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Attorney: Arechederra; Leandro


Number of patents: 83
Last date: February 14, 2012

1      
NumberTitleIssue Date
8115042Oligomerisation of olefins
In the oligomerization of olefins in a tubular reactor employing a molecular sieve catalyst, the temperature of the reaction is monitored and the space velocity of the olefin feed to the reactor is reduced as the temperature increases. This has been found to increas...
02/14/2012
7919551Branched olefin compositions
Olefin compositions comprising C5 to C13 branched chain olefins are stabilised by the addition of 5 to less than 50 ppm by weight of antioxidant. These lower than normal amounts of antioxidant enable improved yields in a hydroformylation reacti...
04/05/2011
7880046Low corrosion in zeolite oligomerisation
Water reacts on molecular sieve catalysts used in oligomerization reactions and forms oxygenated compounds, in particular organic acids that may cause corrosion problems downstream of the reactor, in particular in distillation tower overhead systems and downstream t...
02/01/2011
7875254Internal loop reactor and Oxo process using same
The invention relates to improvements in internal loop reactors. The reactor of the invention is characterized by a plurality of cooling tubes which form the annulus between the riser and the downcomer path of said internal loop reactor. The reactor also provides im...
01/25/2011
7696266Select elastomeric blends and their use in articles
The present invention relates to select elastomeric blends including at least one halogenated random copolymer. In particular, the present invention relates to compositions including at least one halogenated random copolymer of isobutylene and methylstyrene, prefera...
04/13/2010
7659355Elastomeric compositions, air barriers, and processes for the making the same
The invention relates to novel air barriers made from elastomeric compositions. In particular, the invention relates to novel air barriers such as innerliners, air sleeves, and innertubes made from novel C4 to C7 isoolefin based polymers with n...
02/09/2010
7632886Elastomer nanocomposites comprising isobutylene and multifunctional oligomers
The present invention provides a nanocomposite of an elastomer, a polymer or oligomer functionalized with a polar group, and a clay. The nanocomposite can be a mixture of a halogenated elastomer, an acid or acid anhydride modified polymer, and a clay, desirably an e...
12/15/2009
7479327Tie-layer materials for use with ionomer-based films and sheets as skins on other materials
The present invention relates to new tie-layer materials for making (1) new multilayer structures formed from one or more ionomers and one or more new tie-layers including a (co) extrudable tie resin (CTR), and optionally a backing layer to form laminates, (2) new c...
01/20/2009
7432328Enhanced ESCR bimodal HDPE for blow molding applications
Bimodal polyethylene compositions and blow molded bottles made therefrom are provided. In at least one specific embodiment, the composition includes at least one high molecular weight polyethylene component having a molecular weight distribution (MWD) of about 6 to ...
10/07/2008
7414099Hindered polyalicyclic alkyl catalysts and their use in a gas-phase polymerization reactor
Embodiments of the present invention include a method of polymerizing olefins comprising contacting olefins with a catalyst composition made by the process of combining a hindered polyalicyclic alkyl catalyst precursor with a particulate inorganic oxide for a deposi...
08/19/2008
7410926Polymerization process using a supported, treated catalyst system
The present invention relates to a supported, treated catalyst system and its use in a process for polymerizing olefin(s). More particularly, it provides a supported, treated catalyst system produced by a process comprising the steps of: (a) forming a supported bime...
08/12/2008
7405008Ionomer laminates and articles formed from ionomer laminates
The present invention includes a laminate and formation of a laminate having at least one layer of an ionomer and at least one layer of an acid polymer or blend of acid polymer and a thermoplastic polyolefin that can be thermoformed to form a shaped laminate. The sh...
07/29/2008
7393916Method of reducing gels in polyolefins
A process of producing a polyolefin, in one embodiment a polyethylene, and in a preferred embodiment a bimodal polyethylene comprising a high molecular weight component and a low molecular weight component, the process comprising providing a polyolefin having an I
07/01/2008
7381783Polymerization catalyst systems, their use, their products and articles thereof
The present invention relates to a process for the polymerization of monomers utilizing a bulky ligand hafnium transition metal metallocene-type catalyst compound, to the catalyst compound itself and to the catalyst compound in combination with an activator. The inv...
06/03/2008
7381780Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions
Improved catalyst compositions, and polymerization processes using such improved catalyst compositions, are provided. An example of an improved catalyst composition is a supported catalyst system that includes at least one titanium compound, at least one magnesium c...
06/03/2008
7343225Method for reducing off-grade product production during reaction transitions
In some embodiments, a method for determining initial conditions for a transition from an initial reaction to a target reaction to minimize (or substantially minimize) the amount of off-grade material produced during the transition, and optionally also process contr...
03/11/2008
7328733Inner tube compositions having improved heat resistance characteristics
Halogenated isobutylene-co-alkylstyrene polymer, preferably halogenated isobutylene-co-methylstyrene polymer, even more preferably brominated isobutylene-co-paramethylstyrene polymer (BIMS), blends thereof, and blends with a second rubber, show improved heat resista...
02/12/2008
7326760Production of broad molecular weight polyethylene
Broad molecular weight polyethylene and polyethylene having a bimodal molecular weight profile can be produced with chromium oxide based catalyst systems employing alkyl silanols. The systems may also contain various organoaluminum compounds. Catalyst activity and m...
02/05/2008
7323526Supported metallocene-alkyl catalyst composition
A supported catalyst composition having improved flow properties is disclosed comprising an alkylalumoxane, a metallocene-alkyl an inorganic oxide support having an average particle size of from 0.1 to 50 μm and calcined at a temperature greater than 600° C., and ...
