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Patent No. 5285430

Behavior Modification Wristwatch

A wristwatch including a watch band and a watch body having an octagon shaped perimeter and being red in color and having the word STOP thereon to resemble a stop sign.

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Class 558/281 - Plural halo-C(=O)O- groups attached indirectly to each other by nonionic bonding


Subclass of Class 558 - Organic compounds -- part of the class 532-570 series
Definition: Compounds which contain more than one halo-C(=O)O-
No. of patents: 53
Last issue date: 12/18/2007


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NumberTitleIssue Date
7309756Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters
Macrocyclic oligoesters and compositions comprising macrocyclic oligoesters are prepared from intermediate molecular weight polyesters. In one embodiment, a diol is contacted with a dicarboxylic acid or a dicarboxylate in the presence of a catalyst to produce a comp...
12/18/2007
7297754Method for the preparation of aromatic chloroformates
A method for preparing an aromatic chloroformate comprising, introducing a mixture of at least one aromatic hydroxyl compound, phosgene, at least one solvent, and at least one organic base into a flow reactor to obtain a unidirectionally flowing reaction mixture. Th...
11/20/2007
7232865Transparent and high-heat polycarbonate-polysiloxane copolymers and transparent blends with polycarbonate and a process for preparing same
A method is provided for making siloxane polycarbonate copolymers and blends of other polycarbonates with such copolymers wherein the copolymers and blends have excellent transparency and physical characteristic. ...
06/19/2007
7151143Blends containing macrocyclic polyester oligomer and high molecular weight polymer
The invention provides blends of macrocyclic polyester oligomer (MPO) with high-molecular-weight polymer and polymerization catalyst as friable, one-component, ready-to-polymerize materials with long shelf life. The invention also provides methods for preparation an...
12/19/2006
7071291Isolation, formulation and shaping of macrocyclic oligoesters
Processes for isolating, formulating, and shaping macrocyclic oligesters were developed which allow efficient production of macrocyclic oligoesters substantially free from solvent, which may include additives, fillers, and catalysts. ...
07/04/2006
7022806Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters
Macrocyclic oligoesters and compositions comprising macrocyclic oligoesters are prepared from intermediate molecular weight polyesters. In one embodiment, a diol is contacted with a dicarboxylic acid or a dicarboxylate in the presence of a catalyst to produce a comp...
04/04/2006
6994914Macrocyclic polyester oligomers and processes for polymerizing the same
A water slurry process is used to prepare a prepreg and to manufacture articles from macrocyclic polyester oligomers. In one embodiment, a process for preparing a water suspension of macrocyclic polyester oligomers includes the steps of contacting a macrocyclic poly...
02/07/2006
6962968Purification of macrocyclic oligoesters
Acid impurities, such as carboxylic acid-terminated polymers, are removed from macrocyclic oligoesters with ion exchange resins, resulting in macrocyclic oligoesters that are substantially free of acid impurities. The ion exchange resins can be regenerated anew and ...
11/08/2005
6960626Intimate physical mixtures containing macrocyclic polyester oligomer and filler
The invention provides intimate physical mixtures of macrocyclic polyester oligomer (MPO) and filler, as well as methods for their preparation and use. Improved dispersion of filler in a polymer matrix is achieved upon polymerization, and larger amounts of filler wi...
11/01/2005
6911558Method for purifying chloromethyl chloroformate
Describes a method for obtaining substantially pure chloromethyl chloroformate from a chloroformate mixture comprising chloromethyl chloroformate and methyl chloroformate by heating the chloroformate mixture in a reaction zone at temperatures ranging from at least 5...
06/28/2005
6906147Catalytic systems
This invention relates to single-component and multi-component catalytic systems using aryl titanates. Aryl titanate compounds are useful as catalysts and co-catalysts in single-component and multi-component catalytic systems (e.g., for the polymerization of macrocy...
06/14/2005
6613929Process for preparation of fluoroformates
A process for the preparation of fluoroformates of the formula ##STR1## wherein R1 is a saturated or unsaturated, substituted or unsubstituted and primary or secondary aliphatic, a saturated or unsaturated, substituted or unsubstituted secondar...
