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Attorney: Shipley; James E.


Number of patents: 76
Last date: January 09, 2007

1    
NumberTitleIssue Date
7161049Process for purifying hydrofluoropropanes
A process is disclosed for purifying a hydrofluoropropane of undesirable C2–C4 olefinic and C1–C4 saturated chlorinated impurities, comprising the steps of: contacting a first mixture of hydrofluoropropane, olefinic im...
01/09/2007
7122704Fluoroketone compounds
The present invention relates to new fluoroketone compounds from the groups monobromoperfluoroketones, monohydromonobromoperfluoroketones, (perfluoroalkoxy)monobromoperfluoroketones, (fluoroalkoxy)monobromoperfluoroketones, and monochloromonobromoperfluoroketones. T...
10/17/2006
7087788Fluorosulfone compounds
The present invention relates to new fluorosulfone compounds. These fluorosulfone compounds have utility in preventing, controlling and extinguishing fire. ...
08/08/2006
6900362Vapor phase production of 1,1,1,2,3,3,3-heptafluoropropane from hydrogen fluoride and hexafluoropropylene
A process for the production of HFC-227ea from HF and HFP is provided. This process takes advantage of an azeotropic composition of HF and HFC-227ea in order to produce HFC-227ea essentially free of HF and recycle unreacted HF back to the reactor. The recycle of sai...
05/31/2005
6855370Fluoropolymer interlayer dielectric by chemical vapor deposition
A process is disclosed for forming a fluoropolymer layer on a thin film device, comprising contacting said thin film device with a gas phase fluoromonomer, and initiating polymerization of said fluoromonomer with a free radical polymerization initiator whereby said ...
02/15/2005
6303838Separating 1,1,1,3,3-pentafluoropropane from hydrogen fluoride
Disclosed are processes for separating 1,1,1,3,3-pentafluoropropane (HFC-245fa) from hydrogen fluoride (HF) by distillation, wherein hydrocarbons, chloroflurocarbons, hydrochlorofluorocarbons and fluorocarbons are used as entraining agents. The processes ...
10/16/2001
6291727Azeotropic or azeotrop-like compositions of hydrofluoric acid with dihaloethanes
The instant invention relates to azeotropic or azeotrope-like compositions of hydrofluoric acid with at least one of 1,1-dichloroethane, 1-chloro-1-fluoroethane and 1,1 -difluoroethane. The invention also relates to manufacturing processes for separating ...
09/18/2001
6229058Preparation of fluorinated propanes and pentanes
The instant invention relates to producing fluorinated propanes and pentanes. More particularly it relates to producing perhalofluoropropanes and pentanes by reacting dihalodifluoromethanes with polyfluoroethylenes, notably tetrafluoroethylene (TFE) and c...
05/08/2001
6224844Process for the production of calcium fluoride
A process is disclosed for producing calcium fluoride comprising: (a) mixing aqueous H3 PO4 with aqueous H2 SiF6 to form a mixture such that the concentration of H3 PO4 is at least about 3 ...
05/01/2001
6221830Purification process for hexafluoroethane products
The disclosure relates to removing impurities from hexafluoroethane (CF3 CF3), also known as Perfluorocarbon 116 (PFC-116) or Fluorocarbon 116 (FC-116), by using azeotropic distillation such that an overhead product consisting essent...
04/24/2001
6207869Process for perhalofluorinated butanes and hexanes
The instant invention relates to producing perhalofluorobutanes and perhalofluorohexanes, more particularly it relates to their production by utilizing tetrafluoroethylene (hereinafter referred to as "TFE") and chlorotrifluoro-ethylene (hereinafter referr...
03/27/2001
6156161Extractive distillation process for separating difluoromethane and pentafluoroethane using methylene chloride
A process is disclosed for removing chloropentafluoroethane (CFC-115) from a mixture comprising CFC-115, difluoromethane (HFC-32), pentafluoroethane (HFC-125), or from mixtures of these compounds, by azeotropic or extractive distillation....
12/05/2000
6066768Perhalofluorinated butanes and hexanes
The instant invention relates to producing perhalofluorobutanes and perhalofluorohexanes, more particularly it relates to their production by utilizing tetrafluoroethylene (hereinafter referred to as "TFE") and chlorotrifluoro-ethylene (hereinafter referr...
