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Class 502/113 - Containing two or more different Component B metals


Subclass of Class 502 - Catalyst, solid sorbent, or support therefor: product or process of making
Definition: Composition which contains two or more different Group IVb
No. of patents: 681
Last issue date: 03/20/2012


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NumberTitleIssue Date
8138113Dual metallocene catalysts for polymerization of bimodal polymers
This invention relates to catalyst compositions, methods, and polymers encompassing at least one first Group 4 metallocene compound comprising bridging η5-cyclopentadienyl-type ligands, in combination with at least one second Group 4 metallocene with non...
03/20/2012
8088704Polymerization catalysts and methods of using the same to produce polyolefin products
Polymerization catalyst systems including three or more catalyst compounds are provided. Methods for olefin polymerization including the aforementioned catalyst systems are also provided. ...
01/03/2012
8017541Catalyst components based on ferrocenyl complexes used for olefin polymerisation
The present invention discloses catalyst components based on ferrocenyl ligands, their method of preparation and their use in the polymerization of olefins. ...
09/13/2011
7951743Preparation of ultra high molecular weight linear low density polyethylene
Disclosed is a method of preparing an ultra-high molecular weight, linear low density polyethylene with a catalyst system that comprises a bridged indenoindolyl transition metal complex, a non-bridged indenoindolyl transition metal complex, an alumoxane activator an...
05/31/2011
7943545Polyethylene materials prepared using mixed ziegler-natta catalyst systems
A polyethylene may be prepared using a mixture of a silica supported catalyst and a magnesium chloride supported catalyst. By changing the ratio of the two catalysts, the polyethylene produced may have a varying bulk density and shear response. The method allows for...
05/17/2011
7767613Polyethylene and catalyst composition for its preparation
Polyethylene which comprises ethylene homopolymers and copolymers of ethylene with α-olefins and has a molar mass distribution width Mw/Mn of from 6 to 100, a density of from 0.89 to 0.97 g/cm3, a weight average molar mass Mw
08/03/2010
7718564Partially decomposed catalyst and hydrocarbon oxidation processes using the same
The present invention is related to a hydrocarbon oxidation process. The process comprises bringing one or more hydrocarbons into contact with a source of oxygen in the presence of a radical initiator and a catalyst. The catalyst comprises an organic metal complex l...
05/18/2010
7435701Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
A catalytic composition, including a neutral metal-pair complex, is disclosed, along with a method for its preparation. A method for the polymerization of ethylenically unsaturated monomers using the catalytic composition, and the addition polymers produced thereby ...
10/14/2008
7432220Method for the preparation of olefin polymerization catalyst support and an olefin polymerization catalyst
The invention is directed to a process for producing a particulate support for an olefin polymerisation catalyst wherein a solution of a magnesium compound is contacted with a solution of an element of Group (13 or 14) of the Periodic Table (IUPAC) to obtain a solid...
10/07/2008
7429635Preparation of ultra high molecular weight linear low density polyethylene
Disclosed is a method of preparing an ultra-high molecular weight, linear low density polyethylene with a catalyst system that comprises a bridged indenoindolyl transition metal complex, a non-bridged indenoindolyl transition metal complex, an alumoxane activator an...
09/30/2008
7410925Metal compound, and catalyst component and catalyst for addition polymerization, and process for producing addition polymer
A metal compound obtained by a process comprising the step of contacting, in a specific ratio, a compound represented by the formula BiL1r, a compound represented by the formula R1s-1TH, and a compound represented by the f...
08/12/2008
7410926Polymerization process using a supported, treated catalyst system
The present invention relates to a supported, treated catalyst system and its use in a process for polymerizing olefin(s). More particularly, it provides a supported, treated catalyst system produced by a process comprising the steps of: (a) forming a supported bime...
08/12/2008
7402637Method for producing a poly-1-olefin in the presence of a Ziegler catalyst
The invention relates to a method for producing a poly-1-olefin by polymerization of a 1-olefin of the formula R4C═CH2, in which R4 is hydrogen or an alkyl radical having from 1 to 10 carbon atoms, in suspension, in solution or in ...
07/22/2008
7384885Catalyst activation and resins therefrom
The present invention relates to the removal of hydrocarbon residues from a catalyst and more specifically the air activation of a catalyst containing hydrocarbon residues. It also relates to extruded pipe and utility conduit resins comprising polyethylene, househol...
06/10/2008
7381778Method of preparing a treated support
This invention relates to a method of preparing a supported catalyst comprising the steps of contacting a solid titanium with a supported catalyst compound, and heating the combination to at least 150° C. ...
06/03/2008
7378537Olefin oligomerization catalysts and methods of using same
A metal complex comprising a metal compound complexed to a heteroatomic ligand, the metal complex having Structure X: wherein R1, R2, R3, and R4 are each independently an alkyl gr...
05/27/2008
7354880Catalyst composition and methods for its preparation and use in a polymerization process
The present invention relates to a catalyst composition and a method for making the catalyst composition of a polymerization catalyst and a carboxylate metal salt. The invention is also directed to the use of the catalyst composition in the polymerization of olefin(...
04/08/2008
7354979Polymer production at supercritical conditions
This invention relates to a process to polymerize olefins comprising contacting, in a polymerization system, olefins having three or more carbon atoms with a catalyst compound, activator, optionally comonomer, and optionally diluent or solvent, at a temperature abov...
04/08/2008
7348384Supported, titanized chromium catalyst and its use for preparing homopolymers and copolymers of ethylene
Novel supported, titanized chromium catalysts for the homopolymerization of ethylene and the copolymerization of ethylene with α-olefins, a process for preparing them and to their use for the polymerization of olefins. ...
