...that one person who claimed to be the inventor of the television is Russian emigre Vladimir Zworykin? In 1929 David Sarnoff, founder of RCA, asked Zworykin what it would take to develop TV for commercial use. He said: a year and a half and $100,000. In reality, it took 20 years and $50 million! Before his death in 1982 at the age of 92, Zworykin said of his invention: "The technique is wonderful. It is beyond my expectations. But the programs! I would never let my children even come close to this thing."
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| Number | Title | Issue Date |
| 7811956 | Supported olefin polymerization catalyst A supported catalyst system comprises (a) a dehydrated support material, (b) a transition metal compound, and (c) an activator and is characterised in that the support material has been pretreated with at least two different organoaluminum compounds prior to content... | 10/12/2010 |
| 7384884 | Catalyst preparation method This invention relates to a method to prepare a supported catalyst system comprising preparing a combination comprising 1) a first supported catalyst system comprising a support, an activator and a metal catalyst compound, and 2) a second supported catalyst system c... | 06/10/2008 |
| 7271126 | Catalyst for the dehydrogenation of ethyl benzene to STYRENE prepared with a high purity iron precursor A method for producing a catalyst for use in the dehydrogenation of ethylbenzene to styrene is disclosed. The catalyst of the present invention comprises a high purity metal and at least one promoter in the form of solid oxides, oxide hydrates, hydroxides, hydroxyca... | 09/18/2007 |
| 7244795 | Polymerization process using metallocene catalyst systems The present invention relates to a polymerization process using improved metallocene catalyst systems. Specifically, the catalyst systems of the present invention relate to a metallocene compound having optimized metals loading and activator concentration, and demon... | 07/17/2007 |
| 7235614 | Methods for injecting catalyst into a polymerization reactor A polymerization process and a catalyst delivery system are provided. For example, a polymerization process is described, including providing a conduit having a catalyst inlet, a first propylene stream inlet located downstream of the catalyst inlet, and a second pro... | 06/26/2007 |
| 7232785 | Solid catalytic component and catalytic system of the ziegler-natta type, process for their preparation and their use in the polymerization of alk-1-enes The present invention relates to a new solid catalytic component, which can be used in combination with an aluminum compound as co-catalyst and optionally an external electron donor as additional co-catalyst to form a catalytic system of the Ziegler-Natta-catalyst-t... | 06/19/2007 |
| 7232868 | Methods of delivering catalyst systems for propylene polymerization A polymerization process is provided. For example, a polymerization process is described, including providing a catalyst slurry having a metallocene catalyst and a first oil, providing a transport medium including a second oil and combining the transport medium and ... | 06/19/2007 |
| 7229945 | Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins The present invention is for a process for making a catalyst for production of unsaturated aldehydes, such as methacrolein, by gas phase catalytic oxidation of olefins, such as isobutylene, said catalyst containing oxides of molybdenum, bismuth, iron, cesium, tungst... | 06/12/2007 |
| 7220696 | Solid titanium catalyst component for olefin polymerization, catalyst for olefin polymerization, and process for olefin polymerization Disclosed is a catalyst for olefin polymerization comprising [I] a solid titanium catalyst component [S] comprising titanium, magnesium, halogen and an electron donor (b), which is obtained by bringing a solid adduct consisting of a magnesium compound and an electro... | 05/22/2007 |
| 7211534 | Preparation of a magnesium halide support for olefin polymerization and a catalyst composition using the same A magnesium halide support material for a polyolefin catalysts is disclosed. The magnesium halide of present invention is prepared by reacting magnesium with an alkylhalide in a non-polar hydrocarbon solvent. Preparation of the support does not require the use elect... | 05/01/2007 |
| 7208436 | Catalyst components for the polymerization of olefins Catalyst components for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a hydrocarbon radical having 1–12 carbon atoms, comprising Mg, Ti, Cl, OR groups, where R is a C1–C10 alkyl group optionally containing heteroatoms, and an ether... | 04/24/2007 |
| 7199077 | Fischer-tropsch catalyst prepared with a high purity iron precursor A Fischer-Tropsch catalyst comprising iron and at least one promoter is prepared via a method which comprises the preparation of a high purity iron precursor and which uses a nominal amount of water in the catalyst production. The catalyst particles prepared with th... | 04/03/2007 |
