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Class 502/166 - Rhodium containing


Subclass of Class 502 - Catalyst, solid sorbent, or support therefor: product or process of making
Definition: Composition which includes element number 45.
No. of patents: 175
Last issue date: 10/13/2009


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NumberTitleIssue Date
7601667Sulfonate catalyst and method of producing alcohol compound using the same
A sulfonate catalyst represented by the formula below and a ketone compound are placed in a solvent, and the ketone compound is hydrogenated by mixing in the presence of hydrogen to produce an optically active alcohol. ...
10/13/2009
7385064Catalysts for use in enantioselective synthesis
Disclosed are compounds having the following formula: in which Z11 is selected from a substituted or unsubstituted saturated adamantyl or other polycyclic group and a substituted or unsubstituted branched acyclic...
06/10/2008
7335800Hydrogenation catalyst and hydrogenation method
The present invention provides a hydrogenation catalyst effective for hydrogenating 3-hydroxypropionaldehyde to 1,3-propanediol. The hydrogenation catalyst comprises an α-alumina support, nickel, ruthenium, and a promoter. The nickel is deposited on the α-alumina ...
02/26/2008
7294602Hydroformylation process
A process for the production of 4-hydroxybutyraldehyde is described. The process comprises reacting allyl alcohol with a mixture of carbon monoxide and hydrogen in the presence of a solvent and a catalyst system comprising a rhodium complex and a trans-1,2-bis(bis(3...
11/13/2007
7250526Transfer hydrogenation process and catalyst
A catalytic transfer hydrogenation process is provided. The catalyst employed in the process is a metal hydrocarbyl complex which is coordinated to defined bidentate ligands substituted with at least one group selected from an optionally substituted sulphonated hydr...
07/31/2007
7223879Ligands for metals and improved metal-catalyzed processes based thereon
One aspect of the present invention relates to ligands for transition metals. A second aspect of the present invention relates to the use of catalysts comprising these ligands in transition metal-catalyzed carbon-heteroatom and carbon-carbon bond-forming reactions. ...
05/29/2007
7217675Catalyst composition
This invention relates to transition metal catalyst compounds represented by the formula: LMX2 wherein M is a Group 7 to 11 metal; L is a tridentate or tetradentate neutrally charged ligand that is bonded to M by least three or four nitrogen atoms, and at...
05/15/2007
7176158Polymerization catalyst composition
Copolymerization of Ni(H) or Co(II) acenaphthene diimine complexes containing olefinic substituents on aryl groups in the presence of a free radical initiator results in polymerized late transition metal catalysts which can be used for olefin polymerization or oligo...
02/13/2007
7160835Bisphosphine process for producing the same and use thereof
Bisphosphines represented by the general formula (I) wherein Ar1 and Ar2 each represents an arylene group which may be substituted; R1 and R2 each represents an alkyl g...
01/09/2007
7148176Production of novel phosphane ligands and use in catalytical reactions
The present invention is directed to phosphine ligands and the use of such ligands in catalytic complexes with transition metals. The catalysts may be used in a variety of reactions and are especially useful for refining halogenoaromatics. ...
12/12/2006
7144839Polymerization catalysts
A transition metal complex having the following Formula (A): wherein the monovalent groups R1 and R2 are —Ra, —ORb, —NRcRd, and —NHRe; the monovalent groups Ra, Rb
12/05/2006
7141687N'-substituted N-acylamidine metal transition complexes and their use as catalysts
The invention relates to N′-substituted N-acylamidine transition metal complexes of the general formula (I), wherein M represents a transition metal, selected from the group of metals including Ni, Cu, Ru, Rh, Pd, Os, Ir and Pt, X represents Cl, Br, triflate, meth...
11/28/2006
7109343Metal catalysts and methods for making and using same
Compounds having the formula: are disclosed. M1 and M2 are the same or different and are transition metal atoms or ions; Z2 and Z3, independently, are the atoms necessa...
