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Assignee: Quantum Chemical Corporation


Location: Cincinnati, OH
No. of patents: 73

1    
NumberTitleIssue Date
6031129Use of pentavalent group VA oxides in acetic acid processing
Methanol is converted to acetic acid by reaction with carbon monoxide in the presence of an improved carbonylation system which comprises a rhodium catalyst component and a liquid reaction medium containing water in low levels, acetic acid, methyl iodide,...
02/29/2000
5817869Use of pentavalent Group VA oxides in acetic acid processing
Methanol is converted to acetic acid by reaction with carbon monoxide in the presence of an carbonylation system which comprises a rhodium catalyst component and a liquid reaction medium containing acetic acid, methyl iodide, methyl acetate, and at least ...
10/06/1998
5733480Semiconductive extrudable polyolefin compositions and articles
Semiconductive polyolefin formulations are provided which are readily extrudable into films and coatings having low surface resistivity. The formulations of the invention are comprised of a polyethylene resin with 6 to 15 weight percent of a mixture of tw...
03/31/1998
5705576Process for controlling production of in-situ thermoplastic polyolefins and products
An improved gas-phase polymerization process for producing in-situ thermoplastic polyolefins in multiple reactors using high activity Ti/Al catalysts is provided. The improvement consists of developing a control parameter derived from eight integrated reg...
01/06/1998
5681359Ethylene vinyl acetate and isobutylene terpolymer as a cold flow improver for distillate fuel compositions
Terpolymers of ethylene, vinyl acetate and isobutylene as flow improvers in distillate fuels. The terpolymers have number average molecular weights in the range of about 1,600 to about 3,000, and weight average molecular weights in the range of about 4,00...
10/28/1997
5670439Vanadium-containing catalyst system
A vanadium-containing catalyst system particularly suited to the polymerization of olefin polymers. The catalyst system includes a supported, first catalyst component prepared by contacting silica with hexaalkyldisilazane and thereupon with (1) a compound...
09/23/1997
5661095Olefin polymerization catalyst component supported on a copolymer of an olefin and an unsaturated silane
A catalyst component useful in the polymerization of olefins which includes a support formed of a copolymer of an olefin and a silane monomer having at least one unsaturated hydrocaryl substitutent. A process for making the catalyst component as well as a...
08/26/1997
5639818Peroxide modified PP/PE blends with superior melt strength
The instant invention is directed to a process for preparing peroxide modified polypropylene/polyethylene blends that have superior extrusion coating properties. More specifically, the peroxide modified PP/PE blends produced by the instant invention exhib...
06/17/1997
5610246Process for polymerizing propylene using a silica-supported catalyst
A new catalyst useful in the polymerization of at least one olefin is disclosed. The catalyst comprises the product obtained by contacting silica, in random order, with (1) at least one hydrocarbon soluble magnesium-containing compound; and (2) a first mo...
03/11/1997
5597865Adhesive blends for polystyrene
Adhesive blends having special utility in the formation of composite structures with LDPE, EVOH, and impact-modified polystyrene comprise a mixture of an ethylene/ester copolymer such as EVA, polystyrene, such as impact-modified polystyrene, and a functio...
01/28/1997
5587439Polymer supported catalyst for olefin polymerization
The present invention is directed to a supported metallocene catalyst useful in the polymerization of ଱-olefins which is obtained by tethering a metallocene catalyst component to the surface of a particulate, functionalized copolymeric support mater...
12/24/1996
5587436Process for controlling the polymerization of propylene and ethylene and copolymer products
An improved gas-phase copolymerization process for producing copolymers of propylene and ethylene in multiple reactors using high activity Ti/Al catalysts is provided. The improvement consists of developing a control parameter derived from eight integral ...
12/24/1996
5574082Propylene polymer compositions having improved color and stabilizers therefor.
Useful stabilizer combinations and propylene polymer compositions stabilized therewith having improved resistance to discoloration upon processing are provided. The stabilizer combinations of the invention are comprised of a mixture of calcium salts of st...
