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Attorney: McBride; Thomas K., Snyder; Eugene I.


Number of patents: 106
Last date: March 30, 1999

1      
NumberTitleIssue Date
5889186Process for preparation of the pharmaceutically desired (S)-oxetine enantiomers
Improved processes for preparation of the (S)-oxetines in high enantiomeric purity centers on resolution using simulated moving bed chromatography of a racemic precursor early in the oxetine synthesis. Resolution is effected with high enantiomeric purity,...
03/30/1999
5849977Metal cation-modified alkylation catalysts
A process for the alkylation of alkenes having from 2 to 6 carbon atoms with an alkane having from 4 to 6 carbon atoms to afford an alkylate comprises reacting in the liquid phase the alkene and alkane under alkylation conditions in the presence of a nove...
12/15/1998
5763729Alkylation of alkanes with alkyl halides
Although olefins commonly are used to alkylate alkanes using various solid acid catalysts, the process is severely hampered by short catalyst lifetimes attending substantial olefin oligomerization. This problem can be avoided by using an alkyl chloride as...
06/09/1998
5760286Preparation of tertiary phosphine sulfonic acids
Tertiary phosphine sulfonic acids are important ligands for transition metals where the complex is effective in catalyzing the oligomerization of alpha-olefins. An improved method of preparation utilizes inverse addition of lithiated aryl sulfonate salts ...
06/02/1998
5744619Titanovanadosilicalites as epoxidation catalysts for olefins
Titanovanadosilicalites have been found to be very selective, active catalysts in the epoxidation of olefins by peroxides. Dilute hydrogen peroxide suffices to afford high yields of the epoxide. Vanadium incorporation at levels of Si:V in the range 100-25...
04/28/1998
5744679Using water concentration to control ethylene oligomerization
Ethylene is effectively oligomerized to linear alpha-olefins using catalyst systems based on transition metal compounds. It has been found that when the reaction is conducted in a polar organic liquid as solvent, incorporation of water into the solvent at...
04/28/1998
5739074Metal cation-modified alkylation catalysts
A catalytic composite of a refractory inorganic oxide whose bound surface hydroxyl group has reacted with a Friedel-Crafts type metal halide and whose acidity has been modified by the deposition of a monovalent metal cation, especially an alkali metal cat...
04/14/1998
5723710Zeolite beta and its use in aromatic alkylation
There is disclosed a new form of zeolite beta which shows substantially greater stability and greater catalyst lifetime when used in the alkylation and transalkylation of aromatic compounds. The new, surface-modified zeolite beta is characterized by havin...
03/03/1998
5719322Zeolitic capillary columns for gas chromatography
Methods have been found to prepare fused silica capillary gas chromatographic columns where the stationary phase is a molecular sieve affixed to the silica capillary wall without the aid of an organic binder by modifying the interior surface of the silica...
02/17/1998
5705078Oxidative removal of aqueous cyanide by manganese(IV)-containing oxides
Manganese(IV)-containing oxides are effective catalysts for oxidation of water-soluble cyanide over a wide pH range (0.5-12) and temperature (15°-250° C.). Oxygen is the preferred oxidizing agent at partial pressures between about 0.2 and 5 atmospheres ...
01/06/1998
5702503Composite gas separation membranes and making thereof
A composite membrane made of an asymmetric porous support and an ultrathin layer having a thickness of less than 100 nm is provided. A method of making the membrane and method for carrying out gas separations using the membrane are also provided....
12/30/1997
5698103Extraction of water-soluble metal chelates used as catalysts in sweetening sour hydrocarbon feedstocks
Sweetening of sour hydrocarbon feedstocks by contacting with an aqueous solution of a metal chelate as an oxidation catalyst in the presence of oxygen is hindered by the difficulty of recovering metal chelate. Extraction of the aqueous phase with a liquid...
12/16/1997
5672797Alkylation of aromatics using a metal cation-modified friedel-crafts type catalyst
A process for the alkylation of aromatic compounds with an olefin, alcohol, or alkyl halide having from 1 to 24 carbon atoms comprising reacting in the liquid phase the aromatic and alkylating agent under alkylation conditions in the presence of a novel c...