09/19/2006
7049473Hydroformylation
The present invention relates to a process for hydroformylating in the presence of a catalyst comprising at least one complex of a metal of transition group VIII with mono-phosphorus compounds which are capable of dimerizing via noncovalent bonds as ligands, to such...
05/23/2006
7030051Dirhodium catalyst compositions and methods for using same
Disclosed is method for increasing the efficiency of a dirhodium catalyst. The method includes providing a dirhodium catalyst, providing an organic ester, and contacting the dirhodium catalyst and the organic ester under conditions effective to increase the efficien...
04/18/2006
7026498Ligands for metals and improved metal-catalyzed processes based thereon
One aspect of the present invention relates to novel ligands for transition metals. A second aspect of the present invention relates to the use of catalysts comprising these ligands in transition metal-catalyzed carbon-heteroatom and carbon-carbon bond-forming react...
04/11/2006
7026266Catalytic formulation and its preparation
A hetergeneous catalyst includes a solid support having deposited thereon a catalyticaly active material, which is substantially insoluble in organic and aqueous liquid media. The insoluble material is constructed from secondary building blocks derived from suitable...
04/11/2006
RE38947Method of enantioselectively catalyzing a reaction
A chiral catalyst is disclosed together with methods of using it for enantioselective syntheses. The chiral catalyst includes a nucleus with two metal atoms that has four bridging ligands oriented radially to the axis of the nucleus. Each of these ligands includes a...
01/24/2006
6984604Supported bis(phosphorus) ligands and their use in the catalysis
Supported bis(phosphorus) ligands are disclosed for use in a variety of catalytic processes, including the isomerization, hydrogenation, hydroformylation, and hydrocyanation of unsaturated organic compounds. Catalysts are formed when the ligands are combined with a ...
01/10/2006
6962891Solid support dirhodium catalyst compositions and methods for making and using same
Disclosed are dirhodium catalyst compositions. One such dirhodium catalyst composition includes a dirhodium catalyst and a solid support. The dirhodium catalyst includes a Rh—Rh moiety and four bridging ligand moieties. The dirhodium catalyst and the solid support...
11/08/2005
6946560Ligands for metals and improved metal-catalyzed processes based thereon
One aspect of the present invention relates to novel ligands for transition metals. A second aspect of the present invention relates to the use of catalysts comprising these ligands in transition metal-catalyzed carbon-heteroatom and carbon-carbon bond-forming react...
09/20/2005
6878665Diphosphines, their complexes with transisition metals and their use in asymmetric synthesis
The invention relates to novel diphosphines, in optically pure or racemic form, of formula (I): in which: R1 and R2 are a (C5-C7)cycloalkyl...
04/12/2005
6878838Chiral porous metal phosphonates for heterogeneous asymmetric catalysis
Chiral porous zirconium phosphonates containing metal complex moieties are provided, synthesized via a molecular building block approach, and characterized by a variety of techniques including TGA, adsorption isotherms, XRD, SEM, IR, and microanalysis. These hybrid ...
04/12/2005
6855657Ortho substituted chiral phosphines and phosphinites and their use in asymmetric catalytic reactions
3,3′-Substituted chiral biaryl phosphine and phosphinite ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes are useful as catalysts in asymmetric reactions, such as, hydrogenation, hydride tra...
02/15/2005
6841499Supported ferrocene-based catalysts for selective aldehyde hydrogenation
A supported catalyst comprises a cationic rhodium(I) complex of the formula wherein R1 and R2 are the same or different hydrocarbon groups of up to 30 C atoms, or R1 and R2 a...
01/11/2005
6831035Stabilization of fluorophosphite-containing catalysts
Disclosed are novel catalyst systems comprising (1) a diorgano fluorophosphite ligand; (2) rhodium, wherein the ratio of gram moles fluorophosphite ligand (1) to gram atoms of rhodium is at least 1:1; and (3) a Group VIII metal, other than rhodium, or Group VIII met...