| 7189674 | Supported catalyst composition for polymerization of olefins, method for preparing the same and process for polymerization using the same Supported catalyst composition for polymerization of olefins comprising: (i) a titanium compound, a magnesium compound and at least one electron donor compound; (ii) an oxygen containing polymer support; and (iii) a cocatalyst comprising at least one aluminum compou... | 03/13/2007 |
| 7172990 | Highly active spherical metal support catalysts The invention relates to highly active spherical metal support catalysts with a metal content of 10 to 70% by mass, and a process for their production with the use of a mixture of polysaccharides and at least one metal compound which is dropped into a metal salt sol... | 02/06/2007 |
| 7169864 | Metallocene catalysts, their synthesis and their use for the polymerization of olefins A process for the preparation of a catalyst system includes the steps of combining a support material with a first composition which includes at least one aluminoxane in a first solvent to provide an aluminoxane loaded support; and, contacting the aluminoxane loaded... | 01/30/2007 |
| 7135531 | Spherical catalyst for olefin polymerization Disclosed are catalyst systems and methods of making the catalyst systems/supports for the polymerization of an olefin containing a solid titanium catalyst component having a substantially spherical shape and containing an internal electron donor, a support made fro... | 11/14/2006 |
| 7101939 | Ethylene/α-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use An ethylene/α-olefin copolymer comprising a component produced by a non-single-site polymerization catalyst and a component produced by a single-site polymerization catalyst, its preparation and use are described. The copolymer has an α-olefin content of 5 to 20 p... | 09/05/2006 |
| 7094724 | Catalytic solid supported on calcined hydrotalcite for olefinic polymerisation Catalyst solid for olefin polymerization comprising A) at least one calcined hydrotalcite and B) at least one organic transition metal compound, and also a catalyst system comprising the catalyst solid, the use of the catalyst sol... | 08/22/2006 |
| 7081427 | Solid catalyst component for olefin polymerization A solid catalyst component for olefin polymerization comprising titanium, magnesium and a compound of the general formula (I) wherein R1 and R2 are independently a C3 straight or ... | 07/25/2006 |
| 7051782 | System for coupling roller shade tubes A coupling assembly for a multiple-tube roller shade includes a support assembly for rotatably supporting and connecting adjacently located tube-end portions and a clutch mechanism providing relative rotation therebetween. The support assembly includes a tube-end fi... | 05/30/2006 |
| 7033560 | Single source mixtures of metal siloxides This invention pertains to complex mixtures of the formula M is a metal having a valence of from 2–6, L1 is an anionic ligand and L2 is a siloxide or silyl amide ligand suited for producing stable thin-film metal silicates, v is equal to the valence of the metal, ... | 04/25/2006 |
| 7015169 | Catalyst systems of the ziegler-natta type and their preparation The present invention relates to catalyst systems of the Ziegler-Natta type, to a process for preparing them, to their use for the polymerization of olefins and to ethylene copolymers which can be prepared using this catalyst system. ... | 03/21/2006 |
| 6989347 | Catalysts for the oxidation of unsaturated aldehydes to produce carboxylic acids and methods of making the same A catalyst composition for the production of carboxylic acids by the oxidation of the corresponding unsaturated aldehydes, and methods for making and using the catalyst compositions. The catalysts include compositions of the formula: MoaVb | 01/24/2006 |
| 6982236 | Process to polymerize olefins This invention relates to a method to prepare a supported catalyst system comprising preparing a combination comprising 1) a first supported catalyst system comprising a support, an activator and a metal catalyst compound, and 2) a second supported catalyst system c... | 01/03/2006 |
| 6967447 | Pre-configured light modules The present invention includes a light source having N light generators, a receiver, and an interface circuit. Each light generator emitting light of a different wavelength, the intensity of light generated by the kth generator is determined by a signal I... | 11/22/2005 |
| 6967231 | Olefin polymerization process A process for polymerizing ethylene is disclosed. A magnesium chloride-alcohol is used to support an organometallic complex comprising a Group 3 to 10 transition metal and an indenoindolyl ligand. The supported organometallic complex is mixed with an activator and e... | 11/22/2005 |
| 6964936 | Method of making maximally dispersed heterogeneous catalysts A method of making a catalyst with monolayer or sub-monolayer metal by controlling the wetting characteristics on the support surface and increasing the adhesion between the catalytic metal and an oxide layer. There are two methods that have been demonstrated by exp... | 11/15/2005 |