05/23/2000
5985939Processes for producing aerosol propellants that include butane or isobutane
The invention relates to the discovery of compositions useful as aerosol propellants that include a first component of butane or isobutane and a second component of 2-fluoropropane (HFC-281 ea) or 1-fluoropropane (HFC-282 fa)....
11/16/1999
5935390Producing chlorine and hydrogen from hydrogen chloride by plasma process
A process is disclosed for converting hydrogen chloride (HCl) to molecular chlorine (Cl2) and molecular hydrogen (H2), and more particularly to such process conducted in a plasma environment....
08/10/1999
5900044Organic separation from HF
A process is disclosed for separating HF from organics by passing a mixture of HF and organics through a column or bed containing a polymer which sorbs the HF leaving an essentially pure organic stream. The HF may be recovered from the polymer, or the org...
05/04/1999
5874657Process for the purification of 1,1-difluoroethane
The present invention relates to processes for separating 1,1-difluoroethane (HFC-152a) from vinyl chloride by using extractive distillation with an extractive agent selected from the aliphatic hydrocarbons, chlorocarbons and alcohols....
02/23/1999
5789633Azeotropic or azeotrope-like compositions of hydrofluoric acid with dihaloethanes
The instant invention relates to azeotropic or azeotrope-like compositions of hydrofluoric acid with at least one of 1,1-dichloroethane, 1-chloro-1-fluoroethane and 1,1-difluoroethane. The invention also relates to manufacturing processes for separating h...
08/04/1998
5772852Separating HCI and halocarbons
A process for separating HCl from pentafluoroethane, chloropentafluoroethane, chlorotrifluoroethane, trifluoromethane, and other fully saturated and unsaturated fluorocarbons, chlorofluorocarbons and chlorocarbons....
06/30/1998
5770779Process for preparation of fluorinated hydrocarbons
This invention is a process for the selective preparation of fluorinated hydrocarbons from chlorinated hydrocarbons while minimizing formation of oligomeric and polymeric byproducts. The process comprises providing a liquid phase containing chlorinated hy...
06/23/1998
5723429Azeotropic or azeotrope-like compositions of tetrafluoroethane and chlorotetrafluoroethane
The disclosure relates to separating 1,1,2,2 tetrafluoroethane (HFC-134) and 1,1,1,2 tetrafluoroethane (HFC-134a) from each other and/or from fluorocarbon impurities by using extractive distillation with an extractive agent comprising an alcohol. Examples...
03/03/1998
5718807Purification process for hexafluoroethane products
The disclosure relates to removing impurities from hexafluoroethane (CF3 CF3), also known as PerFluoroCarbon 116 (PFC-116) or FluoroCarbon 116 (FC-116), by using azeotropic distillation such that an overhead product containing an HCl...
02/17/1998
5663478Recovery of aluminum and/or fluoride values from used aluminum chlorofluorides
A process is disclosed for treating used aluminum chlorofluoride catalyst either alone or mixed with organics. It involves forming a solution of the catalyst in water or an aqueous acid and then adjusting the pH and/or composition of the aqueous phase for...
09/02/1997
5591699Particle transport fluids thickened with acetylate free xanthan heteropolysaccharide biopolymer plus guar gum
A non-acetylated but otherwise unmodified xanthan heteropolysaccharide polymer plus guar gum, is employed to impart viscosity to an aqueous particle transport fluid (such as a drilling fluid, a fracturing fluid, or a filter structure emplacement fluid) su...
01/07/1997
5534151Process for separating and recovering halocarbons from mixtures thereof
A process is disclosed for separating components of an azeotropic or azeotrope-like mixture containing only organic compounds at least one of which compound is a halocarbon comprising contacting said azeotropic or azeotrope-like mixture with a semipermeab...
07/09/1996
5531975Process for the production of phosphoric acid and calcium fluoride
Fluosilicic acid is reacted with phosphate rock in order to produce wet process phosphoric acid and calcium fluoride which is later reacted with sulfuric acid to produce hydrogen fluoride and calcium sulfate. The hydrogen fluoride is then stripped from th...
07/02/1996
5458674Organic separation from HF
A process is disclosed for separating HF from organics by passing a mixture of HF and organics through a column or bed containing a polymer which sorbs the HF leaving an essentially pure organic stream. The HF may be recovered from the polymer, or the org...
10/17/1995
5456841Process for separating and recovering halocarbons from mixtures thereof
A process is disclosed for separating components of an azeotropic or azeotrope-like mixture containing only organic compounds at least one of which compound is a halocarbon comprising contacting said azeotropic or azeotrope-like mixture with a semipermeab...