09/30/1997
5648579Continuous alkylation of aromatics using solid catalysts; prevention of catalyst deactivation using a pulsed feed reactor
A novel continuous process for the preparation of alkylated benzenes effected by solid catalysts which become deactivated under alkylation conditions uses a single catalyst zone for both reaction and catalyst flushing to prevent deactivation. The process ...
07/15/1997
5645729Separations by simulated moving bed chromatography operating at low k' values using weakly interacting adsorbents as the stationary phase
Resolution of a mixture of organic materials by simulated moving bed chromatography using a weakly interacting adsorbent as a stationary phase can be routinely effected with a liquid mobile phase characterized by atypically low values of k' with recoverie...
07/08/1997
5626762Separations by simulated moving bed chromatography operating at low K' values using weakly interating adsorbents as the stationary phase
Resolution of a mixture of organic materials by simulated moving bed chromatography using a weakly interacting adsorbent as a stationary phase can be routinely effected with a liquid mobile phase characterized by atypically low values of k' with recoverie...
05/06/1997
5620960Use of D-allose as an immunosuppressive agent
D-allose has been found to substantially inhibit segmented neutrophil production and to lower platelet counts during in vivo trials, without other significant detrimental clinical effects. Such pharmacological activity makes D-allose a good candidate for ...
04/15/1997
5600142Measurement of vaporized hydrogen peroxide
On line and essentially continuous measurements of hydrogen peroxide vapor in the presence of water vapor can be made using near infrared (NIR) spectroscopy using fiber optic cables to transmit infrared radiation between, e.g, a sterilization chamber and ...
02/04/1997
5599956Integrated process for the production of propylene oxide
Propylene oxide may be produced by an integrated process utilizing as a basic feedstock a refinery stream containing saturated hydrocarbons. The first element of the process converts one or more of the saturated hydrocarbons to a stream containing propyle...
02/04/1997
5567605Assay for D-allose using a NAD cofactor coupled D-allose dehydrogenase
A D-allose specific dehydrogenase has been isolated which can be used with NAD as a cofactor in a sensitive, specific, quantitative assay for D-allose in aqueous media. A qualitative, color-based test for the presence of D-allose results when an election-...
10/22/1996
5565400Hydrothermally stable metal oxide solid solutions as carriers for catalytic composites
Ternary metal oxide solid solutions containing permutations of magnesium, nickel, and cobalt with trivalent metals such as aluminum, chromium, gallium, and iron show unusual resistance to rehydration. A composite comprising a) a ternary metal oxide solid ...
10/15/1996
5552042Rigid silica capillary assembly
A new type of tubular assembly especially adaptable to capillary columns for use in gas chromatography, comprises a capillary wound on and fused to a hollow mandrel and stress relieved by heating. The entire assembly is rigid and is more resistant to frac...
09/03/1996
5536895Isomerization process using modified zeolite Omega
Forms of zeolite Omega synthesized by hydrothermal crystallization from reaction systems containing alkali metal cations and organic templating agents, modified by calcination in air, ion-exchange, steam calcination and treatment with a low-pH aqueous amm...
07/16/1996
5536301Methods for analysis of volatile organic compounds in water and air
The purge and trap procedure commonly used for analysis of volatile organic compounds in water or air can be significantly improved using traps employing molecular sieves as adsorbents. Silicalite and potassium-exchanged dealuminated zeolite Y form an eff...
07/16/1996
5523508Process for linear alpha-olefin production: eliminating wax precipitation
Linear alpha-olefin formation via oligomerization of ethylene using transition metal catalysis leads to a Schultz-Flory distribution of oligomers. At modest temperatures formation of heavy oligomers which are waxy solids only partly soluble in the LAO pro...
06/04/1996
5518625Chiral separations by simulated moving bed chromatography operating at low k' values
Resolution of a racemic mixture of organic materials by simulated moving bed chromatography using a chiral stationary phase can be routinely effected at atypically low values of k' with recoveries of at least 95% and an optical purity of at least 95%. In ...