12/14/2004
6828271Chiral ligands, transition-metal complexes thereof and uses thereof in asymmetric reactions
Chiral ligands and transition metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The chiral ligands include phospholanes, P,N ligands, N,N ligands, biphenols, and chelating phosphines. The ferrocene-based irridium (R,R)-f-bina...
12/07/2004
6794328Diphosphine compound, production intermediate thereof, transition metal complex containing the compound as ligand and asymmetric hydrogenation catalyst containing the complex
The present invention provides a novel phosphine compound, specifically to provide a novel phosphine compound useful as a ligand for the above catalysts, in particular, a novel catalyst having an excellent performance (chemical selectivity, enantio-selectivity, cata...
09/21/2004
6730629Asymmetric phosphine ligand
A phosphine compound having excellent properties (chemical selectivity, enantioselectivity, catalytic activity) as a catalyst for asymmetric syntheses, especially asymmetric hydrogenations. A phosphine-phospholane compound represented by the following formula (1): ...
05/04/2004
6677268Catalyst based on cobalt and/or rhodium employed in a two-phase medium
An improved catalyst based on cobalt and/or rhodium dissolved in a non-aqueous ionic solvent which is liquid at a temperature of less than 90° C. More particularly, the catalyst comprises at least one complex of cobalt and/or rhodium co-ordinated with at...
01/13/2004
6664350Supported polymerisation catalyst
The invention relates to supported ligands and catalysts for use in the polymerization of olefinically unsaturated monomers such as vinylic monomers, comprising the use of a compound attached to support, the compound being capable of complexing with a tra...
12/16/2003
6617279Catalyst composition and method for producing diaryl carbonates, using bisphosphines
Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an iodide salt, preferably sodium iodide; and at least one organic bisphos...
09/09/2003
6608231Double-metal cyanide catalysts for producing polyether polyols
The invention relates to novel double metal cyanide (DMC) catalysts for the preparation of polyether polyols by polyaddition of alkylene oxides to starter compounds containing active hydrogen atoms, wherein the catalyst contains a) double metal cyanide co...
08/19/2003
6579997Metallacrown ether catalysts for hydroformylation
A metallacrown ether ligand chelates a transition metal atom to form a catalyst well suited to perform hydroformylation in the presence of carbon monoxide, hydrogen and an unsaturated substrate compound....
06/17/2003
6566297Aminonitrile production
Provided is a selective hydrogenation process for producing aminonitriles by contacting the corresponding dinitriles with a hydrogen-containing fluid in the presence of a hydrogenation catalyst, a solvent and tetraalkylammonium hydroxide and/or tetraalkyl...
05/20/2003
6566298Diphosphines
The invention relates to the preparation and use as catalysts of diphosphines of the formula (I) ##STR1## in which R is C6 -C14 -aryl or C4 -C13 -heteroaryl containing 1 to 3 heteroatoms selected from the group ...
05/20/2003
6555715Conversion of light paraffins to oxygenates or olefins using an imide promoter
A process has been developed for oxygenating linear C2 to C6 alkanes to ketones or aldehydes. The process involves reacting the alkanes with oxygen in the presence of a catalyst comprising an imide promoter and a metal co-catalyst. A...
04/29/2003
6534657Chiral ferrocene phosphines and their use in asymmetric catalytic reactions
Ferrocene anchored chiral ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes according to the present invention are useful as catalysts in asymmetric reactions, such as, hydrogenation...
03/18/2003
6500909Transition metal compound, catalyst component for olefin polymerization, catalyst for olefin polymerization, and process for producing olefinic polymer
A transition metal compound represented by the general formula (2) or (3) described below, a catalyst component for olefin polymerization comprising said transition metal compound, a catalyst component for olefin polymerization using said transition metal...
12/31/2002
6455740Process to separate a group 8-10 metal/phosphite ligand complex from an organic liquid
Process to separate a group 8-10 metal/phosphite ligand complex from an organic liquid mixture, wherein the following steps are performed (1) contacting the organic liquid with a support having bonded thereto an organophosphine ligand and separating the organi...
09/24/2002
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