| 6956003 | Catalyst system for ethylene (co)-polymerization A catalyst system for (co)-polymerizing ethylene or ethylene with α-olefin is disclosed. The catalyst system utilizes a catalyst component that contains the product of a reaction of an early transition metal complex such as a titanium alkoxide with a cyclic diene-c... | 10/18/2005 |
| 6949489 | Solid supported catalyst usable for the polymerization of conjugated dienes, process for the preparation thereof and a process for the polymerization of conjugated dienes using this catalyst The present invention relates to a solid supported catalyst usable for the polymerization of conjugated dienes, to a process for the preparation of said catalyst and to a process for the polymerization of conjugated dienes using said catalyst. The solid supported ca... | 09/27/2005 |
| 6943134 | Bimodal polyolefin production process and films therefrom A process of producing a bimodal polyolefin composition is described, which includes in one embodiment contacting monomers with a supported bimetallic catalyst composition for a time sufficient to form a bimodal polyolefin composition that includes a high molecular ... | 09/13/2005 |
| 6936667 | Polymerization catalyst compositions and processes to produce polymers and bimodal polymers A process to produce a first catalyst composition is provided. The process comprises contacting at least one first organometal compound and at least one activator to produce the first catalyst composition. The activator is selected from the group consisting of alumi... | 08/30/2005 |
| 6933353 | Olefin polymerization process A method for preparing a supported organometallic complex is disclosed. An organometallic complex is combined with a support material that has been treated with an organozinc compound. The organometallic complex comprises a Group 3 to 10 transition metal and an inde... | 08/23/2005 |
| 6924248 | Catalyst system for carrying out olefin polymerization comprising a calcined hydro-talcite serving as a supporting material Catalyst system for olefin polymerization comprising A) at least one calcined hydrotalcite, B) at least one organic transition metal compound, C) optionally one or more cation-forming compounds and D) at least one ... | 08/02/2005 |
| 6924343 | Olefin polymerization catalyst component, its preparation and use A process for polymerizing olefins using a high activity catalyst. The catalyst utilize in the present process has a good balance in activity and can be used to carry out ethylene polymerization at high and low melt flow rates to produce low gel or gel free product.... | 08/02/2005 |
| 6921734 | Titanocene complexes and its catalyst for preparing syndiotactic polystyrene The present invention relates to a titanocene complex and a catalyst comprising the same and an alkylaluminoxane for preparing syndiotactic polystyrene. The catalyst is applicable to the industrial production of the syndiotactic polymerization of styrene. The titano... | 07/26/2005 |
| 6900152 | Catalyst for trimerization of ethylene and process for trimerizing ethylene using the catalyst A catalyst used for trimerization of ethylene into 1-hexene is descrobed, which comprises (i) a specific organometallic complex having a neutral multidentate ligand having a tripod structure, (ii) an alkylaluminoxane, and an optional ingredient selected from: (iii) ... | 05/31/2005 |
| 6864207 | Ziegler-Natta catalyst for polyolefins A process for making a polyolefin catalyst component, catalyst and polymer resin is disclosed. Controlling the viscosity of a catalyst synthesis solution with the addition of aluminum alkyl alters the precipitation of the catalyst component from a catalyst synthesis... | 03/08/2005 |
| 6861487 | Catalyst precursor for the polymerization of olefins and polymerization process using the same The present invention relates to a catalyst precursor for homo- or copolymerization of olefins comprising a metallocene compound, a magnesium containing compound and a thermoplastic polymer support, and optionally further comprising a metal alkoxy compound, an alumi... | 03/01/2005 |
| 6828268 | Polymerization catalyst systems and processes using alkyl lithium compounds as a cocatalyst A catalyst system composition comprising a chromium compound supported on a silica-titania support, wherein said catalyst system has been reduced with carbon monoxide, and a cocatalyst selected from the group consisting of i) alkyl lithium compounds, ii) dialkyl alu... | 12/07/2004 |
| 6818584 | Process for preparing a Ziegler-Natta catalyst Especially homogeneous supported Ziegler-Natta catalysts may be prepared in a simple one reaction vessel process from a magnesium hydrocarbyloxy starting material which is soluble in a hydrocarbon solvent. The process comprises: (I) reacting a magnesium hydrocarbylo... | 11/16/2004 |