05/21/1996
5512751Calibration of NIR spectra in measuring properties of petroleum products
The observation was made that virtually all octane number variations arise from 23 components present in a broad variety of gasolines. Consequently it is possible to develop a calibration set consisting of a gasoline base stock as modified by one or more ...
04/30/1996
5491271Detergent alkylation using a regenerable clay catalyst
Tetrahedrally charged clays have been found to be active, regenerable catalysts in detergent alkylation, both as delaminated and pillared clays. The pillared saponites and beidellites are especially favored in forming detergent range alkylates using olefi...
02/13/1996
5488156Preparation of a heat-stable lactic acid
Lactic acid formed via fermentation generally is susceptible to the development of color bodies when heated to temperatures of approximately 180° C. and above. Color development appears to result from carbonization of small amounts of carbohydrates. Cons...
01/30/1996
5476985Process for separating linear and branched hydrocarbons using alkylene-bridged polysilsesquioxanes
An adsorptive process to separate the components of a solution of linear and branched hydrocarbons into a linear hydrocarbon portion and a branched hydrocarbon portion where the adsorbent is an alkylene-bridged polysilsesquioxane has been developed. The h...
12/19/1995
5476964Continuous racemization of benzylic alcohols, ethers, and esters by solid acid catalyst
Benzyl alcohols having a chiral center at the benzylic carbon can be conveniently racemized by treatment with solid acids which are strongly acidic cation exchange materials. Racemization may be effected generally in the range from 20°-150° C. in aqueou...
12/19/1995
5476596Oxidation and hydrolysis of cyanides using metal chelates on supports of metal oxide solid solutions
The oxidation of inorganic cyanides and the concurrent hydrolysis of many organic cyanides can be effected in aqueous media using a diversity of metal chelates supported on metal oxide solid solutions. Metal oxide solid solutions containing magnesium and ...
12/19/1995
5475162Acid functionalized organically-bridged polysilsesquioxanes as catalysts for acid catalyzed reactions
A process of effecting an acid catalyzed reaction wherein a reactant capable of undergoing an acid catalyzed reaction is contacted with an acid functionalized organically-bridged polysilsesquioxane catalyst where all of the acid functionality is covalentl...
12/12/1995
5473105Process for concurrently producing diisopropyl ether and isoproyl ethyl ether
A process for concurrently producing diisopropyl ether and isopropyl ethyl ether from water, ethanol from an independent source, and propylene, has been developed. The product mixture may be used as a high octane number booster due mainly to the presence ...
12/05/1995
5470890Bis-(N-alkylaminocyclohexyl)methanes as curing agents in polyurethane and polyurea flexible foam manufacture
Flexible foam resistant to both photochemical and oxidative degradation result from the use of bis(N-alkylaminocyclohexyl)methanes as curing agents for polyisocyanates or polyisocyanate prepolymers. The chain extenders may be used alone or in combination ...
11/28/1995
5470482Control process for simulated moving bed para-xylene separation
A process of continuously controlling at least one characteristic of a simulated moving bed para-xylene separation process has been developed. The characteristics controlled may be the purity or the recovery of the para-xylene. The process involves measur...
11/28/1995
5466835Titanosilicate as an epoxidation catalyst for olefins
The oxidation of olefinic compounds generally using hydroperoxides, especially aqueous solutions of hydrogen peroxide, can be effected in high yield and with good selectivity in the presence of a catalyst which is a mixture of small particles of titania a...
11/14/1995
5458787Extraction of certain metal cations from aqueous solutions
Carbonaceous pyropolymers possessing recurring units containing at least carbon and hydrogen atoms on their surface are effective in removing from solution metal cations having a standard reduction potential to their zerovalent state of greater than -0.2 ...
10/17/1995
5457260Control process for simulated moving adsorbent bed separations
A process of continuously controlling at least one characteristic of a simulated moving adsorbent bed separation process has been developed. The characteristics controlled may be the purity or the recovery of the component of interest. The process involve...
10/10/1995
5449696Process for methanol production using simulated moving bed reactive chromatography
A process for the continuous production of methanol through contacting at least one feed stream containing at least carbon monoxide and hydrogen, and optionally carbon dioxide, with a simulated moving bed acting as a catalyst for methanol synthesis and an...
09/12/1995
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