09/02/2003
6479690Phosgenation under pressure of alcohol's for producing chloroformates
The invention concerns a method for phosgenation of monohydroxy alcohol's and/or polyols characterised in that it consists of treating alcohol and or polyol, whether in the presence of solvent or not, with a molar excess of phosgene, preferably 2 to 30 ti...
11/12/2002
6175017Process for the production of aryl carbonates
A process for the preparation of carbonates containing aromatic ester groups is disclosed. The process entails reacting aromatic monohydroxy componds with phosgene or with chlorocarbonic acid esters of aromatic monohydroxy compounds at a temperature of 50...
01/16/2001
5162564Method for making oligomeric carbonate bischloroformates with low phosgene usage
Oligomeric carbonate bischloroformates are prepared with low phosgene usage by phosgenating a dihydroxyaromatic compound in an interfacial reaction in the presence of small amounts of trialkylamine, preferably, triethylamine. In this invention, the molar ...
11/10/1992
5144055Liquid crystalline bis-chlorocarbonic acid esters
Liquid crystalline bis-chlorocarbonic acid esters are 4-hydroxybenzoic acid-(4'-hydroxyphenyl) esters corresponding to the following formula ##STR1## wherein R1, R2, R3 and R4 denote, independently of one a...
09/01/1992
5142088Preparation of branched polycarbonates and chloroformates, and intermediates therefor
Ester polyphenols such as the tris(bisphenol A) ester of trimellitic acid are prepared by the reaction of the corresponding aromatic poly(acyl halide) with a dihydroxyaromatic compound such as bisphenol A. They may be employed in the preparation of branch...
08/25/1992
5011967Method for preparing aromatic bischloroformate compositions
Bischloroformate oligomer compositions are prepared by passing phosgene into a heterogeneous aqueous-organic mixture containing at least one dihydroxyaromatic compound, with simultaneous introduction of a base at a rate to maintain a specific pH range and...
04/30/1991
5011966Low phosgene method for preparing aromatic bischloroformates
Aromatic bischloroformates are prepared by the reaction of a dihydroxyaromatic compound such as bisphenol A with phosgene in the presence of water, base and an organic liquid such as methylene chloride. Initially, a mixture of the bisphenol, organic liqui...
04/30/1991
4994595Preparation of spirobiindane bisphenol bischloroformate compositions
Bischloroformate compositions are prepared from spirobiindane bisphenols by phosgenation in a substantially inert organic liquid in a two-step reaction. The pH during the first step is maintained in the range of about 8-14 by addition of aqueous base. In ...
02/19/1991
4973729Method for preparing hydroquinone and hydroquinone-bisphenol a Bischloroformates
Bischloroformates of bisphenol compositions comprising hydroquinone or a hydroquinone-bisphenol A mixture are prepared by passing phosgene into a vigorously agitated mixture of water, an alkaline earth metal hydroxide, the bisphenols and a substantially i...
11/27/1990
4904810Bischoloroformate preparation method with phosgene removal and monochloroformate conversion
Aqueous bischloroformates are prepared by the reaction of a dihydroxyaromatic compound (e.g., bisphenol A) with phosgene in a substantially inert organic liquid (e.g., methylene chloride) and in the presence of an aqueous alkali metal or alkaline earth me...
02/27/1990
4814420Detecting the stoichiometric end point of phosgenation reactions
A method is provided for determining the stoichiometric end point of phosgenation reactions which produce polycarbonates and chloroformates, respectively, by monitoring the rate of heat generated by the reaction mixture per unit of phosgene utilized....
03/21/1989
4810813Method for making reaction products of phosgene and dihydric phenol with stable suspension of dihydric phenol, alkali metal hydroxide and water
A method is provided for making reaction products of phosgene and dihydric phenol under interfacial reaction conditions. The dihydric phenol such as BPA is introduced into the reactor in the form of a stable suspension which reduces phosgene hydrolysis, m...
03/07/1989
4767877Nitrogen-containing bisphenol compositions
Bisamide and bisurethane bisphenols and bishaloformates are prepared by the reaction of amines with dicarboxylic acid halides or bisphenol bishaloformates. They are useful as intermediates for the preparation of cyclic heterocarbonates, which may in turn ...
08/30/1988
4722995Detecting the stoichiometric end point of phosgenation reactions