01/29/2008
7312279Polyethylene blend compositions
Disclosed herein are various compositions, including a high density polyethylene composition, comprising: (a) a bimodal polyethylene component that includes a high molecular weight polyethylene component having a high average molecular weight (MWHMW) and ...
12/25/2007
7300987Polymerization process
The present invention relates to a continuous gas phase process comprising polymerizing one or more hydrocarbon monomer(s) in a fluidized bed reactor in the presence of catalyst system or polymerization catalyst and a condensable fluid for a period of at least 12 ho...
11/27/2007
7288596Polyethylene compositions having improved tear properties
Disclosed are various compositions, including but not limited to a high density multimodal polyethylene composition, that has a density of 0.935 g/cc or more, and that includes a blend of a first polyethylene component and a second polyethylene component, in which: ...
10/30/2007
7276566De-foaming spray dried catalyst slurries
A method for preparing a spray dried catalyst and a low viscosity, low foam spray dried catalyst system for olefin polymerization are provided. In one aspect, the method includes preparing a catalyst system including one or more components selected from metallocenes...
10/02/2007
7270791Angular flow distribution bottom head
An improved angled annular deflector for a gas-phase polymerization reactor and improved method for delivery of a stream of polymerizable fluid to a gas-phase polymerization reator. The angled annular deflector has an outer surface with a conical shape, an inner sur...
09/18/2007
7244795Polymerization process using metallocene catalyst systems
The present invention relates to a polymerization process using improved metallocene catalyst systems. Specifically, the catalyst systems of the present invention relate to a metallocene compound having optimized metals loading and activator concentration, and demon...
07/17/2007
7232872Polymerization processes
The invention provides for a process to produce polymers utilizing a hydrofluorocarbon diluent. ...
06/19/2007
7226789Method of applying non-linear dynamics to control a gas-phase polyethylene reactor operability
The present invention describes a method for determining reactor continuity of a polymerization reactor by non-linear dynamics. Specifically, the invention relates to a method of analyzing system variables to indicate gas phase reactor continuity in real-time and co...
06/05/2007
7220804Method for preparing a catalyst system and its use in a polymerization process
The present invention relates to a supported catalyst composition and a method for making the supported catalyst composition and its use in a process for polymerizing olefin(s). In particular, the invention is directed to a method for making a supported catalyst com...
05/22/2007
7199255Imino-amide catalysts for olefin polymerization
The present invention provides a catalyst precursor, a catalyst system comprising the precursor, and a polymerization method using the catalyst system, an embodiment of the precursor is selected from the following structures:
04/03/2007
7199072Process of producing a supported mixed catalyst system and polyolefins therefrom
A process for preparing a mixed catalyst compound used in the polymerization of polyolefins to produce bimodal polyethylenes is disclosed. In an embodiment, a process of preparing the mixed catalyst system includes: mixing a first catalyst and an activator in a firs...
04/03/2007
7196032Fluoroalcohol leaving group for non-metallocene olefin polymerization catalysts
A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ...
03/27/2007
7193017High strength biomodal polyethylene compositions
Disclosed are various compositions, including but not limited to a high strength bimodal polyethylene composition having a density of 0.940 g/cc or more, the composition comprising a high molecular weight polyethylene component having a higher weight average molecul...
03/20/2007
7183234Multi-donor catalyst system for the polymerization of olefins
The present invention provides catalyst systems including a Ziegler-Natta or Ziegler-Natta-type catalyst in combination with a mixture of certain electron donors. ...
02/27/2007
7179876High tear films from hafnocene catalyzed polyethylenes
A polyethylene film having a balance of improved physical and mechanical properties and a method for making the same are provided. In one aspect, the film includes a 1% secant modulus of greater than 25,000 psi, a dart impact resistance of greater than 500 g/mil, an...
02/20/2007
7172816High tear films from hafnocene catalyzed polyethylenes
A polyethylene film having a balance of improved physical and mechanical properties and a method for making the same are provided. In one aspect, the film includes a 1% secant modulus of greater than 25,000 psi, a dart impact resistance of greater than 500 g/mil, an...
02/06/2007
7172987Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom
Bimetallic catalysts, and methods of producing a bimetallic catalyst comprising a modified Ziegler-Natta catalyst and a metallocene are provided, in one embodiment the method including combining: (a) a Ziegler-Natta catalyst comprising a Group 4, 5 or 6 metal halide...
02/06/2007
7163991Fluoroalcohol leaving group for non-metallocene olefin polymerization catalysts
A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ...
01/16/2007
7157591Metallocenes and catalyst compositions derived therefrom
Metallocenes and catalyst systems for olefin polymerization derived therefrom. The metallocenes may be represented by the formula: wherein M1 preferably is zirconium or hafnium; and R5 is di...
01/02/2007
7157531Methods for producing polymers with control over composition distribution
Methods for controlling a melt viscosity of a polyolefin, controlling comonomer distribution of a polyolefin, achieving a targeted melt viscosity of a polyolefin, and films made from such polyolefins are provided. The methods include contacting an olefin monomer and...
01/02/2007
7141632Mixed metallocene catalyst systems containing a poor comonomer incorporator and a good comonomer incorporator
The present invention provides polymerization catalyst compounds, catalyst systems including these catalyst compounds, and to their use in the polymerization of ethylene and at least one comonomer. In particular, the invention provides a catalyst system comprising a...
11/28/2006
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