11/12/1996
5534472Vanadium-containing catalyst system
A vanadium-containing catalyst system particularly suited to the polymerization of blow moldable olefin polymers. The catalyst system includes a supported, first catalyst component prepared by contacting preheated silica, with (1) a compound or complex wh...
07/09/1996
5525672Adhesive blends of modified anhydride-grafted polyolefins
Anhydride-functionalized polymers are modified in accordance with the present invention by reacting all or a portion of the anhydride functionality with an aliphatic alcohol to convert the anhydride groups to half-esters. Half-esters produced by modifying...
06/11/1996
5486333Blow molding extrusion die with rectangular slots
A die for a blow molding machine has at least one circumferential rectangular cutout section contiguous with the die exit in at least the die ring or the mandrel. The rectangular cutout section expands the material flow channel between the die ring and th...
01/23/1996
5486575High performance blow molding resins and process for their preparation
A process is provided to improve the properties of polyethylene resins obtained from chromium catalyzed polymerizations and blow molded bottles produced therefrom. The process entails modifying the polyethylene resin by contacting the resin in a molten st...
01/23/1996
5466648Supported alpha-olefin dimerization catalyst
The present invention is directed to a supported tungsten-based catalyst composition useful for the dimerization of alpha-olefins including ethylene. More particularly, the catalyst composition of the instant invention comprises an organic or inorganic su...
11/14/1995
5459201Impact strength, stress-whitening and bruise-resistance for impact modified polypropylene
The present invention relates to a process for preparing high melt flow rate thermoplastic compositions that have improved impact and bruise-resistance properties and to the thermoplastic composition that are produced by the process of the instant inventi...
10/17/1995
5439965Abrasion resistant crosslinkable insulation compositions
Flame retardant and abrasion resistant crosslinkable compositions useful as insulation for wire and cable are provided. The compositions contain an ethylene-vinyl acetate copolymer having a vinyl ester content of 5 to 12 wt. %, a halogenated compound, ant...
08/08/1995
5439974Propylene-based extrudable adhesive blends
Adhesive blends especially suitable for adhesion to one or more polypropylene substrates consisting essentially of a mixture of a modified impact copolymer and a graft reaction product of a propylene polymer and a carboxylic acid or derivative thereof are...
08/08/1995
5426153High impact strength film grade polymeric composition
A polymeric composition including a first copolymer of ethylene and a higher ଱-olefin having 3 to 12 carbon atoms, said first copolymer having a density of between 0.880 g/cc. and about 0.949 g/cc. and a melt index of between about 0.01 and about 10...
06/20/1995
5424263Supported polymerization catalyst
A catalyst component useful in the polymerization of olefins is disclosed. The catalyst component comprises the product obtained by steps of (a) contacting silica with at least one hydrocarbon soluble magnesium-containing compound; (b) contacting the prod...
06/13/1995
5422386Process to simultaneously reactor-fill polyolefins and compatibilize fillers with polyolefins
The present invention relates to a process to simultaneously reactor-fill polyolefins and to a compatibilized, reactor-filled polyolefin composite produced by the process of the instant invention. More specifically, the instant invention provides a proces...
06/06/1995
5412025Method to reactor-fill polyolefins by employing a sticky prepolymer as a blending and compatibilizing agent
The present invention relates to a process to in-situ reactor-fill polyolefins. More specifically, the instant invention provides a process to reactor-fill polyolefins comprising the steps of (a) adding a sufficient amount of alpha-olefin to a filler prio...
05/02/1995
5412012Flame retardant insulation compositions having improved strippability
The present invention relates to flame retardant insulation and jacketing compositions useful for wire and cable products which exhibit improved adhesion to the metal conductor. This is achieved by the use of a specific stabilizer package comprised of thr...
05/02/1995
5412001Method to reactor-fill polyolefins by formation of a dual catalyst system causing compatibilization of the filler with the maxtrix polymer
The present invention relates to a method to reactor-fill polyolefins and to reactor-filled composites obtained from the instant method. More specifically, the present invention relates to a method to reactor-fill polyolefins comprising the steps of (a) a...