10/10/1995
5449846Purification of saturated halocarbons
A process for reducing the content of unsaturated impurities in saturated fluorohalocarbons and fluorohalohydrocarbons by contacting the impure saturated fluorohalocarbon and/or fluorohalohydrocarbon in a substantially dry fluid state with a substantially...
09/12/1995
5449845Purification of saturated halocarbons
A process for reducing the content of unsaturated impurities in saturated fluorohalocarbons and fluorohalohydrocarbons by contacting the impure saturated fluorohalocarbon and/or fluorohalohydrocarbon in a substantially dry fluid state with a substantially...
09/12/1995
5427757Process for the production of phosphoric acid and hydrogen fluoride from phosphate rock and fluosilicic acid
Fluosilicic acid is reacted with phosphate rock in order to produce wet process phosphoric acid and calcium fluoride which is later reacted with sulfuric acid to produce hydrogen fluoride and calcium sulfate. The hydrogen fluoride is then stripped from th...
06/27/1995
5318716Azeotrope-like mixtures of 1,1-dichloro-2,2,2-trifluoroethane and 1,1-dichloro-1-fluoroethane
Azeotrope-like mixtures of 1,1-dichloro-2,2,2-trifluoroethane and 1,1-dichloro-1-fluoroethane, being useful as cleaning solvents, refrigerants and foam blowing agents....
06/07/1994
5282968Process for separating and recovering halocarbons from mixtures thereof
A process is disclosed for separating components of an azeotropic or azeotrope-like mixture containing only organic compounds at least one of which compound is a halocarbon comprising contacting said azeotropic or azeotrope-like mixture with a semipermeab...
02/01/1994
5262077Halocarbon blends
Azeotrope-like blends are disclosed comprising effective amounts of 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethane (HFC-152a) and a halocarbon selected from the group consisting of 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124), 2-chloro-1,1...
11/16/1993
5246617Azeotropic compositions of 1,1-dichloro-1-fluoroethane and methanol/ethanol
Azeotropic mixtures of 1,1-dichloro-1-fluoroethane (HCFC-141b) with methanol or ethanol, the azeotropic mixtures being useful in solvent cleaning applications....
09/21/1993
5240634Ternary azeotropic compositions of 1,1-dichloro-1,2-difluoroethane and cis-1,2-dichloroethylene with methanol or ethanol or n-propanol
Azeotropic mixtures of 1,1-dichloro-1,2-difluoroethane (HCFC-132c) and cis-1,2-dichloroethylene (c-HCC-1130) with methanol, or ethanol or n-propanol are useful in solvent cleaning applications, as refrigerants, aerosol propellants and blowing agents....
08/31/1993
5227087Constant-boiling, azeotrope-like mixtures of dichlorotrifluoroethane, 1,1-dichloro-1-fluoroethane and methanol and/or ethanol
Constant boiling, azeotrope-like mixtures of dichlorotrifluoroethane, 1,1-dichloro-1-fluoroethane and methanol and/or ethanol, the constant-boiling, azeotrope-like mixtures being useful in solvent cleaning applications....
07/13/1993
5196616Process for separating and recovering fluorocarbons and hydrogen fluoride from mixtures thereof
A process for separating and recovering an organic phase (e.g., fluorocarbons such as chlorofluorocarbons, hydrochlorofluorocarbons, hydrofluorocarbons and perfluorocarbons) from a feed stream of a mixture of fluorocarbons and hydrogen fluoride, wherein t...
03/23/1993
5194169Azeotrope-like refrigerant mixtures of 1,1-dichloro-2,2,2-trifluoroethane and 1,1-dichloro-1-fluoroethane
Azeotrope-like mixtures of 1,1-dichloro-2,2,2-trifluoroethane and 1,1-dichloro-1-fluoroethane, being useful as cleaning solvents, refrigerants and foam blowing agents....
03/16/1993
5182040Azeotropic and azeotrope-like compositions of 1,1,2,2-tetrafluoroethane
The azeotropic and azeotrope-like compositions of 1,1,1,2-tetrafluoroethane and one of 1,1-difluoroethane, 1-chloro-1,1,-difluoroethane, dimethyl ether, perfluorocyclobutane, n-butane, isobutane and 1,1,1,2,3,3,3-heptafluoropropane, and their use as refri...
01/26/1993
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