03/25/2008
7348383Spray-dried, mixed metal ziegler catalyst compositions
A Ziegler-Natta catalyst composition comprising a solid mixture formed by halogenation of: Al) a spray-dried catalyst precursor comprising the reaction product of a magnesium compound, a non-metallocene titanium compound, and at least one non-metallocene compound of...
03/25/2008
7335716Ethylene (co)polymers and uses thereof
An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measure...
02/26/2008
7326760Production of broad molecular weight polyethylene
Broad molecular weight polyethylene and polyethylene having a bimodal molecular weight profile can be produced with chromium oxide based catalyst systems employing alkyl silanols. The systems may also contain various organoaluminum compounds. Catalyst activity and m...
02/05/2008
7323523Adjusting polymer characteristics through process control
Properties of a polymer produced in gas phase or slurry phase using a dual catalyst such as polydispersity and comonomer incorporation, may be controlled by controlling reaction parameters such as temperature, (co)monomer pressure, hydrogen partial pressure and the ...
01/29/2008
7321015Adjusting polymer characteristics through process control
Properties of a polymer produced using a dual catalyst on the same support, such as polydispersity and comonomer incorporation, may be controlled by controlling reaction parameters such as temperature, monomer pressure, hydrogen partial pressure and the presence of ...
01/22/2008
7319125Supercritical polymerization process and polymers produced therefrom
This invention relates to a process to produce propylene polymers comprising contacting a metallocene catalyst compound and an activator in a reaction medium comprising propylene, from 0 to 30 volume % of one or more solvents and from 0 to 30 mole % of one or more c...
01/15/2008
7312283Polymerization catalysts and process for producing bimodal polymers in a single reactor
Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. Methods for preparing and using such catalysts to produce polyolefins are also provided. The compositions...
12/25/2007
7309677Supported polymerisation catalysts
A method for the preparation of a supported transition metal catalyst system which includes the steps of: (i) mixing together in a suitable solvent (a) an aluminoxane and (b) an ionic activator containing a cation and an anion, wherein the anion has at least one sub...
12/18/2007
7304125Process for the preparation of polymers from polymer slurries
A process for manufacturing a polymer having a molecular weight in excess of 5,000, and preferably in excess of 40,000, comprises, producing a polymerized reaction mass in which the polymer is dispersed, the reaction mass including solvent(s), unreacted monomer and ...
12/04/2007
7294600Supported hybrid metallocene catalyst, method for preparing the same, and method for preparing polyolefin using the same
The present invention relates to a supported metallocene catalyst used for preparing polyolefin whose physical properties and molecular weight distribution can be easily controlled, a method for preparing the same, and a method for preparing polyolefin using the sam...
11/13/2007
7294674Soft polyolefin compositions with improved flow
A polyolefin composition suitable for preparing films and sheets, comprising: (A) from 15 to 40% by weight of a crystalline copolymer of propylene with at least one alpha-olefin of formula H2C═CHR1, where R
11/13/2007
7294599Acidic activator-supports and catalysts for olefin polymerization
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, typically using a supported catalyst composition. In one aspect, this invention encompasses precontacting a metall...
11/13/2007
7291575Active, heterogeneous bi- or tri-dentate catalyst
A catalyst composition, and olefin polymerization process using same, formed from a mixture of a non-aluminoxane aluminum compound, an inorganic oxide and a transition metal bidentate or tridentate complex in certain prescribed proportions. The composition can be fo...
11/06/2007
7285679Oxidation of alkanes
Alkanes are oxidised to oxygenates such as carboxylic acids with molecular oxygen employing a two component catalyst system which uses a liganded heavy metal compound and a mixed metal oxide. ...
10/23/2007
7282546Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations
Polyolefins may be prepared using a cocatalyst conforming to the formula: AIRz(Xz)nLzm wherein Rz is a linear or branched organic moiety having at least 5 carbons and Xz
10/16/2007
7276566De-foaming spray dried catalyst slurries
A method for preparing a spray dried catalyst and a low viscosity, low foam spray dried catalyst system for olefin polymerization are provided. In one aspect, the method includes preparing a catalyst system including one or more components selected from metallocenes...
10/02/2007
7273914Olefin polymerization methods
Methods for making polyolefins are disclosed. One method comprises polymerizing an olefin in the presence of a catalyst system comprising a single-site complex, an agglomerated metal oxide/clay support-activator, and an ionic borate. Including an ionic borate with t...
09/25/2007
7271124Process to produce polymers
A process to produce ethylene polymers is provided. ...
09/18/2007
7271120Catalyst for the synthesis of dimethyl carbonate from urea and methanol, preparation and use thereof
A catalyst for the preparation of dimethyl carbonate from urea and methanol having a composition on weight base of: active component of from 20 to 50 wt %, and carrier of from 80 to 50 wt %, and prepared by equal-volume spraying and impregnating method is disclosed....
09/18/2007
7271126Catalyst for the dehydrogenation of ethyl benzene to STYRENE prepared with a high purity iron precursor
A method for producing a catalyst for use in the dehydrogenation of ethylbenzene to styrene is disclosed. The catalyst of the present invention comprises a high purity metal and at least one promoter in the form of solid oxides, oxide hydrates, hydroxides, hydroxyca...
09/18/2007
7268194Continuous slurry polymerization process and apparatus
A process of converting a loop reactor into multiple loop reactors comprising starting with a loop reactor comprising at least 8 vertical legs, at least two non-vertical conversion runs, each non-vertical run connected in fluid flow communication with two vertical l...
09/11/2007
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