A method is provided for determining the stoichiometric end point of phosgenation reactions which produce polycarbonates and chloroformates, respectively, by monitoring the rate of heat generated by the reaction mixture per unit of phosgene utilized....
02/02/1988
4701544Method for making reaction products of phosgene and dihydric phenol
A method is provided for making reaction products of phosgene and dihydric phenol, such as bischloroformates and polycarbonates utilizing a reactor with an overhead condenser. Reduced phosgene blow-by is achieved by using an absorber for phosgene which is...
10/20/1987
4649210Reducing phosgenation reaction temperatures
A method is provided for reducing the reflux temperatures of methylene chloride in phosgenation reactions by introducing a second inert vaporizable component to the reaction medium. This second inert vaporizable component has a lower vaporization temperat...
03/10/1987
4638077Method for the preparation of chloroformate compositions
Chloroformate compositions, particularly bischloroformate compositions, are prepared by the reaction of phosgene with a hydroxy compound, preferably a dihydroxy compound such as bisphenol A, in a heterogeneous mixture, while adding a hydrogen chloride sca...
01/20/1987
4614829Process for the preparation of ଱-chlorinated chloroformates
Process for the preparation of ଱-chlorinated chloroformates with the formula ##STR1## where R is H, an aliphatic or aromatic hydrocarbon radical or heterocyclic radical, substituted or non-substituted and n an integer. The process consists of r...
09/30/1986
4601858Method for preparing bischloroformate compositions
Bischloroformate compositions are prepared by passing gaseous phosgene into an agitated aqueous solution of a di-(alkali metal) salt of an organic dihydroxy compound such as bisphenol A, while maintaining said solution at a temperature within the range of...
07/22/1986
4592872Process for the synthesis of ଱-chlorinated chloroformates
Process for the synthesis of ଱-chlorinated chloroformates, and new ଱-chlorinated chloroformates. The invention relates to a new process for the manufacture of ଱-chlorinated chloroformates and, to new ଱-chlorinated chloroformates as...
06/03/1986
4592874Process for the synthesis of alpha-chlorinated chloroformates
Process for the synthesis of ଱-chlorinated chloroformates, and new ଱-chlorinated chloroformates. The invention relates to a new process for the manufacture of ଱-chlorinated chloroformates and, to new ଱-chlorinated chloroformates as...
06/03/1986
4568391Sizing agents
The invention provides new sizing agents, in particular for paper, which contain chloroformic acid esters of ester alcohols and/or carboxamide alcohols. The chloroformic acid esters in question preferably have the following idealized structure: wherein X=...
02/04/1986
4415722Branched aromatic polycarbonate from aliphatic polyol
This invention relates to the use of polyol compounds as branching agents for the manufacture of randomly branched novel polycarbonates. The polycarbonates are useful for the fabrication of blow molded articles....
11/15/1983
4411838Unsymmetrical polynitrocarbonates and symmetrical 1,3-bis(halo- and nitroalkyl carbonyldioxy)-2,2-dinitropropanes and methods of preparation
Unsymmetrical carbonates of the formula ##STR1## are prepared by the following reaction sequence ##STR2## where R and R' can each be --CH2 C(NO2)3, CH2 CF(NO..2)2, --CH2 CF2...
10/25/1983
4372877Di(acylperoxy)-1,4-cyclohexane dimethanol-bis-carbonates
Di(acylperoxy)-bis-carbonates of the formula: ##STR1## wherein each R is selected from alkyl and aryl of up to about 20 carbon atoms. The new molecules have exceptional thermal stability, which facilitates storage at ambient temperatures. They have u...
02/08/1983
4332744Unsymmetrical polynitrocarbonates and methods of preparation
Unsymmetrical carbonates of the formula ##STR1## are prepared by the following reaction sequence ##STR2## where R and R' can each be --CH2 C(NO2)3, CH2 CF(NO..2)2, --CH2 CF2...
06/01/1982
4293503Synthesis of polyol bis(allyl carbonate) utilizing reagent recovery and recycle
Disclosed is an improved method of forming polyol (allyl carbonate) monomers. In the disclosed method, the organic by-products as diallyl carbonate and unreacted reagents as allyl alcohol are separated from the brine and wash water derived aqueous phase a...
10/06/1981
4273726Polyol (allyl carbonate) synthesis utilizing solid alkali metal hydroxide
Disclosed is a method of synthesizing a polyol (allyl carbonate) by the alkali metal hydroxide catalyzed reaction of allyl alcohol and a polyol chloroformate where a portion of the alkali metal hydroxide is anhydrous....
06/16/1981
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