05/02/1995
5405817V/TI multi-site olefin polymerization catalyst
Catalysts useful in olefin polymerization are a mixture of (a) a titanium-containing compound which is (i) Ti(Z1)t (OZ2)p-t, (ii) the product of reacting Z3 --Mg--N(--Z5)--Si(Z4)...
04/11/1995
5401787Flame retardant insulation compositions
Improved flame retardant moisture curable insulation compositions are comprised of an ethylene-alkoxysilane copolymer, a halogenated anhydride and antimony trioxide provided. The compositions have good processability and can be moisture cured to provide p...
03/28/1995
5399540ZR/V multi-site olefin polymerization catalyst
A catalyst useful in the polymerization of olefins, especially ethylene, is disclosed. The catalyst is obtained by admixing a zinc composition, a zirconium composition and a vanadium composition. The catalyst may be combined with a co-catalyst and, option...
03/21/1995
5376742Monomer recovery in gas phase fluid bed olefin polymerization
Unreacted monomer present in an ethylene/C3 -C8 alpha-olefin copolymer product produced in a catalyzed fluid bed polymerization process is purged with a gaseous stream obtained by subjecting a portion of the gaseous effluent from the...
12/27/1994
5374597Vanadium based olefin polymerization catalyst
Catalysts useful in olefin polymerization are a mixture of (a) (i) one or more compounds Zn(X1)2 and one or more compounds Al(R1)3, or (ii) Zn(X1)2.2Al(R1)3, wherein X...
12/20/1994
5370941Laminates of 4-methylpentene-1 polymers and vinyl alcohol polymers and adhesives therefor
Improved two-component blends which exhibit good adhesion to 4-methylpentene-1 polymers and vinyl alcohol polymers and which may be used as an adhesive interlayer when laminating layers of the polymers are provided. Ethylene-alkyl acrylate copolymers, pre...
12/06/1994
5369194Olefin polymerization method
A multiple site solid catalyst component capable of producing polyolefins having a broad or multimodal molecular weight distribution, such as a bimodal molecular weight distribution, is prepared by contacting a particulate solid support with a zirconium c...
11/29/1994
5367022Grafted polymeric products, and adhesive blends
Highly functional grafted polymeric products of a predominantly propylene polymeric composition containing a thermoplastic ethylene-propylene copolymer and a carboxylic acid or derivative grafting monomer and having a desirably low melt flow rate, adhesiv...
11/22/1994
5349847Releasable stationary plate for rheometer
A stationary plate assembly for a rheometer that selectively provides steady state and dynamic testing of melt viscoelastic characteristics of a material sample. The stationary plate assembly has a stationary sample plate magnetically coupled to its suppo...
09/27/1994
5346872Cocatalyst for vanadium/titanium containing polymerization catalyst
The present invention relates to a novel catalyst component for ethylene polymerization comprising vanadium and titanium. Moreover, when the vanadium/titanium containing catalyst of the present invention is employed with an aluminum-containing cocatalyst ...
09/13/1994
5344886Process for making graft propylene polymers
A process for making a graft propylene copolymer in which a propylene polymer, selected from the group consisting of propylene homopolymers and propylene copolymers, is contacted with a polymerizable, unsaturated carboxylic acid or acid derivative in the ...
09/06/1994
5344803Cocatalyst for transition metal-containing ଱-olefin polymerization catalyst
The present invention is directed to a novel halosilane cocatalyst component which, when used in conjunction with an aluminum containing cocatalyst, is effective in increasing the activity of a supported magnesium/titanium containing catalyst in the polym...
09/06/1994
5344888Process for making graft propylene polymers
A process for making a graft propylene copolymer in which a propylene polymer, selected from the group consisting of propylene homopolymers and propylene copolymers, is contacted with a polymerizable, unsaturated carboxylic acid or acid derivative in the ...
09/06/1994
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