21/1989
4808748Trifluoromethylation process
Trifluoromethylaromatic compounds are prepared by reacting the corresponding aromatic bromide or iodide with potassium trifluoroacetate in the presence of cuprous iodide and a dipolar aprotic solvent....
02/28/1989
4722808Use of cyclododecenylacetonitrile as a fragrance component
Cyclododecenylacetonitrile is prepared by reacting cyclododecanone with cyanoacetic acid in the presence of a catalyst. Purified cyclododecenylacetonitrile has a pleasant scent reminiscent of roses and lilies of the valley, containing additionally a musk ...
02/02/1988
4716237Process for the production of 3-oxonitriles
3-oxonitriles are produced by reaction of carboxylic acid esters with carboxylic acid nitriles in the presence of 70 to 80% suspension of sodium hydride in white oil. The oxonitrile are intermediate products for the production of 3-oxocarboxylic acid amid...
12/29/1987
4670577Novel process
A novel process for the preparation of pent-4-enoic acids of the formula ##STR1## wherein X is selected from the group consisting of hydrogen, cyano and alkoxycarbonyl of 2 to 5 carbon atoms and Y is selected from the group consisting of hydrogen, cy...
06/02/1987
4667050Preparation of pyrethroid precursors
Substituted vinylcyclopropane carboxylates, useful precursors to pyrethroid insecticides, are prepared by noble metal catalyzed addition of 1-methyl-3-buten-2-yl or 4-methyl-3-penten-1-yl carbonates or carboxylic acid esters to malonic acid diesters, alky...
05/19/1987
4567005Allylation of carbon acids
Carbon acids are allylated by contacting with an allyl carbonate in the presence of an iron, cobalt, nickel, ruthenium, rhodium, osmium, iridium or platinum catalyst....
01/28/1986
4540791Production of ଲ-amino-଱,ଲ-unsaturated carboxylic acid esters
A process for producing a compound of the formula ##STR1## wherein A is aryl or alkyl, R1 is an aromatic radical and R2 is hydrogen, alkyl, aryl, cyano, --COOalkyl or --COOaryl, which process comprises reacting 1 mol of an aroma...
09/10/1985
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